Related papers: Laser spectroscopy of $^{176}$Lu$^+$
Iridium ions near $4f$-$5s$ level crossings are the leading candidates for a new type of atomic clocks with a high projected accuracy and a very high sensitivity to the temporal variation of the fine structure constant $\alpha$. To identify…
High-harmonic spectroscopy driven by circularly-polarized laser pulses and their counter-rotating second harmonic is a new branch of attosecond science which currently lacks quantitative interpretations. We extend this technique to the…
Precision measurements of the Lu$^+$ $^3D_1$ and $^3D_2$ quadrupole moments have been carried out giving $\Theta(^3D_1)=0.63862(74)\,e a_0^2$ and $\Theta(^3D_2)=0.8602(14)\,e a_0^2$, respectively. The measurements utilize the differential…
We report a precise measurement of hyperfine structure in the $ \rm {3\,S_{1/2}} $ state of the odd isotope of Li, namely $ \rm {^7Li} $. The state is excited from the ground $ \rm {2\,S_{1/2}} $ state (which has the same parity) using two…
We present a comprehensive theoretical investigation of hyperfine-resolved excitation and detection of the low-energy isomeric state of $^{229}$Th in trapped $^{229}\mathrm{Th}^{3+}$ ions. Using a quantum master equation approach, we…
We show that optical spectroscopy of Rydberg states can provide accurate {\em in situ} thermometry at room-temperature. Transitions from a metastable state to Rydberg states with principal quantum numbers of 25 to 30 have 200 times larger…
We report on spectroscopy of the low-lying electronic transitions in $^{224}$Ra$^+$. The ion's low charge to mass ratio and convenient wavelengths make $^{224}$Ra$^+$ a promising optical clock candidate. We measured the frequencies of the…
We perform the four-body calculation of the hyperfine structure in the first rotational state $J=1$ of the H$_2$, D$_2$, and HD molecules and determine the accurate value for the deuteron electric quadrupole moment $Q_d =…
We have developed a broadly-applicable approach that drastically increases the ability to accurately predict properties of complex atoms. We applied it to the case of Ir$^{17+}$, which is of particular interest for the development of novel…
The absolute frequencies of the hyperfine components of the R(26) 62-0 transition in molecular iodine at 501.7 nm are measured for the first time with an optical clockwork based on a femtosecond laser frequency comb generator. The set-up is…
We present and characterize a laser system for the spectroscopy on highly-charged ^209Bi^82+ ions at a wavelength of 243.87 nm. For absolute frequency stabilization, the laser system is locked to a near-infra-red laser stabilized to a…
We report the measurement of hyperfine splitting in the $7d$ $^{2}D_{3/2}$ state of $^{133}$Cs using high resolution Doppler-free two-photon spectroscopy in a Cs vapor cell. We determine the hyperfine coupling constants $A = 7.3509(9)$ MHz…
We consider transitions of electron holes (vacancies in otherwise filled shells of atomic systems) in multiply-charged ions that, due to level-crossing of the holes, have frequencies within the range of optical atomic clocks. Strong E1…
We report new experimental hyperfine structure (HFS) constants of neutral and singly ionized scandium (Sc I and Sc II). We observed spectra of Sc-Ar and Sc-Ne hollow cathode discharges in the region 200-2500 nm (50,000-4000 cm$^{-1}$) using…
We report on fabrication of three dimensional (3D) microstructures in glass with isotropic spatial resolutions. To achieve high throughput fabrication, we expand the focal spot size with a low-numerical-aperture lens, which naturally…
Collinear laser spectroscopy measurements were performed on $^{69,71,73}$Ge isotopes ($Z = 32$) at ISOLDE-CERN. The hyperfine structure of the $4s^2 4p^2 \, ^3P_1 \rightarrow 4s^2 4p 5s \, ^3P_1^o$ transition of the germanium atom was…
An atom exposed to an electric field will experience Stark shifts of its internal energy levels, proportional to their polarizabilities. In optical frequency metrology, the Stark shift due to background black-body radiation (BBR) modifies…
Highly charged ions (HCIs) offer many opportunities for next-generation clock research due to the vast landscape of available electronic transitions in different charge states. The development of XUV frequency combs has enabled the search…
Molecular hydrogen ions are of metrological relevance due to the possibility of precise theoretical evaluation of their spectrum and of external-field-induced shifts. We report the results of the calculations of the rate of laser-induced…
Atom interferometry on optical clock transitions is being pursued for numerous long-baseline experiments both terrestrially and for future space missions. Crucial to meeting these experiments' required sensitivities is the implementation of…