Constraints on Onsager coefficients from quasi-static and reversible operations
Statistical Mechanics
2020-09-18 v2
Abstract
The performance of a generic, cyclic heat engine between two heat reservoirs is discussed within a linear-irreversible framework. The Onsager reciprocal relation is derived as a consequence of the equivalence between quasi-static and reversible operations, under the tight-coupling condition. When the latter condition is relaxed, it is possible to achieve reversible cycle in a finite duration. Onsager reciprocity must be violated when either the quasi-static cycle is not reversible, or the reversible cycle is not quasi-static.
Keywords
Cite
@article{arxiv.2008.13721,
title = {Constraints on Onsager coefficients from quasi-static and reversible operations},
author = {Ramandeep S. Johal},
journal= {arXiv preprint arXiv:2008.13721},
year = {2020}
}
Comments
5 pages, RevTex4-1, 2 figures, discussion added