By harvesting a wider range of the solar spectrum, intermediate band solar cells (IBSCs) can achieve efficiencies 50% higher than conventional single-junction solar cells. For this, additional requirements are imposed to the light-absorbing semiconductor, which must contain a collection of in-gap levels, called intermediate band (IB), optically coupled to but thermally decoupled from the valence and conduction bands (VB and CB). Quantum-dot-in-perovskite (QDiP) solids, where inorganic quantum dots (QDs) are embedded in a halide perovskite matrix, have been recently suggested as a promising material platform for developing IBSCs. In this work, QDiP solids with excellent morphological and structural quality and strong absorption and emission related to the presence of in-gap QD levels are synthesized. With them, QDiP-based IBSCs are fabricated and, by means of temperature-dependent photocurrent measurements, it is shown that the IB is strongly thermally decoupled from the valence and conduction bands. The activation energy of the IB→CB thermal escape of electrons is measured to be 204 meV, resulting in the mitigation of this detrimental process even under room-temperature operation, thus fulfilling the first mandatory requisite to enable high-efficiency IBSCs.
@article{arxiv.2302.13305,
title = {Thermal-Carrier-Escape Mitigation in a Quantum-Dot-In-Perovskite Intermediate Band Solar Cell via Bandgap Engineering},
author = {Ugur D. Menda and Guilherme Ribeiro and Jonas Deuermeier and Esther López and Daniela Nunes and Santanu Jana and Irene Artacho and Rodrigo Martins and Iván Mora-Seró and Manuel J. Mendes and Iñigo Ramiro},
journal= {arXiv preprint arXiv:2302.13305},
year = {2024}
}