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A detailed investigation using variable temperature powder neutron diffraction demonstrates that BiFeO3 undergoes a phase transition from the ferroelectric alpha phase (rhombohedral, R3c) to a paraelectric beta phase (orthorhombic, Pbnm)…

Materials Science · Physics 2009-08-21 Donna C. Arnold , Kevin S. Knight , Finlay D. Morrison , Philip Lightfoot

The octahedral tilting and ferroelectric-like structural transition of LiOsO3 metallic perovskite [Nature Materials 12, 1024 (2013)] was examined using first-principles density-functional theory. In LiOsO3, a-a-a- octahedral titling mode is…

Materials Science · Physics 2015-06-17 Hyunsu Sim , Bog G. Kim

Stoichiometric, epitaxial LaCrO3 films have been grown on TiO2-terminated SrTiO3(001) substrates by molecular beam epitaxy using O2 as the oxidant. Film growth occurred in a layer-by-layer fashion, giving rise to structurally excellent…

Materials Science · Physics 2015-05-28 L. Qiao , T. C. Droubay , M. E. Bowden , V. Shutthanandan , T. C. Kaspar , S. A. Chambers

Thin films of (1-x)BiFeO<sub>3</sub>-xPbTiO<sub>3</sub> (BF-xPT) with x ~ 0.60 were fabricated on Pt/Si substrates by chemical solution deposition of precursor BF and PT layers alternately in three different multilayer configurations. These…

We have investigated the out-of-plane lattice relaxation related to the ferroelectric transitions in epitaxial BaTiO$_3$ (BTO) films using synchrotron X-ray diffraction. Under either compressive strain or tensile strain, there is evidence…

Materials Science · Physics 2007-05-23 Feizhou He , Barrett O. Wells

The spectacular metal-to-insulator transition of V2O3 can be progressively suppressed in thin film samples. Evidence for phase separation was observed using microbridges as a mesoscopic probe of transport properties where the same film…

Materials Science · Physics 2009-11-13 C. Grygiel , A. Pautrat , W. C. Sheets , W. Prellier , B. Mercey , L. Mechin

Although the structural phase transitions in single-crystal hybrid methyl-ammonium (MA) lead halide perovskites (MAPbX3, X = Cl, Br, I) are common phenomena, they have never been observed in the corresponding nanocrystals. Here we…

Applied Physics · Physics 2020-04-08 Yuri D. Glinka , Rui Cai , Xian Gao , Dan Wu , Rui Chen , Xiao Wei Sun

We report the epitaxial growth of BiFeO3 by pulsed electron deposition and the resulting crystal quality, magnetic and nanoscale switching properties. X-ray diffraction shows high quality single phase, epitaxial (001) oriented films grown…

Materials Science · Physics 2015-06-12 Hongxue Liu , Ryan Comes , Yonghang Pei , Jiwei Lu , Stuart Wolf

High-quality YTiO3 thin films were grown on LaAlO3 (110) substrates at low oxygen pressures (<10-8 Torr) using pulsed laser deposition. The in-plane asymmetric atomic arrangements at the substrate surface allowed us to grow epitaxial YTiO3…

Materials Science · Physics 2009-11-11 S. C. Chae , Y. J. Chang , S. S. A. Seo , T. W. Noh , D. -W. Kim , C. U. Jung

The structural properties of the SrFe2As2 and CaFe2As2 compounds have been extensively analyzed by transmission electron microscopy (TEM) from room temperature down to 20K. The experimental results demonstrate that the SrFe2As2 crystal, in…

Superconductivity · Physics 2013-05-29 C. Ma , H. X. Yang , H. F. Tian , H. L Shi , J. B. Lu , Z. W. Wang , L. J. Zeng , G. F. Chen , N. L. Wang , J. Q. Li

A previous study of the growth conditions has shown that single-phase BiFeO3 thin films can only be obtained in a narrow pressure-temperature window and that these films display a weak magnetic moment. Here we study in more detail the…

Materials Science · Physics 2009-11-13 H. Bea , M. Bibes , S. Petit , J. Kreisel , A. Barthelemy

The rich phase diagram of bulk Pr$_{1-x}$Ca$_{x}$MnO$_3$ resulting in a high tunability of physical properties gave rise to various studies related to fundamental research as well as prospective applications of the material. Importantly, as…

Controlling the Mott transition through strain engineering is crucial for advancing the development and application of memristive and neuromorphic computing devices. Yet, Mott insulators are heterogeneous due to intrinsic phase boundaries…

Materials Science · Physics 2024-07-02 Ziming Shao , Aileen Luo , Eti Barazani , Tao Zhou , Zhonghou Cai , Martin V. Holt , Yoav Kalcheim , Andrej Singer

We measure the remnant polarization of ferroelectric domains in BiFeO3 films down to 3.6 nm using low energy electron and photoelectron emission microscopy. The measured polarization decays strongly below a critical thickness of 5-7 nm…

Materials Science · Physics 2013-01-04 J. E. Rault , W. Ren , S. Prosandeev , S. Lisenkov , D. Sando , S. Fusil , M. Bibes , A. Barthelemy , L. Bellaiche , N. Barrett

Temperature dependent structural phase transitions of SrRuO3 thin films epitaxially grown on SrTiO3(001) single crystal substrates have been studied using high-resolution x-ray diffraction. In contrast to bulk SrRuO3, coherently strained…

Materials Science · Physics 2009-11-13 Arturas Vailionis , Wolter Siemons , Gertjan Koster

We report on growth-mode transitions in the growth of SrRuO3 thin films on atomically flat Ti4+ single-terminated SrTiO3 (111) substrates, investigated by reflection high-energy electron diffraction and atomic force microscopy. Over the…

Materials Science · Physics 2010-02-03 Jaewan Chang , Yoon-Seok Park , Jong-Woo Lee , Sang-Koog Kim

In this letter we show that superconducting Fe1.01Se undergoes a structural transition at 90 K from a tetragonal to an orthorhombic phase but that non-superconducting Fe1.03Se does not. Further, high resolution electron microscopy study at…

Superconductivity · Physics 2009-08-11 T. M. McQueen , A. J. Williams , P. W. Stephens , J. Tao , Y. Zhu , V. Ksenofontov , F. Casper , C. Felser , R. J. Cava

We report a detailed high-resolution powder neutron diffraction investigation of the structural behaviour of the multiferroic hexagonal polymorph of YMnO3 between room temperature and 1403 K. The study was aimed at resolving previous…

Materials Science · Physics 2015-05-19 Alexandra S. Gibbs , Kevin S. Knight , Philip Lightfoot

The structural evolution of a polydomain ferroelectric Pb(Zr0.2Ti0.8)O3 film was studied by temperature dependent X-ray diffraction. Two critical temperatures were evidenced: T*=740K, corresponding to a change in the domain structure…

Scanning tunnelling spectroscopy measurements were performed on La0.7Sr0.3MnO3 thin films both at room temperature and liquid nitrogen temperature. While no inhomogeneities were recorded at liquid nitrogen temperature on any sample, a clear…

Strongly Correlated Electrons · Physics 2009-11-11 R. Di Capua , C. A. Perroni , V. Cataudella , F. Miletto Granozio , P. Perna , M. Salluzzo , U. Scotti Di Uccio , R. Vaglio