Related papers: AC Stark Effect in Ultracold Polar RbCs Molecules
We calculate the microwave spectra of ultracold KRb alkali metal dimers, including hyperfine interactions and in the presence of electric and magnetic fields. We show that microwave transitions may be used to transfer molecules between…
Demonstrating the quantum-confined Stark effect (QCSE) in silicon nanocrystals (NCs) embedded in oxide has been rather elusive, unlike the other materials. Here, the recent experimental data from ion-implanted Si NCs is unambiguously…
We report the measurement of hyperfine splitting in the $7d$ $^{2}D_{3/2}$ state of $^{133}$Cs using high resolution Doppler-free two-photon spectroscopy in a Cs vapor cell. We determine the hyperfine coupling constants $A = 7.3509(9)$ MHz…
Carbon monoxide molecules in their electronic, vibrational, and rotational ground state are highly attractive for trapping experiments. The optical or ac electric traps that can be envisioned for these molecules will be very shallow,…
Atoms coupled to optical fields confined in one and two spatial dimensions in solid state microstructures can experience very large light shifts if the driving frequencies are close to a resonance of the microstructures and an atomic…
We report the full control over the internal states of ultracold $^{23}$Na$^{87}$Rb molecules, including vibrational, rotational and hyperfine degrees of freedom. Starting from a sample of weakly bound Feshbach molecules, we realize the…
We report on the direct conversion of laser-cooled 41K and 87Rb atoms into ultracold 41K87Rb molecules in the rovibrational ground state via photoassociation followed by stimulated Raman adiabatic passage. High-resolution spectroscopy based…
Polar molecules are desirable systems for quantum simulations and cold chemistry. Molecular ions are easily trapped, but a bias electric field applied to polarize them tends to accelerate them out of the trap. We present a general solution…
We consider how trapped molecules can be sympathetically cooled by ultracold atoms. As a prototypical system, we study LiH molecules co-trapped with ultracold Li atoms. We calculate the elastic and inelastic collision cross sections of LiH…
We have focused and decelerated benzonitrile (C$_7$H$_5$N) molecules from a molecular beam, using an array of time-varying inhomogeneous electric fields in alternating gradient configuration. Benzonitrile is prototypical for large…
We investigate the effects of rotation on one-dimensional ultracold bosons confined to optical ring lattices. First, we show that there exists a critical rotation frequency at which the ground state of a weakly-interacting and…
Experimental and theoretical studies are presented related to the ground-state magneto-optical resonance prepared in Cesium vapour confined in an Extremely Thin Cell (ETC, with thickness equal to the wavelength of the irradiating light). It…
Laser cycling of resonances can remove entropy from a system via spontaneously emitted photons, with electronic resonances providing the fastest cooling timescales because of their rapid relaxation rates. Although atoms are routinely laser…
We investigate the energy levels of heteronuclear alkali metal dimers in levels correlating with the lowest rotational level of the ground electronic state, which are important in efforts to produce ground-state ultracold molecules. We use…
We demonstrate the deceleration of heavy polar molecules in low-field seeking states by combining a cryogenic source and a travelling-wave Stark decelerator. The cryogenic source provides a high intensity beam with low speed and…
We demonstrate theoretically the existence of a linear dc Stark shift of the individual substates of an alkali atom in its ground state, dressed by a circularly polarized laser field. It arises from the electroweak nuclear anapole moment…
Recent work with laser-cooled molecules in attractive optical traps has shown that the differential AC Stark shifts arising from the trap light itself can become problematic, limiting collisional shielding efficiencies, rotational coherence…
We report on the determination of the dynamical polarizability of ultracold erbium atoms in the ground and in one excited state at three different wavelengths, which are particularly relevant for optical trapping. Our study combines…
We present a new theoretical analysis of the strongly suppressed F- and M-dependent Stark shifts of the Cs ground state hyperfine structure. Our treatment uses third order perturbation theory including off-diagonal hyperfine interactions…
Chemisorbed molecules at a fuel cell electrode are a very sensitive probe of the surrounding electrochemical environment, and one that can be accurately monitored with different spectroscopic techniques. We develop a comprehensive…