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Organic-inorganic halide perovskites recently have emerged as a promising material for highly effective light-emitting diodes (LEDs) and solar cells (SCs). Despite efficiencies of both perovskite SCs and LEDs are already among the best, the…

Metal halide perovskites (MHPs) have had a profound impact on numerous emerging optoelectronic technologies, achieving performance metrics that rival or exceed incumbent materials. This impact is underpinned by the exceptional properties of…

Perovskite solar cells with record power conversion efficiency are fabricated by alloying both hybrid and fully inorganic compounds. While the basic electronic properties of the hybrid perovskites are now well understood, key electronic…

Perovskite solar cells (PSCs) are attracting great attention as the most promising candidate for the next generation solar cells. This is due to their low cost and high power conversion efficiency in spite of their relatively short period…

Applied Physics · Physics 2018-11-05 Chol-Jun Yu

Hybrid halide perovskites are currently under intense investigation due to their potential applications in optoelectronics and solar cells. Among them, MAPbI$_3$ where MA stands for the methylammonium cation, exhibits ideal properties for…

Materials Science · Physics 2017-07-10 A. Koliogiorgos , S. Baskoutas , I. Galanakis

Halide perovskites have emerged as a promising class of materials for photovoltaic applications. A challenge in these applications is how to prevent the crystal structure from degradation to photovoltaically inactive phases, which requires…

Materials Science · Physics 2024-03-22 Erik Fransson , J. Magnus Rahm , Julia Wiktor , Paul Erhart

All-inorganic halide perovskites have received a lot of attention as attractive alternatives to overcome the stability issues of hybrid halide perovskites that are commonly associated with organic cations. To find a compromise between the…

Materials Science · Physics 2026-04-28 Mike Pols , Adri C. T. van Duin , Sofía Calero , Shuxia Tao

Layered lead halide A'2An-1PbnI3n+1 perovskites (2D LHPs) are attracting considerable attention as a more stable alternative with respect to APbI3 parent phases - a promising material for a new generation of solar cells. However, a critical…

Under external stimuli, lead halide perovskites exhibit large atomic fluctuations, impacting optical and electron transport properties that affect device performance in operational settings. However, a thorough understanding of the atomic…

Lead-free halide double perovskites with the formula of quaternary A$_2^+$B'B'$^{3+}$X$_6^-$ have recently attracted intense interest as alternatives to lead-halide-perovskite-based optoelectronic materials for their non-toxicity and…

Materials Science · Physics 2018-08-17 Tianshu Li , Xingang Zhao , Dongwen Yang , Mao-Hua Du , Lijun Zhang

A variety of organic-inorganic hybrid perovskites (APbX3) consisting of mixed center cations [A = CH3NH3+, HC(NH2)2+, Cs+] with different PbX3- cages (X = I, Br, Cl) have been developed to realize high-efficiency solar cells. Nevertheless,…

Despite the tremendous interest in halide perovskites in solar cells, the reason that the all-inorganic perovskite CsPbI$_3$ is unstable at room temperature remains mysterious. Here single-crystal X-ray diffraction and powder pair…

Materials Science · Physics 2020-07-08 Daniel B. Straus , Shu Guo , Milinda Abeykoon , Robert J. Cava

The performance of perovskite solar cells recently exceeded 15% solar-to-electricity conversion efficiency for small-area devices. The fundamental properties of the active absorber layers, hybrid organic-inorganic perovskites formed from…

Materials Science · Physics 2013-10-11 Federico Brivio , Alison B. Walker , Aron Walsh

Cesium based halide perovskites, such as CsPbI3 and CsSnI3, have emerged as exceptional candidates for next generation photovoltaic and optoelectronic technologies, but their practical application is limited by temperature dependent phase…

Materials Science · Physics 2025-10-30 Atefe Ebrahimi , Franco Pellegrini , Stefano De Gironcoli

Organic-inorganic halide perovskite materials have emerged as attractive alternatives to conventional solar cell building blocks. Their high light absorption coefficients and long diffusion lengths suggest high power conversion efficiencies…

Lead-free halide double perovskites are promising alternatives to Pb-based semiconductors, but their discovery is challenging because structural formability, thermodynamic stability, band-gap placement, optical-transition strength,…

The search for non-toxic lead-free halide perovskites that can compete with the lead-based counterparts has led to the emergence of double perovskites as potential candidates. Among many options, Cs2AgBiBr6 stands out as one of the most…

Materials Science · Physics 2025-10-30 Pannan I. Kyesmen , Eugen Klein , Brindhu Malani S , Rostyslav Lesyuk , Christian Klinke

Hybrid perovskites (CH3NH3PbI3) is one of the most promising novel materials for solar harvesting. Toxicity of lead (Pb), however, has always remained a concern. We investigated the electronic structure of complete replacement of Pb by…

Materials Science · Physics 2016-10-18 Jiban Kangsabanik , Vikram , Aftab Alam

Lead poisoning and notorious ambient instability in lead-based halide perovskites pave the way for the exploration of alternative materials for affordable and efficient solar cell fabrication. An important prerequisite to this end is the…

Halide perovskites are a promising class of materials for optoelectronic applications, due to their excellent optoelectronic performance. However, they suffer several dynamical degradation problems, the characterization of which is…

Materials Science · Physics 2021-11-01 Sander Raaijmakers , Mike Pols , José Manuel Vicent-Luna , Shuxia Tao