Related papers: Regularized Boltzmann entropy determines macroscop…
We develop the framework of classical Observational entropy, which is a mathematically rigorous and precise framework for non-equilibrium thermodynamics, explicitly defined in terms of a set of observables. Observational entropy can be seen…
We consider an overdamped Brownian particle subject to an asymptotically flat potential with a trap of depth $U_0$ around the origin. When the temperature is small compared to the trap depth ($\xi=k_B T/U_0 \ll 1$), there exists a range of…
We consider a one-dimensional system consisting of two infinite ideal fluids, with equal pressures but different temperatures T_1 and T_2, separated by an adiabatic movable piston whose mass M is much larger than the mass m of the fluid…
By applying adiabatic theorem to a Markovian system, we calculate the adiabatic and diabatic entropy changes along a path. As well known, the total path entropy change is separated into two parts, system and environment entropy changes,…
Microscopic thermal machines promise to play an important role in future quantum technologies. Making such devices widely applicable will require effective strategies to channel their output into easily accessible storage systems like…
The issue of the thermodynamics of a system of distinguishable particles is discussed in this paper. In constructing the statistical mechanics of distinguishable particles from the definition of Boltzmann entropy, it is found that the…
We revisit the Rayleigh--Riabouchinsky paradox in dimensional analysis by making explicit the bridge between thermodynamics and the mechanical interpretation of temperature. Boltzmann's constant $k_B$ acts as a dimensional unifier, leading…
A way to construct Boltzmann entropy, i.e., the entropy as a function of a microscopic pure state, for quantum field systems is proposed. Operators that shift the field in wavevector space are used in the construction. By employing an…
We generalize the usual exponential Boltzmann factor to any reasonable and potentially observable distribution function, $B(E)$. By defining generalized logarithms $\Lambda$ as inverses of these distribution functions, we are led to a…
A question that is currently highly debated is whether the microcanonical entropy should be expressed as the logarithm of the phase volume (volume entropy, also known as the Gibbs entropy) or as the logarithm of the density of states…
In systems with detailed balance, the stationary distribution and the equilibrium distribution are identical, creating a clear connection between energetic and entropic quantities. Many driven systems violate detailed balance and still pose…
The thermodynamical one-loop entropy $S^{TD}$ of a two-dimensional black hole in thermal equilibrium with the massless quantum gas is calculated. It is shown that $S^{TD}$ includes the Bekenstein-Hawking entropy, evaluated for the quantum…
Boltzmann introduced in the 1870's a logarithmic measure for the connection between the thermodynamical entropy and the probabilities of the microscopic configurations of the system. His entropic functional for classical systems was…
Boltzmann's principle S=k ln W allows to extend equilibrium thermo-statistics to ``Small'' systems without invoking the thermodynamic limit. The clue is to base statistical probability on ensemble averaging and not on time averaging. It is…
Thermodynamics makes definite predictions about the thermal behavior of macroscopic systems in and out of equilibrium. Statistical mechanics aims to derive this behavior from the dynamics and statistics of the atoms and molecules making up…
A general formulation of stochastic thermodynamics is presented for open systems exchanging energy and particles with multiple reservoirs. By introducing a partition in terms of "macrostates" (e.g. sets of "microstates"), the consequence on…
Ergodicity, this is to say, dynamics whose time averages coincide with ensemble averages, naturally leads to Boltzmann-Gibbs (BG) statistical mechanics, hence to standard thermodynamics. This formalism has been at the basis of an enormous…
The operation of near-term quantum technologies requires the development of feasible, implementable, and robust strategies of controlling complex many body systems. To this end, a variety of techniques, so-called "shortcuts to adiabaticty",…
Despite well over a century of effort, the proper expression for the classical entropy in statistical mechanics remains a subject of debate. The Boltzmann entropy (calculated from a surface in phase space) has been criticized as not being…
Thermodynamic macro variables, such as the temperature or volume macro variable, can take on a continuum of allowable values, called thermodynamic macro values. Although referring to the same macro phenomena, the macro variables of…