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We study a novel regime of the Rydberg excitation blockade using highly Stark-shifted, yet long-living, states of Rb atoms subject to electric fields above the classical ionization limit. Such states allow tuning the dipole-dipole…
We perform a comparative analysis of different computational approaches employed to explore the electronic structure of ultralong-range Rydberg molecules. Employing the Fermi pseudopotential approach, where the interaction is approximated…
For low-density plasmas, the classical limit described by the Debye-H\"uckel theory is still considered as an appropriate description even though a clear experimental proof of this paradigm is lacking due to the problems in determining the…
Alkaline earth Rydberg atoms are very promising tools for quantum technologies. Their highly excited outer electron provides them with the remarkable properties of Rydberg atoms and, notably, with a huge coupling to external fields or to…
Rydberg atoms have shown significant promise as the basis for highly sensitive detectors of continuous radio-frequency (RF) E-fields. Here, we study their time-dependent response to pulse-modulated RF E-fields at 19.4 GHz using a cesium…
We investigate the dynamical formation of crystalline states with systems of polar molecules or Rydberg atoms loaded into a deep optical lattice. External fields in these systems can be used to couple the atoms or molecules between two…
N$_2$ molecules traveling in pulsed supersonic beams have been excited from their ${\mathrm{X\,^1\Sigma_{\mathrm{g}}^+}}$ ground electronic state to long-lived Rydberg states with principal quantum numbers between 39 and 48 using a…
We develop and study quantum and semi-classical models of Rydberg-atom spectroscopy in amplitude-modulated optical lattices. Both initial- and target-state Rydberg atoms are trapped in the lattice. Unlike in any other spectroscopic scheme,…
Measurements of the electron's electric dipole moment (eEDM) are demanding tests of physics beyond the Standard Model. We describe how ultracold YbF molecules could be used to improve the precision of eEDM measurements by two to three…
Networks of Rydberg atoms provide a powerful basis for quantum simulators and quantum technologies. Inspired by matter-wave atomtronics, here we engineer switches, diodes and universal logic gates. Our schemes control the Rydberg excitation…
Ultracold polar molecules offer the possibility of exploring quantum gases with interparticle interactions that are strong, long-range, and spatially anisotropic. This is in stark contrast to the dilute gases of ultracold atoms, which have…
Rydberg atom arrays have emerged as a leading platform for quantum information science. Reaching system sizes of hundreds of long-lived qubits, these arrays are used for highly coherent analog quantum simulation, as well as digital quantum…
In proposals for quantum computers using arrays of trapped ultracold polar molecules as qubits, a strong external field with appreciable gradient is imposed in order to prevent quenching of the dipole moments by rotation and to distinguish…
Precise control and study of molecules is challenging due to the variety of internal degrees of freedom and local coordinates that are typically not controlled in an experiment. Employing quantum gas microscopy to position and resolve the…
Atoms confined in optical tweezer arrays constitute a platform for the implementation of quantum computers and simulators. State-dependent operations are realized by exploiting electrostatic dipolar interactions that emerge, when two atoms…
The electronic spectrum of a Rydberg atom immersed in a Bose-Einstein condensate is investigated. The Heisenberg equations of motions for the condensate and the Rydberg atom are derived. Neglecting the backaction of the Rydberg atom onto…
Quantum sensing has attracted significant attention due to its ability to measure physical quantities with extremely high accuracy. Rydberg atoms - typically alkali atoms with a highly excited valence electron that is far from the nucleus -…
Electrons in atoms and molecules are versatile physical systems covering a vast range of light-matter interactions, enabling the physics of Rydberg states, photon-photon bound states, simulation of condensed matter Hamiltonians, and quantum…
An operator that generates an approximate symmetry of long-range Rydberg molecules (LRRMs) formed by two alkali atoms, one in a Rydberg state and the other in the ground state, is identified. This is first done by evaluating the natural…
We show that the recently observed class of long-range ion-Rydberg molecules can be divided into two families of states, which are characterised by their unique electronic structures resulting from the ion-induced admixture of quantum…