Related papers: Regularized Boltzmann entropy determines macroscop…
Equilibrium statistical mechanics is intended to link the microscopic dynamics of particles to the thermodynamic laws for macroscopic quantities. However, the modern statistical theory is faced with significant difficulties, as applied to…
We extend the recently developed non-gaussian thermodynamic formalism \cite{tre98} of a (presumably strongly turbulent) non-Markovian medium to its most general form that allows for the formulation of a consistent thermodynamic theory. All…
A multi-parametric version of the nonadditive entropy $S_{q}$ is introduced. This new entropic form, denoted by $S_{a,b,r}$, possesses many interesting statistical properties, and it reduces to the entropy $S_q$ for $b=0$, $a=r:=1-q$ (hence…
A pedagogical derivation of statistical mechanics from quantum mechanics is provided, by means of open quantum systems. Besides, a new definition of Boltzmann entropy for a quantum closed system is also given to count microstates in a way…
We demonstrate that Shannon's information entropy and the thermodynamic entropy of Boltzmann and Gibbs are quantitatively equivalent for real condensed-matter systems. By interpreting atomic configurations as information sources, we compute…
In statistical mechanics entropy is a measure of disorder obeying Boltzmann's formula $S=\log{\cal N}$, where ${\cal N}$ is the accessible phase space volume. In black hole thermodynamics one associates to a black hole an entropy…
The applicability of stochastic differential equations to thermodynamics is considered and a new form, different from the classical Ito and Stratonovich forms, is introduced. It is shown that the new presentation is more appropriate for the…
In thermodynamics a macroscopic state of a system results from a number of its microscopic states. This number is given by the exponent of the system's entropy $\exp(S)$. In non-interacting systems with discrete energy spectra, such as…
The proper definition of entropy is fundamental to the relationship between statistical mechanics and thermodynamics. It also plays a major role in the recent debate about the validity of the concept of negative temperature. In this paper,…
A thermodynamic-like formalism is developed for superstatistical systems based on conditional entropies. This theory takes into account large-scale variations of intensive variables of systems in nonequilibrium stationary states. Ordinary…
We prove an adiabatic theorem that applies at timescales short of the typical adiabatic limit. Our proof analyzes the stability of solutions to Schrodinger's equation under perturbation. We directly characterize cross-subspace effects of…
The inference of thermodynamic quantities from the description of an only partially accessible physical system is a central challenge in stochastic thermodynamics. A common approach is coarse-graining, which maps the dynamics of such a…
Statistical thermodynamics is valuable as a conceptual structure that shapes our thinking about equilibrium thermodynamic states. A cloud of unresolved questions surrounding the foundations of the theory could lead an impartial observer to…
We show that macroscopic irreversible thermodynamics for viscous fluids can be derived from exact information-theoretic thermodynamic identities valid at the microscale. Entropy production, in particular, is a measure of the loss of…
We review the quantum adiabatic approximation for closed systems, and its recently introduced generalization to open systems (M.S. Sarandy and D.A. Lidar, e-print quant-ph/0404147). We also critically examine a recent argument claiming that…
When making the connection between the thermodynamics of irreversible processes and the theory of stochastic processes through the fluctuation-dissipation theorem, it is necessary to invoke a postulate of the Einstein-Boltzmann type. For…
We consider a small Hamiltonian system strongly interacting with a much larger Hamiltonian system (the bath), while being driven by both a time-dependent control parameter and non-conservative forces. The joint system is assumed to be…
The Boltzmann distribution for an equilibrium system constrains the statistics of the system by the energetics. Despite the non-equilibrium generalization of the Boltzmann distribution being studied extensively, a unified framework valid…
We review two definitions of temperature in statistical mechanics, $T_B$ and $T_G$, corresponding to two possible definitions of entropy, $S_B$ and $S_G$, known as surface and volume entropy respectively. We restrict our attention to a…
On a fine grained scale the Gibbs entropy of an isolated system remains constant throughout its dynamical evolution. This is a consequence of Liouville's theorem for Hamiltonian systems and appears to contradict the second law of…