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A new two-dimensional (2D) material, borophene (2D boron sheet), has been grown successfully recently on single crystal Ag substrates by two parallel experiments [Mannix \textit{et al., Science}, 2015, \textbf{350}, 1513] [Feng \textit{et…

Materials Science · Physics 2017-03-22 Bo Peng , Hao Zhang , Hezhu Shao , Zeyu Ning , Yuanfeng Xu , Hongliang Lu , David Wei Zhang , Heyuan Zhu

The atomic structure of icosahedral B$_4$C boron carbide is determined by comparing existing infra-red absorption and Raman diffusion measurements with the predictions of accurate {\it ab initio} lattice-dynamical calculations performed for…

Materials Science · Physics 2009-10-31 R. Lazzari , N. Vast , J. M. Besson , S. Baroni , A. Dal Corso

Noting the structural relationships between phases of carbon and boron carbide with phases of boron nitride and boron subnitride, we investigate their mutual solubilities using a combination of first principles total energies supplemented…

Materials Science · Physics 2016-04-13 Hantao Zhang , Sanxi Yao , Michael Widom

The configurations, stability and electronic structures of a new class of boron sheet and related boron nanotubes are predicted within the framework of density functional theory. This boron sheet is sparser than those of recent proposals.…

Materials Science · Physics 2011-04-28 Jing Wang , Ying Liu , You-Cheng Li

A systematic study of the structural, electronic, and optical properties of cage-like boron clusters, with the number of constituent atoms ranging from 20 to 122, has been carried out within the framework of density-functional theory (DFT),…

Materials Science · Physics 2025-12-24 Kashinath T. Chavan , Ihsan Boustani , Alok Shukla

Two-dimensional and layered materials, such as graphene, have emerged in recent years for their potential use in several applications in technology, for example in electronics, bioelectronics, optoelectronics and related fields.…

Materials Science · Physics 2020-07-10 Francesco Mercuri

Borophene, the boron atom analogue to graphene, being atomic thick have been just recently experimentally fabricated. In this work, we employ first-principles density functional theory calculations to investigate the interaction of Ca, Mg,…

Materials Science · Physics 2017-04-17 B Mortazavi , A Dianat , O Rahaman , G Cuniberti , T Rabczuk

Based on crystal chemistry rationale and calculations within the density functional theory DFT, the U:B system is complemented with additional binary compounds UB3, U2B6, and UB6 possessing two-dimensional 2D and 3D boron substructures.…

Materials Science · Physics 2020-02-18 Samir F. Matar

Investigation on oxidation resistance of two-dimensional (2D) materials is critical for many of their applications, because 2D materials could have higher oxidation kinetics than their bulk counterparts due to predominant surface atoms and…

Materials Science · Physics 2014-03-06 Lu Hua Li , Jiri Cervenka , Kenji Watanabe , Takashi Taniguchi , Ying Chen

By high-throughput calculations based on the density functional theory, we construct a structure map for AB$_2$ type monolayers of 3844 compounds which are all the combinations of 62 elements selected from the periodic table. The structure…

Materials Science · Physics 2019-04-15 Masahiro Fukuda , Jingning Zhang , Yung-Ting Lee , Taisuke Ozaki

Hexagonal boron nitride (h-BN) is a two dimensional (2D) layered insulator with superior dielectric performance that offers excellent interaction with other 2D materials (e.g. graphene, MoS2). Large-area h-BN can be readily grown on…

Two-dimensional (2D) crystals, such as graphene, hexagonal boron nitride and transitional metal dichalcogenides, have attracted tremendous amount of attention over the past decade due to their extraordinary thermal, electrical and optical…

Materials Science · Physics 2017-02-16 Y. Zhao , Z. Wan , U. Hetmaniuk , M. P. Anantram

Borophene, a monoatomic layer of boron atoms, stands out among two-dimensional (2D) materials, with its versatile properties of polymorphism, metallicity, plasmonics, superconductivity, tantalizing for physics exploration and…

Materials Science · Physics 2021-11-25 Qiyuan Ruan , Luqing Wang , Ksenia V. Bets , Boris I. Yakobson

Since the rising of graphene, boron nitride monolayers have been deeply studied due to their structural similarity with the former. A hexagonal graphene-like boron-carbon-nitrogen (h-BCN) monolayer was synthesized recently using bis-BN…

Elementary semiconductors are rare and attractive, especially for low-dimensional materials. Unfortunately, most of boron nanostructures were found to be metallic, despite of their typical semiconducting bulk structure. Herein, we propose a…

Mesoscale and Nanoscale Physics · Physics 2018-11-01 Shao-Gang Xu , Xiao-Tian Li , Yu-Jun Zhao , Wang-Ping Xu , Ji-Hai Liao , Xiu-Wen Zhang , Hu Xu , Xiao-Bao Yang

The structural and electronic properties of the doubly calcium-doped boron cluster B$_{18}$Ca$_2$ have been systematically investigated using density functional theory calculations. Basin-hopping searches reveal that B$_{18}$Ca$_2$ adopts a…

Materials Science · Physics 2026-01-06 P. L. Rodríguez-Kessler

Two-dimensional (2D) materials as electrodes is believed to be the trend for future Li-ion and Na-ion batteries technologies. Here, by using first-principles methods, we predict that the recently reported borophene (2D born sheet) can serve…

Mesoscale and Nanoscale Physics · Physics 2016-10-19 Xiaoming Zhang , Junping Hu , Yingchun Cheng , Hui Ying Yang , Yugui Yao , Shengyuan A. Yang

Recent discoveries of supposedly pure alpha-tetragonal boron require to revisit its structure. The system is also interesting with respect to a new type of geometrical frustration in elemental crystals, which was found in beta-rhombohedral…

Materials Science · Physics 2016-03-23 Naoki Uemura , Koun Shirai , Hagen Eckert , Jens Kunstmann

The doping of graphene to tune its electronic structure is essential for its further use in carbon based electronics. Adapting strategies from classical silicon based semiconductor technology, we use the incorporation of heteroatoms in the…

Systematic ab initio structure prediction was applied for the first time to predict low energy surface reconstructions by employing the minima hopping method on the \alpha-boron (111) surface. Novel reconstruction geometries were identified…

Materials Science · Physics 2013-10-02 Maximilian Amsler , Silvana Botti , Miguel A. L. Marques , Stefan Goedecker