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Intermediate band solar cells (IBSCs) pursue the increase in efficiency by absorbing below-bandgap energy photons while preserving the output voltage. Experimental IBSCs based on quantum dots have already demonstrated that both…

Mesoscale and Nanoscale Physics · Physics 2021-01-14 Juan Villa , Iñigo Ramiro , José María Ripalda , Ignacio Tobías , Pablo García-Linares , Elisa Antolín , Antonio Martí

Recombination through quantum dots (QDs) is a major factor that limits efficiency of QD intermediate-band (IB) solar cells. Our proposal for a new IB solar cell based on type-II GaSb QDs located outside the depletion region of a GaAs…

Mesoscale and Nanoscale Physics · Physics 2012-10-08 A. Kechiantz , A. Afanasev , J. -L. Lazzari , A. Bhouri , Y. Cuminal , P. Christol

As an appealing concept for developing next-generation solar cells, intermediate-band solar cells (IBSCs) promise to drastically increase the quantum efficiency of photovoltaic conversion. Yet to date, a standing challenge lies in the lack…

Materials Science · Physics 2012-10-10 Fengcheng Wu , Haiping Lan , Zhenyu Zhang , Ping Cui

Harnessing low energy photons is of paramount importance for multi-junction high efficiency solar cells as well as for thermo-photovoltaic applications. However, semiconductor absorbers with bandgap lower than 0.8 eV have been limited to…

Perovskite indoor photovoltaics (PIPVs) are emerging as a transformative technology for low-light intensity energy harvesting, owing to their high power conversion efficiencies (PCEs), low-cost fabrication, solution-processability, and…

Metal halide perovskites are attracting tremendous interest for a variety of optoelectronic applications. The ability to tune the perovskite bandgap by tweaking the chemical compositions opens up new applications as coloured emitters and as…

Light-harvesting devices made from PbS quantum dot (QD) absorbers are one of the many promising technologies of third-generation photovoltaics. Their simple, solution-based fabrication together with a highly tunable and broad light…

We demonstrate four and two-terminal perovskite-perovskite tandem solar cells with ideally matched bandgaps. We develop an infrared absorbing 1.2eV bandgap perovskite, $FA_{0.75}Cs_{0.25}Sn_{0.5}Pb_{0.5}I_3$, that can deliver 14.8 %…

The intermediate band solar cell (IBSC) and quantum ratchet solar cell (QRSC) have the potential to surpass the efficiency of standard single-junction solar cells by allowing sub-gap photon absorption through states deep inside the band…

Applied Physics · Physics 2020-06-24 Emily Z. Zhang , Jacob J. Krich

Inorganic cesium lead iodide (CsPbI$_3$) perovskite solar cells (PSCs) have attracted enormous attention due to their excellent thermal stability and optical bandgap (~1.73 eV), well-suited for tandem device applications. However, achieving…

Solution-processed quantum dots (QDs) have a high potential for fabricating low cost, flexible and large-scale solar energy harvesting devices. It has recently been demonstrated that hybrid devices employing a single monovalent cation…

We perform the quantum yields in a multi-band quantum dot (QD) photocell via doping an intermediate band (IB) between the conduction band (CB) and valence band (VB). Under two different sub-band gap layouts, the output power has a prominent…

Mesoscale and Nanoscale Physics · Physics 2024-02-13 Shun-Cai Zhao , Qi-Xuan Wu

The spin-split indirect bandgap in hybrid-halide perovskites provides a momentum-space realisation of a photon-ratchet intermediate band. Excited electrons thermalise to recombination-protected Rashba pockets offset in momentum space,…

Materials Science · Physics 2016-11-30 Jarvist M. Frost , Pooya Azarhoosh , Scott McKechnie , Mark van Schilfgaarde , Aron Walsh

Organic-inorganic halide perovskite materials have emerged as attractive alternatives to conventional solar cell building blocks. Their high light absorption coefficients and long diffusion lengths suggest high power conversion efficiencies…

We present a multiscale approach for modeling an intermediate-band solar cell based on a GaAs-GaAlAs quantum dot superlattice of cubic symmetry. Our framework combines high-accuracy theoretical calculations of the superlattice band…

Mesoscale and Nanoscale Physics · Physics 2025-11-24 Naira Petrosyan , Lilit Yeganyan , Aram Manaselyan , Vram Mughnetsyan , Vidar Gudmundsson , Albert Kirakosyan

Introducing an isolated intermediate band (IB) into a wide band gap semiconductor can potentially improve the optical absorption of the material beyond the Shockley-Queisser limitation for solar cells. Here, we present a systematic study of…

Materials Science · Physics 2018-05-24 Tingting Wang , Xiaoguang Li , Wenjie Li , Li Huang , Ya Cheng , Jun Cui , Hailin Luo , Guohua Zhong

We present a theoretical analysis of intraband optical transitions from the intermediate pseudo-band of confined states to the conduction band in a finite, inhomogeneous stack of self-assembled semiconductor quantum dots. The chain is…

Mesoscale and Nanoscale Physics · Physics 2015-03-20 Igor Bragar , Paweł Machnikowski

We present a new approach to ubiquitous sensing for indoor applications, using high-efficiency and low-cost indoor perovksite photovoltaic cells as external power sources for backscatter sensors. We demonstrate wide-bandgap perovskite…

The intermediate band (IB) cell is a concept of highly efficient solar cells proposed by Luque and Marti in 1997. The IB concept uses nonlinear effect of two photon absorption enforced with concentration of such photons for generation of…

Mesoscale and Nanoscale Physics · Physics 2012-09-11 A. Kechiantz , A. Afanasev , J. -L. Lazzari

Utilizing hot carriers is the crucial approach for solar cell to exceed the thermodynamic detailed balance limit, yet effective extraction of hot carriers in absorber materials via most commonly used semiconductor acceptors has been a…

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