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We show the three-dimensional electronic structure of the Kondo lattice CeIn3 using soft x-ray angle resolved photoemission spectroscopy in the paramagnetic state. For the first time, we have directly observed the three-dimensional topology…

Strongly Correlated Electrons · Physics 2016-09-20 Yun Zhang , Haiyan Lu , Xiegang Zhu , Shiyong Tan , Qin Liu , Qiuyun Chen , Wei Feng , Donghua Xie , Lizhu Luo , Yu Liu , Haifeng Song , Zhengjun Zhang , Xinchun Lai

For the first time, the dielectric response of a BaTiO3 thin film under an AC electric field is investigated using time-resolved X-ray absorption spectroscopy at the Ti K-edge to clarify correlated contributions of each constituent atom on…

Materials Science · Physics 2021-02-01 S. Kato , N. Nakajima , S. Yasui , S. Yasuhara , D. Fu , J. Adachi , H. Nitani , Y. Takeichi , A. Anspoks

Coulomb explosion imaging (CEI) with x-ray free electron lasers has recently been shown to be a powerful method for obtaining detailed structural information of gas-phase planar ring molecules [R. Boll et al. Nat. Phys. 18, 423-428 (2022)].…

We report on the heteroepitaxial stabilization of YCrO3 ultra-thin films on LSAT (001) substrate. Using a combination of resonant X-ray absorption spectroscopy (XAS) and atomic multiplet cluster calculation, the electronic structure of…

Materials Science · Physics 2018-08-01 Banabir Pal , Xiaoran Liu , Fangdi Wen , Mikhail Kareev , A. T. N Diaye , P. Shafer , E. Arenholz , Jak Chakhalian

Amongst the iron-based superconductors, LiFeAs is unrivalled in the simplicity of its crystal structure and phase diagram. However, our understanding of this canonical compound suffers from conflict between mutually incompatible…

The evolution of electron correlation in Sr$_{x}$Ca$_{1-x}$VO$_3$ has been studied using a combination of bulk-sensitive resonant soft x-ray emission spectroscopy (RXES), surface-sensitive photoemission spectroscopy (PES), and ab initio…

Strongly Correlated Electrons · Physics 2013-07-25 J. Laverock , B. Chen , K. E. Smith , R. P. Singh , G. Balakrishnan , M. Gu , J. W. Lu , S. A. Wolf , R. M. Qiao , W. Yang , J. Adell

Fast-cooling after sintering or annealing of BiFeO3-BaTiO3 mixed oxide ceramics yields core-shell structures that give excellent functional properties, but their precise phase assemblage and nanostructure remains an open question. By…

We propose a self-consistent method for electronic structure calculations of correlated systems, which combines the local spin-density approximation (LSDA) and the dynamical mean field theory (DMFT). The LSDA part is based on the exact…

Strongly Correlated Electrons · Physics 2007-05-23 L. Chioncel , L. Vitos , I. A. Abrikosov , J. Kollar , M. I. Katsnelson , A. I. Lichtenstein

We have performed the bulk-sensitive high-resolution soft x-ray photoemission study of a Kondo semiconductor CeRhAs and related compounds CeNiSn and CePdSn. The comparison of the spectra of polycrystalline CePdSn on the fractured and…

Strongly Correlated Electrons · Physics 2018-10-02 A. Sekiyama , Y. Fujita , M. Tsunekawa , S. Kasai , A. Shigemoto , S. Imada , D. T. Adroja , T. Yoshino , F. Iga , T. Takabatake , T. Nanba , S. Suga

The work presents the electronic structure, spin state and optical properties of TM-dinuclear molecules (TM = Cr, Mn, Fe, Co, and Ni) which was modelled according to the recently reported Pt$^{II}$-dinuclear complex…

Materials Science · Physics 2019-12-19 Indukuru Ramesh Reddy , Kartick Tarafder

We have performed an angle-resolved photoemission spectroscopy (ARPES) study of the undoped and electron-doped iron pnictides BaFe2\_{-x}CoxAs2 (Ba122) (x=0, 0.14) and studied the Fermi surfaces (FSs) and band dispersions near the Fermi…

Investigating Shubnikov-de Haas (SdH) oscillations in high magnetic fields, we experimentally infer the electronic band structure of the quasi-two-dimensional electron gas (2DEG) at the ionic-liquid gated amorphous (a)-LaAlO$_3$/KTaO$_3$…

Materials Science · Physics 2021-09-15 Km Rubi , Shengwei Zeng , Femke Bangma , Michel Goiran , A. Ariando , Walter Escoffier , Uli Zeitler

Novel low-band-gap copolymer oligomers are proposed on the basis of density functional theory (DFT) quantum chemical calculations of photophysical properties. These molecules have an electron donor-accepter (D-A) architecture involving…

Chemical Physics · Physics 2017-08-18 Tarek Mestiri , Ala Aldin M. H. M. Darghouth , Mark E. Casida , Kamel Alimi

Resonant valence-band X-ray photoelectron spectra (ResPES) excited near 2p$_{3/2}$ core level energies, 2p X-ray photoelectron spectra (XPS) and L$_{3,2}$ X-ray absorption spectra (XAS) of Ti and Mn in single crystal of 1T-Mn$_2$TiSe$_2$…

Materials Science · Physics 2015-05-27 M. V. Yablonskikh , A. S. Shkvarin , Y. M. Yarmoshenko , N. A. Skorikov , A. N. Titov

The excited state electronic structure of $\pi$ conjugated phenylene-acetylene oligomers is calculated using time-dependent density functional theory (TD-DFT) approaches. The theoretical fluorescence spectra are analyzed in terms of…

Chemical Physics · Physics 2015-06-26 R. J. Magyar , S. Tretiak , Y. Gao , H. L. Wang , A. P. Shreve

The authors report in situ Auger electron spectroscopy (AES) of the surfaces of complex oxides thin films grown by pulsed laser deposition (PLD). The authors demonstrate the utility of the technique in studying chemical composition by…

Materials Science · Physics 2021-02-10 Thomas Orvis , Mythili Surendran , Yang Liu , Austin Cunniff , Jayakanth Ravichandran

Poly(3,4-ethylenedioxythiophene) : poly(styrene sulfonic acid (PEDOT:PSS), an optically transparent organic semi-conductor, constitutes a suspension of conducting PEDOT:PSS grains, shelled by an insulating layer of PSS. While a percolation…

Materials Science · Physics 2013-09-19 A. N. Papathanassiou , I. Sakellis , J. Grammatikakis , E. Vitoratos , S. Sakkopoulos

The electronic structures, charge and spin dynamics of the cobalt pnictide compounds ACo2As2 (A=Ba, Sr, Ca) in the paramagnetic state are investigated by using density functional theory combined with dynamical mean-field theory. In contrast…

Strongly Correlated Electrons · Physics 2018-09-25 Huican Mao , Zhiping Yin

The formation of ordered phases of dimethyl-disulfide on the Au(111) surface has been investigated by means of Low-Energy Electron Diffraction (LEED), X-ray Photoemission Spectroscopy (XPS), and state-of-the-art Density Functional Theory…

Condensed Matter · Physics 2007-05-23 V. De Renzi , D. Marchetto , R. Biagi , U. del Pennino , R. Di Felice , A. Selloni

We study spatial coherence properties of a system composed of periodic silver nanoparticle arrays covered with a fluorescent organic molecule (DiD) film. The evolution of spatial coherence of this composite structure from the weak to the…