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The efficiency and cooling power of a two-terminal thermoelectric refrigerator are analyzed near the limit of vanishing dissipation (ideal system), where the optimal efficiency is the Carnot one, but the cooling power then unfortunately…

Mesoscale and Nanoscale Physics · Physics 2014-01-22 O. Entin-Wohlman , J-H Jiang , Y. Imry

Improvement of thermoelectric systems in terms of performance and range of applications relies on progress in materials science and optimization of device operation. In this chapter, we focuse on optimization by taking into account the…

Classical Physics · Physics 2013-09-02 H. Ouerdane , C. Goupil , Y. Apertet , A. Michot , A. Abbout

We present a general framework for determining the power-efficiency trade-off relations across arbitrary thermal machines, addressing the lack of unified optimization results stemming from their diverse functionalities (e.g., heat engines,…

Statistical Mechanics · Physics 2025-11-20 Yu-Han Ma , Cong Fu

One of the main issues that real energy converters present, when they produce effective work, is the inevitable entropy production. Within the context of Non-equilibrium Thermodynamics, entropy production tends to energetically degrade…

Statistical Mechanics · Physics 2024-01-08 L. A. Arias-Hernandez , G. Valencia-Ortega , F. Angulo-Brown , C. R. Martinez-Garcia

Thermodynamic uncertainty relations (TURs) are recently established relations between the relative uncertainty of time-integrated currents and entropy production in nonequilibrium systems. For small perturbations away from equilibrium,…

Statistical Mechanics · Physics 2018-10-05 Katarzyna Macieszczak , Kay Brandner , Juan P. Garrahan

Generalizations of Onsager reciprocity relations are established for the nonlinear response coefficients of ballistic transport in the effusion of gaseous mixtures. These generalizations, which have been established on the basis of the…

Statistical Mechanics · Physics 2011-03-29 Pierre Gaspard , David Andrieux

We investigate a stochastic heat engine based on an over-damped particle diffusing on the positive real axis in an externally driven time-periodic log-harmonic potential. The periodic driving is composed of two isothermal and two adiabatic…

Statistical Mechanics · Physics 2014-05-28 Viktor Holubec

In this paper we clarify the role of heat flux in the hydrodynamic balance equations, facilitating the formulation of an Onsager relation within the framework of this theory. Previously thought to be unobtainable from the present form of…

Condensed Matter · Physics 2009-10-28 M. W. Wu , H. L. Cui , N. J. M. Horing

We investigate a kinetic heat engine model constituted by particles enclosed in a box where one side acts as a thermostat and the opposite side is a piston exerting a given pressure. Pressure and temperature are varied in a cyclical…

Statistical Mechanics · Physics 2016-04-19 Luca Cerino , Andrea Puglisi , Angelo Vulpiani

In this paper we revisit the thermocouple model, as a linear irreversible thermodynamic energy converter. As is well known, the linear model of the thermocuple is one of the classics in this branch. In this model we note two types of…

Statistical Mechanics · Physics 2020-02-10 S. Gonzalez-Hernandez , L. A. Arias-Hernandez

The performance of a generic, cyclic heat engine between two heat reservoirs is discussed within a linear-irreversible framework. The Onsager reciprocal relation is derived as a consequence of the equivalence between quasi-static and…

Statistical Mechanics · Physics 2020-09-18 Ramandeep S. Johal

Optimality principles in nonequilibrium transport networks are linked to a thermodynamic formalism based on generalized transport potentials endowed with Legendre duality and related contact structure. This allows quantifying the distance…

Statistical Mechanics · Physics 2025-06-23 Amilcare Porporato , Shashank Kumar Anand , Salvatore Calabrese , Luca Ridolfi , Lamberto Rondoni

Controllability and observability energy functions play a fundamental role in model order reduction and are inherently connected to optimal control problems. For linear dynamical systems the energy functions are known to be quadratic…

Dynamical Systems · Mathematics 2025-02-11 Linus Balicki , Serkan Gugercin

We investigate how to minimize the work dissipated during nonequilibrium processes. To this end, we employ methods from linear response theory to describe slowly varying processes, i.e., processes operating within the linear regime around…

Statistical Mechanics · Physics 2014-07-03 Marcus V. S. Bonança , Sebastian Deffner

Linearized models of power systems are often desirable to formulate tractable control and optimization problems that still reflect real-world physics adequately under various operating conditions. In this paper, we propose an approach that…

Optimization and Control · Mathematics 2018-05-28 Marc Hohmann , Joseph Warrington , John Lygeros

In the linear regime, Onsager's response matrix provides the coupling between heat and charge currents crossing a section of thermoelectric materials of infinitesimal thickness. Integrating this response over the finite thickness of a…

Statistical Mechanics · Physics 2024-12-20 Paul Raux , Christophe Goupil , Gatien Verley

Chemical processes in closed systems are poorly controllable since they always relax to equilibrium. Living systems avoid this fate and give rise to a much richer diversity of phenomena by operating under nonequilibrium conditions. Recent…

Chemical Physics · Physics 2019-09-11 Emanuele Penocchio , Riccardo Rao , Massimiliano Esposito

For a general thermodynamic system described as a Markov process, we prove a general lower bound for dissipation in terms of the square of the heat current, thus establishing that nonvanishing current inevitably implies dissipation. This…

Statistical Mechanics · Physics 2016-11-02 Naoto Shiraishi , Keiji Saito , Hal Tasaki

Symmetry relations are manifestations of fundamental principles and constitute cornerstones of modern physics. An example are the Onsager relations between coefficients connecting thermodynamic fluxes and forces, central to transport theory…

Mesoscale and Nanoscale Physics · Physics 2014-12-11 J. Matthews , F. Battista , D. Sanchez , P. Samuelsson , H. Linke

We consider irreversible and coupled reversible-irreversible nonlinear port-Hamiltonian systems and the respective sets of thermodynamic equilibria. In particular, we are concerned with optimal state transitions and output stabilization on…

Optimization and Control · Mathematics 2024-10-08 Friedrich Philipp , Manuel Schaller , Karl Worthmann , Timm Faulwasser , Bernhard Maschke