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Molecular hydrogen in silicon has been studied by path-integral molecular dynamics simulations in the canonical ensemble. Finite-temperature properties of these point defects were analyzed in the range from 300 to 900 K. Interatomic…

Materials Science · Physics 2009-07-31 Carlos P. Herrero , Rafael Ramirez

Defects on surfaces of semiconductors have a strong effect on their reactivity and catalytic properties. The concentration of different charge states of defects is determined by their formation energies. First-principles calculations are an…

Mesoscale and Nanoscale Physics · Physics 2017-07-05 Dmitry Vinichenko , M. Gokhan Sensoy , Cynthia M. Friend , Efthimios Kaxiras

A novel approach to predict the atomic densities of amorphous materials is explored on the basis of Car-Parrinello molecular dynamics (CPMD) in density functional theory. Despite that determination of the atomic density of matter is crucial…

Disordered Systems and Neural Networks · Physics 2018-01-17 Yoritaka Furukawa , Yu-ichiro Matsushita

Deep defects in silicon carbide (SiC) possess atom-like electronic, spin and optical properties, making them ideal for quantum-computing and -sensing applications. In these applications, deep defects are often placed within fabricated…

Materials Science · Physics 2022-05-09 Tamanna Joshi , Pratibha Dev

We study the structural, dynamical and electronic properties of amorphous Si\sub{1-x}Ge\sub{x}:H alloys using first principles local basis molecular dynamics simulation. The network topology and defects in the amorphous network have been…

Materials Science · Physics 2007-05-23 T. A. Abtew , D. A. Drabold

In this contribution we present the results of Density-Functional Theory (DFT) calculations of platelets as modelled by infinite planar arrangements of hydrogen atoms and vacancies in (100) planes of silicon. From the observation of the…

Materials Science · Physics 2011-11-29 Liviu Bîlteanu , Jean-Paul Crocombette

We study sub-surface arsenic dopants in a hydrogen terminated Si(001) sample at 77 K, using scanning tunnelling microscopy and spectroscopy. We observe a number of different dopant related features that fall into two classes, which we call…

We present a systematic study of the atomic and electronic structure of the Si(111)-(5x2)-Au reconstruction using first-principles electronic structure calculations based on the density functional theory. We analyze the structural models…

Materials Science · Physics 2009-11-11 Sampsa Riikonen , Daniel Sanchez-Portal

We present a study of the self-interstitial point defect formation energies in silicon using a range of quantum chemical theories including the coupled cluster (CC) method within a periodic supercell approach. We study the formation…

Materials Science · Physics 2023-06-23 Faruk Salihbegović , Alejandro Gallo , Andreas Grüneis

The anharmonic decay rates of atomic vibrations in amorphous silicon (a-Si) and paracrystalline silicon (p-Si), containing small crystalline grains embedded in a disordered matrix, are calculated using realistic structural models. The…

Disordered Systems and Neural Networks · Physics 2009-11-10 Jaroslav Fabian , Joseph L. Feldman , C. Stephen Hellberg , S. M. Nakhmanson

The stability and formation mechanism of the defects relevant to silicon and carbon vacancies at the 4H-SiC(000$\bar{1}$)/SiO$_2$ interface after wet oxidation are investigated by first-principles calculation based on the density functional…

Materials Science · Physics 2024-01-09 Mukai Tsunasaki , Tomoya Ono , Mitsuharu Uemoto

To assess the potential of amorphous Si (a-Si) as an anode for Li, Na, and Mg-ion batteries, the energetics of Li, Na, and Mg atoms in a-Si are computed from first-principles and compared to those in crystalline Si (c-Si). It is shown that…

Materials Science · Physics 2014-12-30 Fleur Legrain , Oleksandr I. Malyi , Sergei Manzhos

Amorphous silicon contains tunneling two-level systems, which are the dominant energy loss mechanisms for amorphous solids at low temperatures. These two-level systems affect both mechanical and electromagnetic oscillators and are believed…

Materials Science · Physics 2021-03-10 M. Molina-Ruiz , Y. J. Rosen , H. C. Jacks , M. R. Abernathy , T. H. Metcalf , X. Liu , J. L Dubois , F. Hellman

The influence of intrinsic defects of 1T-TaS2 on charge density waves (CDW) is studied using scanning tunneling microscopy and spectroscopy (STM, STS), angle-resolved photoelectron spectroscopy (ARPES), and density functional theory (DFT).…

We use molecular dynamics computer simulations to study the equilibrium properties of the surface of amorphous silica. Two types of geometries are investigated: i) clusters with different diameters (13.5\AA, 19\AA, and 26.5\AA) and ii) a…

Statistical Mechanics · Physics 2009-10-31 Alexandra Roder , Walter Kob , Kurt Binder

This letter introduces ab initio study of the full activation-volume tensor of crystalline defects as a means to make contact with mechanical response experiments. We present a theoretical framework for prediction of the internal friction…

Materials Science · Physics 2015-06-24 H. Ustunel , D. Roundy , T. A. Arias

Silicon is indispensable in semiconductor industry. Understanding its high-temperature thermodynamic properties is essential both for theory and applications. However, first-principle description of high-temperature thermodynamic properties…

Materials Science · Physics 2023-10-30 M. V. Kondrin , Y. B. Lebed , V. V. Brazhkin

The molecular dynamics method is applied to simulate the recrystallization of an amorphous/crystalline silicon interface. The atomic structure of the amorphous material is constructed with the method of Wooten, Winer, and Weaire. The…

Computational Physics · Physics 2011-07-07 Christophe Krzeminski , Quentin Brulin , V. Cuny , Emmanuel Lecat , Evelyne Lampin , Fabrizio Cleri

Hydrogenated amorphous silicon (a-Si:H) has garnered considerable attention in the semiconductor industry, particularly for its use in solar cells and passivation layers for high performance silicon solar cells, owing to its exceptional…

Materials Science · Physics 2025-02-14 Zhuo Chen , Yuejin Yuan , Yanzhou Wang , Penghua Ying , Shouhang Li , Cheng Shao , Wenyang Ding , Gang Zhang , Meng An

We perform total energy calculations based on the tight-binding Hamiltonian scheme (i) to study the structural properties and energetics of the extended {311} defects depending upon their dimensions and interstitial concentrations and (ii)…

Materials Science · Physics 2009-10-28 Jeongnim Kim , John W. Wilkins , Furrukh S. Khan , Andrew Canning
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