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We report on the crystallographic structure of penta-twinned gold nanoparticles. Although gold typically exhibits a face-centered cubic (fcc) lattice, other phases have been reported in some nanoscale systems. We show that the…

The influence of delay-time between two sequential femtosecond pulses on the properties of nanoparticles obtained via laser ablation of gold in ethanol has been studied. The morphological and optical properties of the nanoparticles attained…

Mesoscale and Nanoscale Physics · Physics 2010-08-03 E. Axente , M. Barberoglou , P. G. Kuzmin , E. Magoulakis , P. A. Loukakos , E. Stratakis , G. A. Shafeev , C. Fotakis

Gold nanorods grafted with short chain polymers are assembled into controlled open structures using polymer-induced depletion interactions and structurally characterized using small angle x-ray scattering. When the nanorod diameter is…

Soft Condensed Matter · Physics 2018-02-13 Ryan Poling-Skutvik , Jonghun Lee , Suresh Narayanan , Ramanan Krishnamoorti , Jacinta C. Conrad

Polymeric nanoparticles (NPs) have a great application potential in science and technology. Their functionality strongly depends on their size. We present a theory for the size of NPs formed by precipitation of polymers into a bad solvent…

Soft Condensed Matter · Physics 2012-11-06 R. Stepanyan , J. G. J. L. Lebouille , J. J. M. Slot , R. Tuinier , M. A. Cohen Stuart

We review theoretical explanation of mechanisms of control of uniformity in growth of nanosize particles and colloids. The nanoparticles are synthesized as nanocrystals, by burst nucleation from solution. The colloids are self-assembled by…

Statistical Mechanics · Physics 2010-09-22 Vladimir Privman

The self-assembly of metallic nanoparticles is a promising route to metasurfaces with unique properties for many optical applications, such as surface-enhanced spectroscopy, light manipulation, and sensing. We present an in-depth…

Mesoscale and Nanoscale Physics · Physics 2019-07-08 Bruno G. M. Vieira , Niclas S. Mueller , Eduardo B. Barros , Stephanie Reich

A method of preparing the nanoparticles of CaCu3Ti4O12 (CCTO) with the crystallite size varying from 30 to 200 nm is optimized at a temperature as low as 680 1C from the exothermic thermal decomposition of an oxalate precursor,…

Materials Science · Physics 2013-01-18 P. Thomas , K. Dwarakanath , K. B. R. Varma , T. R. N. Kutty

We report numerical investigations of a three-dimensional model of diffusive growth of fine particles, the internal structure of which corresponds to different crystal lattices. A growing cluster (particle) is immersed in, and exchanges…

Statistical Mechanics · Physics 2010-10-12 Vyacheslav Gorshkov , Alexandr Zavalov , Vladimir Privman

Surface structure affects the growth, shape and properties of nanoparticles. In wet chemical syntheses, metal additives and surfactants are used to modify surfaces and guide nanocrystal growth. To understand this process, it is critical to…

Nanocrystals, used as building blocks, may self-assemble in long-range ordered assemblies socalled supracrystals. Different structures FCC, BCC but also Frank-Kasper phases have been observed and the roles of the soft ligands surrounding…

Soft Condensed Matter · Physics 2021-09-14 Helen Ibrahim , Victor Balédent , Marianne Impéror-Clerc , Brigitte Pansu

The study of metallic nanoparticles has a long tradition in linear and nonlinear optics [1], with current emphasis on the ultrafast dynamics, size, shape and collective effects in their optical response [2-6]. Nanoparticles also represent…

Ample experimental evidence has been accumulated demonstrating that the formation of monodispersed colloids proceeds through a more complex mechanism, than the generally excepted diffusional "burst nucleation" process. Instead, the…

Materials Science · Physics 2010-09-22 Jongsoon Park , Vladimir Privman , Egon Matijevic

Molecular dynamics simulations show that gold clusters with about 600--3000 atoms crystallize into a Mackay icosahedron upon cooling from the liquid. A detailed surface analysis shows that the facets on the surface of the Mackay icosahedral…

Materials Science · Physics 2009-11-10 Yanting Wang , S. Teitel , Christoph Dellago

A number of metal-based nanopowders such kinds as Fe, Co, Fe/Co alloy, Fe/C, Fe/organic shell were successfully produced by aerosol synthesis method. The mechanism of nanoparticles formation and the influence of experimental parameters on…

Materials Science · Physics 2007-08-13 E. S. Vasilieva , O. V. Tolochko , V. E. Yudin , D. Kim , D. -W. Lee

Nanoporous gold is widely used in research and nanotechnology because of its diverse properties, including high surface area and catalytic activity. The ligament size is usually considered as the only parameter controlling thermal stability…

Materials Science · Physics 2020-01-13 Maria Koifman Khristosov , Shiri Dishon , Imrit Noi , Alex Katsman , Boaz Pokroy

Being able to predict and tune the colloidal stability of nanoparticles is essential for a wide range of applications, yet our ability to do so is currently poor due to a lack of understanding of how they interact with one another. Here, we…

Soft Condensed Matter · Physics 2018-08-30 Thomas Kister , Debora Monego , Paul Mulvaney , Asaph Widmer-Cooper , Tobias Kraus

We suggest that the size effect in heterogeneous catalysis on gold nanoparticles (GNP) of ~1.3 - 9 nm size can be related to spontaneous terahertz (THz) emission of GNPs in the process of channeling the energy of longitudinal phonons…

Materials Science · Physics 2018-09-03 Kamil Moldosanov , Andrei Postnikov

Optical properties of polymer capped gold nanoparticles of various sizes (diameter 3-6 nm) have been studied. We present a new scheme to extract size dependent variation of total dielectric function of gold nanoparticles from measured…

Materials Science · Physics 2009-11-13 M. Haridas , S. Srivastava , J. K. Basu

The properties and applications of metallic nanoparticles are inseparably connected not only to their detailed morphology and composition, but also to their structural configuration and mutual interactions. As a result, the assemblies often…

We study the role of gold droplets in the initial stage of nanowire growth via the vapor liquid solid method. Apart from serving as a collections center for growth species, the gold droplets carry an additional crucial role that necessarily…