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Using density functional theory, the structural and electronic-structure properties of a recently discovered, zero-dimensional antimony halide perovskite are studied. It is found that the herein considered material EtPySbBr$_\mathrm{6}$…

Materials Science · Physics 2018-09-21 David A. Egger

Metal halide perovskite solar cells have achieved dramatic improvements in their power conversion efficiency in the recent past. Since compositional engineering plays an important role in optimizing material properties, we investigate the…

Hybrid organic-inorganic (HOI) compounds are excellent candidates for a wide spectrum of applications in diverse fields such as optics, electronics, energy and biotechnology. Their broad range of versatility is achieved by combining the…

Materials Science · Physics 2019-07-15 Trilochan Sahoo , Uchenna A. Anene , S. Pamir Alpay , Sanjeev K. Nayak

Hybrid organic-inorganic halide perovskites for photovoltaics have attracted research interest due to their unique material properties, but suffered from poor material stability. In this work, we investigated the surface phase diagrams of…

Applied Physics · Physics 2021-09-30 Yun-Sim Kim , Chol-Hyok Ri , Yun-Hyok Kye , Un-Gi Jong , Chol-Jun Yu

Organic-inorganic halide perovskites, especially methylammonium lead halide, have recently led to a remarkable breakthrough in photovoltaic devices. However, due to the environmental and stability concerns of the heavy metal, lead, in these…

Materials Science · Physics 2015-09-29 Shijing Sun , Satoshi Tominaka , Jung-Hoon Lee , Fei Xie , Paul D. Bristowe , Anthony K. Cheetham

We use density functional theory methods to study the electronic structures of a series of $s-p$ cubic perovskites $ABX_{3}$: the experimentally available SrBiO$_{3}$, BaBiO$_{3}$, BaSbO$_3$, CsTlF$_{3}$, and CsTlCl$_{3}$, as well as the…

The electronic properties of ABX3 (A = Cs, CH3NH3, NH2CHNH2; B = Sn, Pb; X = Cl, Br, I) type compounds in the cubic phase are systematically studied using the first-principles calculations. We find that these compounds have direct band gaps…

Materials Science · Physics 2015-06-17 Li Lang , Ji-Hui Yang , Heng-Rui Liu , H. J. Xiang , X. G. Gong

The low ionization energy of an $A$ site molecule is a very important factor, which determines the thermodynamical stability of $A$PbI$_3$ hybrid halide perovskites, while the size of the molecule governs the stable phase at room…

Materials Science · Physics 2018-02-13 Chao Zheng , Oleg Rubel

Halide perovskite light absorbers have great advantages for photovoltaics such as efficient solar energy absorption, but charge accumulation and recombination at the interface with an electron transport layer (ETL) remains a major challenge…

Materials Science · Physics 2020-12-18 Nikolai Tsvetkov , Byeong Cheul Moon , Jeung Ku Kang , Muhammad Ejaz Khan , Yong-Hoon Kim

The transition to sustainable energy has accelerated research into perovskite solar cells (PSCs) as promising candidates for next-generation photovoltaics. Despite their remarkable efficiencies, the commercialization of PSCs is hindered by…

Materials Science · Physics 2025-08-07 Nassim Mahammedi

Despite the promising optoelectronic properties of methylammonium lead iodide (MAPbI3)-based perovskite solar cells (PSCs), their commercial viability is hindered by interfacial energy misalignment, suboptimal light absorption, and thermal…

Optics · Physics 2025-09-04 Md. Faiaad Rahman , Arpan Sur , Ahmed Zubair

Lead halide perovskites (LHPs) exhibit outstanding optoelectronic properties, making them highly promising for applications in various optoelectronics devices. However, rapid ion migration in LHPs not only undermines device stability but…

Single crystals of Cs2BiAgBr6 lead-free perovskite were grown by crystallization from supersaturated solution. According to characterization by XRD and EBSD methods the double perovskite single crystal are of the cubic Fm-3m symmetry with…

The centrosymmetric halide perovskites undergo a continuous phase transition from a normal insulator to a topological insulator at the critical value of strain. Contrarily, in noncentrosymmetric halide perovskites, this phase transition is…

Materials Science · Physics 2023-02-28 Ankita Phutela , Sajjan Shoeran , Saswata Bhattacharya

By harvesting a wider range of the solar spectrum, intermediate band solar cells (IBSCs) can achieve efficiencies 50% higher than conventional single-junction solar cells. For this, additional requirements are imposed to the light-absorbing…

Perovskite solar cells (PSCs) with transparent electrodes can be integrated with existing solar panels in tandem configurations to increase the power conversion efficiency. A critical layer in semi-transparent PSCs is the inorganic buffer…

Halide double perovskite semiconductors such as Cs2AgBiBr6 are widely investigated as a more stable, less toxic alternative to lead-halide perovskites in light conversion applications including photovoltaics and photoredox catalysis.…

Perovskite compounds have the potential to harvest solar energy as well as exploit the thermoelectric potential of a number of available materials. Here, we present the electronic, structural, thermoelectric, and optical properties of…

Materials Science · Physics 2022-05-31 G. Murtaza

Perovskite indoor photovoltaics (PIPVs) are emerging as a transformative technology for low-light intensity energy harvesting, owing to their high power conversion efficiencies (PCEs), low-cost fabrication, solution-processability, and…

We investigate the lead-free halide double perovskites (HDPs) Cs$ _2BB'X_6$ ($B$=Ag, Na; $B'$=In, Bi; $X$=Cl, Br) via first-principles calculations. We find that both the geometric and electric structures of the HDPs obtained by the…

Materials Science · Physics 2022-08-08 Yuyang Ji , Peize Lin , Xinguo Ren , Lixin He
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