Related papers: Structures, Branching Ratios and Laser Cooling Sch…
Aluminum monofluoride (AlF) is a suitable molecule for laser cooling and trapping. Such experiments require an extensive spectroscopic characterization of the electronic structure. Two of the theoretically predicted higher lying triplet…
We have trapped BaF molecules in neon ice, and used laser-induced fluorescence spectroscopy to map out optical transitions in the trapped molecules. Our measurements show that the neon lattice does not significantly perturb certain optical…
Direct laser cooling of molecules has made significant progress in recent years. However, the selective cooling and manipulation of molecules based on their isotopic composition, which is ubiquitous in atomic laser cooling, has not yet been…
The parameter $W_\mathrm{a}$, which characterizes nuclear spin-dependent parity violation effects within the effective molecular spin-rotational Hamiltonian, was computed for the electronic ground state of radium fluoride (RaF) and found to…
Crystal and electronic structure, lattice dynamics and thermodynamic stability of little known mixed valent diamagnetic AgIAgIIIF4 beta form of AgF2 is thoroughly examined for the first time and compared with well known antiferromagnetic…
The transition metal nitride BaHfN$_2$, which consists of weakly bonded neutral slabs of closed shell ions, has structural and chemical similarities to other layered nitrides which have impressive superconducting T$_c$ when electron doped:…
The vibrational branching ratios from the lowest excited electronic state for $\textrm{SrOCH}_3$, $\textrm{SrNH}_2$, and $\textrm{SrSH}$ are measured at the $< 0.1\%$ level. Spectra are obtained by driving the $\tilde{X} - \tilde{A}$…
Sideband cooling is a popular method for cooling atoms to the ground state of an optical trap. Applying the same method to molecules requires a number of challenges to be overcome. Strong tensor Stark shifts in molecules cause the optical…
We study the formation and destabilization of dark states in a single trapped 88Sr+ ion caused by the cooling and repumping laser fields required for Doppler cooling and fluorescence detection of the ion. By numerically solving the…
Recent work with laser-cooled molecules in attractive optical traps has shown that the differential AC Stark shifts arising from the trap light itself can become problematic, limiting collisional shielding efficiencies, rotational coherence…
The collective Raman cooling of trapped one- and two-component Fermi gases is considered. We obtain the quantum master equation that describes the laser cooling in the festina lente regime, for which the heating due to photon reabsorption…
Vibrational branching ratios in the B$^2\Sigma^+$ -- X$^2\Sigma^+$ and A$^2\Pi$ -- X$^2\Sigma^+$ optical-cycling transitions of BaH molecules are investigated using measurements and {\it ab initio} calculations. The experimental values are…
We present a laser cooling scheme for trapped ions and atoms using a combination of laser couplings and a magnetic gradient field. In a Schrieffer-Wolff transformed picture, this setup cancels the carrier and blue sideband terms completely…
We have studied the effect of resonant electronic state coupling on the formation of ultracold ground-state $^{85}$Rb$_2$. Ultracold Rb$_2$ molecules are formed by photoassociation (PA) to a coupled pair of $0_u^+$ states, $0_u^+(P_{1/2})$…
We propose the application of laser cooling to a number of transition-metal atoms, allowing numerous bosonic and fermionic atomic gases to be cooled to ultra-low temperatures. The non-zero electron orbital angular momentum of these atoms…
We demonstrate the effect of Zeeman and hyperfine optical pumping and transverse laser cooling of a dysprosium (Dy) atomic beam on the $4f^{10}6s^2(J = 8) \rightarrow 4f^{10}6s6p(J = 9)$ transition at 421.291 nm. For $^{163}$Dy, an…
Molecular predissociation is the spontaneous, nonradiative bond breaking process that can occur upon excitation. In the context of laser cooling, predissociation is an unwanted consequence of molecular structure that limits the ability to…
Recently, new FeAs based high-temperature superconductors CaAFe4As4 (A=K, Rb, Cs) with a layered tetragonal crystal structure were synthesized (TC ~ 30 K). In this Letter, we report for the first time the band structures, Fermi surface…
We investigated the optical cycling effect of the $\mathrm{X}^2\Sigma(v=0,\ N=1^-) - \mathrm{A}^2\Pi_{1/2}(v'=0,\ J'=1/2^+)$ band of MgF molecules, specifically the $\mathrm{P_1/Q_{12}(1)}$ transition, which serves as the main transition in…
We present a magnetically enhanced laser cooling scheme applicable to multi-level type-II transitions and further diatomic molecules with adiabatic transfer. An angled magnetic field is introduced to not only remix the dark states, but also…