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Context : Despite the low cosmic abundance of deuterium (D/H ~ 1e-5), large degrees of deuterium fractionation in molecules are observed in star forming regions with enhancements that can reach 13 orders of magnitude, which current models…

Astrophysics · Physics 2016-08-30 B. Parise , C. Ceccarelli , A. G. G. M. Tielens , A. Castets , E. Caux , B. Lefloch , S. Maret

[abridged] The enhanced degrees of deuterium fractionation observed in envelopes around protostars demonstrate the importance of chemistry at low temperatures, relevant in pre- and protostellar cores. formaldehyde is an important species in…

Extremely high deuteration of several molecules have been observed around low mass protostars since a decade. Among them, formaldehyde and methanol present particularly high deuteration, with observations of abundant doubly and triply…

Astrophysics of Galaxies · Physics 2015-06-04 Vianney Taquet , Cecilia Ceccarelli , Claudine Kahane

The study of deuteration in pre-stellar cores is important to understand the physical and chemical initial conditions in the process of star formation. In particular, observations toward pre-stellar cores of methanol and deuterated…

Context: Methanol is thought to be mainly formed during the prestellar phase and its deuterated form keeps memory of the conditions at that epoch. Thanks to the unique combination of high angular resolution and sensitivity provided by ALMA,…

In the context of the ASAI (Astrochemical Surveys At IRAM) project, we carried out an unbiased spectral survey in the millimeter window towards the well known low-mass Class I source SVS13-A. The high sensitivity reached (3-12 mK) allowed…

Solar and Stellar Astrophysics · Physics 2016-08-03 C. Codella , C. Ceccarelli , E. Bianchi , R. Bachiller , B. Lefloch , F. Fontani , V. Taquet , L. Testi

Methanol is a key species in astrochemistry since it is the most abundant organic molecule in the ISM and is thought to be the mother molecule of many complex organic species. Estimating the deuteration of methanol around young protostars…

The study of deuterium fractionation is a valuable tool for reconstructing our chemical history from the early prestellar stages to the formation of planets. In the context of the ALMA Large Programme FAUST, we observed formaldehyde,…

Molecular deuteration is a powerful diagnostic tool for probing the physical conditions and chemical processes in astrophysical environments. In this work, we focus on formaldehyde deuteration in the protobinary system NGC\,1333 IRAS\,4A,…

The deuteration of molecules forming in the ices such as methanol (CH$_3$OH) is sensitive to the physical conditions during their formation in dense cold clouds and can be probed through observations of deuterated methanol in hot cores.…

Context. Deuterium in H-bearing species is enhanced during the early stages of star formation, however, only a small number of high spatial resolution deuteration studies exist towards protostellar objects, leaving the small-scale…

Prestellar cores represent early sites of low-mass ($M$ $\leq$ few M$_\odot$) star and planet formation and provide insight into initial chemical conditions of complex organic molecules (COMs). Deuterated COMs trace the degree of molecular…

The abundance of deuterated molecules in a star-forming region is sensitive to the environment in which they are formed. Deuteration fractions therefore provide a powerful tool for studying the physical and chemical evolution of a…

We are carrying out a physical and chemical study of the protostellar envelopes in a representative sample of IM Class 0 protostars. In our first paper (Crimier et al. 2010), we determined the physical structure (density-temperature radial…

We investigate the deuteration of methanol towards the high-mass star forming region NGC 7538-IRS1. We have carried out a multi-transition study of CH$_3$OH, $^{13}$CH$_3$OH and of the deuterated fllavors, CH$_2$DOH and CH$_3$OD, between…

Isotopic fractionation is a very powerful tool to follow the evolution of material from one stage to the next in the star-formation process. Pre-stellar cores exhibit some of the highest levels of deuteration because their physical…

Astrophysics of Galaxies · Physics 2026-02-20 S. Spezzano , W. Riedel , P. Caselli , O. Sipilä , Y. Lin , H. A. Bunn , E. Redaelli , L. H. Coudert , A. Megías , I. Jimenez-Serra

Although deuterium enrichment of water may provide an essential piece of information in the understanding of the formation of comets and protoplanetary systems, only a few studies up to now have aimed at deriving the HDO/H2O ratio in…

Astrophysics of Galaxies · Physics 2015-03-17 F. -C. Liu , B. Parise , L. Kristensen , R. Visser , E. F. van Dishoeck , R. Güsten

Despite the detection of numerous interstellar complex organic molecules (iCOMs) for decades, it is still a matter of debate whether they are synthesized in the gas-phase or on the icy surface of interstellar grains. In the past, molecular…

Chemical Physics · Physics 2022-11-22 F. Vazart , C. Ceccarelli , D. Skouteris , N. Balucani

The inheritance of material across the star and planet formation process is traced by deuterium fractionation. We report here the first detection of doubly deuterated methanol towards pre-stellar cores. We study the deuterium fractionation…

Astrophysics of Galaxies · Physics 2023-01-11 Yuxin Lin , Silvia Spezzano , Paola Caselli

We report the first detection of triply-deuterated methanol, with 12 observed transitions, towards the low-mass protostar IRAS 16293-2422, as well as multifrequency observations of 13CH3OH, used to derive the column density of the main…

Astrophysics · Physics 2007-05-23 B. Parise , A. Castets , E. Herbst , E. Caux , C. Ceccarelli , I. Mukhopadhyay , A. G. G. M. Tielens
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