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Electrostatic trapping of N$_2$ molecules in high Rydberg states

Atomic Physics 2024-03-20 v1 Chemical Physics

Abstract

N2_2 molecules traveling in pulsed supersonic beams have been excited from their X1Σg+{\mathrm{X\,^1\Sigma_{\mathrm{g}}^+}} ground electronic state to long-lived Rydberg states with principal quantum numbers between 39 and 48 using a resonance-enhanced two-color three-photon excitation scheme. The Rydberg states populated had static electric dipole moments exceeding 50005000 D which allowed deceleration of the molecules to rest in the laboratory-fixed frame of reference and three-dimensional trapping using inhomogeneous electric fields. The trapped molecules were confined for up to 10 ms, with effective trap decay time constants increasing with principal quantum number, and ranging from 450μ\mus to 700 μ\mus. These observations, and comparison with the results of similar measurements with He atoms, indicate that the decay dynamics of the trapped Rydberg N2_2 molecules are dominated by spontaneous emission and do not exhibit significant contributions from effects of intramolecular interactions that lead to non-radiative decay.

Keywords

Cite

@article{arxiv.2403.12315,
  title  = {Electrostatic trapping of N$_2$ molecules in high Rydberg states},
  author = {M. H. Rayment and S. D. Hogan},
  journal= {arXiv preprint arXiv:2403.12315},
  year   = {2024}
}

Comments

6 pages, 4 figures