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Two different types of boron-doped graphene/copper interfaces synthesized using two different flow rates of Ar through the bubbler containing the boron source were studied. X-ray photoelectron spectra (XPS) and optically stimulated electron…

Boron carbonitride (BxCyNz) represents an interesting family of materials containing all light elements and two dimensional graphene like hybrid layers. Although rich literature exists on this peculiar material in chemically processed form,…

Modification of graphene to open a robust gap in its electronic spectrum is essential for its use in field effect transistors and photochemistry applications. Inspired by recent experimental success in the preparation of homogeneous alloys…

Materials Science · Physics 2015-04-21 Sharmila N. Shirodkar , Umesh V. Waghmare , Timothy S. Fisher , Ricardo Grau-Crespo

We investigate the symmetry of the boron buckyball and a related boron nanotube. Using large-scale ab-initio calculations up to second-order M{\o}ller Plesset perturbation theory, we have determined unambiguously the equilibrium…

Materials Science · Physics 2015-05-14 N. Gonzalez Szwacki , C. J. Tymczak

In the present paper, we investigate the structural, thermodynamic, dynamic, elastic, and electronic properties of doped 2D diamond C$_4$X$_2$ (X = B or N) nanosheets in both AA$'$A$''$ and ABC stacking configurations, by first-principles…

Materials Science · Physics 2024-01-10 Bruno Ipaves , João F. Justo , Biplab Sanyal , Lucy V. C. Assali

Boron nitride (BN) is an exceptional material and among its polymorphs, two-dimensional (2D) hexagonal and three-dimensional (3D) cubic BN (h-BN and c-BN) phases are most common. The phase stability regimes of these BN phases are still…

Carbon has numerous one-dimensional (1D), two-dimensional (2D), and three-dimensional (3D) allotropic structures. The study of carbon materials has been a major focus of material science and condensed matter physics. Previous studies have…

Materials Science · Physics 2020-06-11 Yuanping Chen , Yuee Xie , Xiaohong Yan , Marvin L. Cohen , Shengbai Zhang

In this work, we explore the structure of single-wall boron nanotubes with large diameters (about 21~{\AA}) and a broad range of surface densities of atoms. The computations are done using an evolutionary approach combined with a nearest…

Mesoscale and Nanoscale Physics · Physics 2022-12-06 Tomasz Tarkowski , Nevill Gonzalez Szwacki

Phosphorene, the monolayer form of the (black) phosphorus, was recently exfoliated from its bulk counterpart. Phosphorene oxide, by analogy to graphene oxide, is expected to have novel chemical and electronic properties, and may provide an…

Materials Science · Physics 2015-06-22 Gaoxue Wang , Ravindra Pandey , Shashi P. Karna

We present an ab-initio study of boron nitride as well as carbon allotropes. Their relative thermodynamic stabilities and structural phase transitions from low- to high-density phases are investigated. Pressure-temperature phase diagrams…

Materials Science · Physics 2019-02-22 Thomas Gruber , Andreas Grüneis

Boron carbide, a lightweight, high temperature material, has various applications as a structural material and as a neutron absorber. The large solubility range of carbon in boron, between $\approx$ 9% and 20%, stems from the…

Materials Science · Physics 2021-06-09 Guido Roma , Kevin Gillet , Antoine Jay , Nathalie Vast , Gaëlle Gutierrez

2D ferroelectrics with robust polarization down to atomic thicknesses provide novel building blocks for functional heterostructures. Experimental reports, however, remain scarce because of the requirement of a layered polar crystal. Here,…

Mesoscale and Nanoscale Physics · Physics 2021-06-04 Kenji Yasuda , Xirui Wang , Kenji Watanabe , Takashi Taniguchi , Pablo Jarillo-Herrero

Hexagonal boron nitride (BN) is widely used as a substrate and gate insulator for two-dimensional (2D) electronic devices. The studies on insulating properties and electrical reliability of BN itself, however, are quite limited. Here, we…

Materials Science · Physics 2015-10-08 Y. Hattori , K. Watanabe , T. Taniguchi , K. Nagashio

Graphite and hexagonal boron nitride (h-BN) are two prominent members of the family of layered materials possessing a hexagonal lattice. While graphite has non-polar homo-nuclear C-C intra-layer bonds, h-BN presents highly polar B-N bonds…

Materials Science · Physics 2012-04-16 Oded Hod

The recent discovery of pure boron nanotubes raises questions about their detailed atomic structure. Previous simulations predicted tubular structures with smooth or puckered surfaces. Here, we present some novel results based on ab initio…

Materials Science · Physics 2007-05-23 Jens Kunstmann , Alexander Quandt

Carbon's versatility allows it to form diverse structures with unique properties, driven by its moderate electronegativity, small ionic radius, and ability to adopt \textit{sp}, \textit{sp\textsuperscript{2}}, and…

Designing new 2D systems with tunable properties is an important subject for science and technology. Starting from graphene, we developed an algorithm to systematically generate 2D carbon crystals belonging to the family of graphdiynes…

Materials Science · Physics 2021-03-25 Patrick Serafini , Alberto Milani , Davide M. Proserpio , Carlo S. Casari

In this work, we have studied the chemical and magnetic interactions of Fe_n; n <= 6, clusters with a divacancy site in a graphene sheet by ab-initio density functional calculations. Our results show significant chemical interactions…

Mesoscale and Nanoscale Physics · Physics 2010-06-11 Bhalchandra S. Pujari , Dilip G. Kanhere , Biplab Sanyal

Currently, solid interfaces composed of two-dimensional materials (2D) in contact with metal surfaces (m-surf) have been the subject of intense research, where the borophene bilayer (BBL) has been considered a prominent material for the…

Materials Science · Physics 2023-11-21 Wanderlã L. Scopel , F. Crasto de Lima , Pedro H. Souza , José E. Padilha , Roberto H. Miwa

Molecular-crystalline duality of graphene ensures a tight alliance of its physical and chemical natures, each of which is unique in its own way. The paper examines the physical-chemical harmony and/or confrontation in terms of the molecular…

Mesoscale and Nanoscale Physics · Physics 2013-12-05 Elena F. Sheka
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