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We show that the quantum statistical mechanics describing quantum and thermal properties of objects has only the sense of a particular semiclassical approximation. We propose a more general (than that theory) microdescription of objects in…

Statistical Mechanics · Physics 2010-12-23 A. D. Sukhanov , V. G. Bar'yakhtar , O. N. Golubjeva

The simulation of adiabatic evolution has deep connections with Adiabatic Quantum Computation, the Quantum Approximate Optimization Algorithm and adiabatic state preparation. Here we address the error analysis problem in quantum simulation…

Quantum Physics · Physics 2022-02-09 Changhao Yi

Boltzmann's principle is used to select the "most probable" realization (macrostate) of an isolated or closed thermodynamic system, containing a small number of particles ($N \llsp \infty$), for both classical and quantum statistics. The…

Statistical Mechanics · Physics 2015-05-13 Robert K. Niven

For a dynamical system far from equilibrium, one has to deal with empirical probabilities defined through time-averages, and the main problem is then how to formulate an appropriate statistical thermodynamics. The common answer is that the…

Statistical Mechanics · Physics 2009-11-10 A. Carati

On the occasion of the 100th anniversary of the beginning of the revolutionary contributions to physics by Einstein, I am happy to respond to a problem posed by him in 1905. He said: In this paper it will be shown that according to the…

Quantum Physics · Physics 2007-05-23 Elias P. Gyftopoulos

In an attempt to derive thermodynamics from classical mechanics, an approximate expression for the equilibrium temperature of a finite system has been derived [M. Bianucci, R. Mannella, B. J. West, and P. Grigolini, Phys. Rev. E 51, 3002…

Statistical Mechanics · Physics 2015-06-24 Artur B. Adib

There are three levels of description in classical statistical mechanics, the microscopic/dynamic, the macroscopic/statistical and the thermodynamic. At one end there is a well-used concept of equilibrium in thermodynamics and at the other…

Statistical Mechanics · Physics 2007-05-23 D. A. Lavis

Stochastic thermodynamics extends the notions and relations of classical thermodynamics to small systems that experience strong fluctuations. The definitions of work and heat and the microscopically reversible condition are two key concepts…

Statistical Mechanics · Physics 2019-07-23 Geng Li , Z. C. Tu

This is an analysis of the additivity of the entropy of thermodynamical systems with finite heat baths. It is presented an expression for the physical entropy of weakly interacting ergodic systems, and it is shown that it is valid for both…

Statistical Mechanics · Physics 2007-05-23 M. P. Almeida

Traditionally, phase transitions are defined in the thermodynamic limit only. We propose a new formulation of equilibrium thermo-dynamics that is based entirely on mechanics and reflects just the {\em geometry and topology} of the N-body…

Statistical Mechanics · Physics 2009-10-31 D. H. E. Gross

We study the motion of an overdamped particle connected to a thermal heat bath in the presence of an external periodic potential in one dimension. When we coarse-grain, i.e., bin the particle positions using bin sizes that are larger than…

Statistical Mechanics · Physics 2023-03-01 Lucianno Defaveri , Eli Barkai , David A. Kessler

Boltzmann-Gibbs statistical mechanics is based on the entropy $S_{BG}=-k \sum_{i=1}^W p_i \ln p_i$. It enables a successful thermal approach of ubiquitous systems, such as those involving short-range interactions, markovian processes, and,…

Statistical Mechanics · Physics 2009-11-10 Constantino Tsallis , Edgardo Brigatti

The resource theory of thermal operations, an established model for small-scale thermodynamics, provides an extension of equilibrium thermodynamics to nonequilibrium situations. On a lattice of any dimension with any translation-invariant…

This is the fourth paper, the last one, on solution to the problem of absence of detailed balance in nonequilibrium processes. It is an approach based on another known universal dynamics: The evolutionary dynamics first conceived by Darwin…

Other Condensed Matter · Physics 2008-06-03 P Ao

The relation between saddle points of the potential of a classical many-particle system and the analyticity properties of its Boltzmann entropy is studied. For finite systems, each saddle point is found to cause a nonanalyticity in the…

Statistical Mechanics · Physics 2008-05-14 Michael Kastner , Oliver Schnetz , Steffen Schreiber

Understanding the connection between thermodynamics and dynamics in glass-forming liquids remains a central challenge in condensed matter physics. In this study, we investigate a novel model system that enables a continuous crossover from a…

Soft Condensed Matter · Physics 2025-05-30 Ehtesham Anwar , Ujjwal Kumar Nandi , Palak Patel , Sanket Kumawat , Sarika Maitra Bhattacharyya

The problem of the insensitivity of the macroscopic behavior of any thermodynamical system to partitioning generates a bias between the reproducibility of its macroscopic behavior viewed as the simplest form of causality and its long-term…

General Physics · Physics 2007-05-23 Maria K. Koleva

The nonadiabatic entropy production is a useful tool for the thermodynamic analysis of continuously dissipating, nonequilibrium steady states. For open quantum systems, two seemingly distinct definitions for the nonadiabatic entropy…

Quantum Physics · Physics 2015-06-19 Jordan M. Horowitz , Takahiro Sagawa

Recently a number of approaches has been developed to connect the microscopic dynamics of particle systems to the macroscopic properties of systems in nonequilibrium stationary states, via the theory of dynamical systems. This way a direct…

Statistical Mechanics · Physics 2009-10-31 L. Rondoni , E. G. D. Cohen

In adiabatic quantum computing the aim is to track an eigenstate as the Hamiltonian changes. In the usual setup this is achieved using the natural time-dependent Hamiltonian evolution of the system and the main technical tool is the…

Quantum Physics · Physics 2026-05-29 Joseph Cunningham , Jérémie Roland