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We investigate the equilibrium geometries and the systematics of bonding in various isomers of a 24-atom boron cluster using Born-Oppenheimer molecular dynamics within the framework of density functional theory. The isomers studied are the…

Atomic and Molecular Clusters · Physics 2009-11-10 S. Chacko , D. G. Kanhere , I. Boustani

We study the mechanical properties of two-dimensional (2D) boron, borophenes, by first-principles calculations. The recently synthesized borophene with 1/6 concentration of hollow hexagons (HH) is shown to have in-plane modulus C up to 210…

Materials Science · Physics 2017-01-12 Zhuhua Zhang , Yang Yang , Evgeni S. Penev , Boris I. Yakobson

We predict a two-dimensional (2D) antiferromagnetic (AFM) boron (designated as M-boron) by using ab initio evolutionary methodology. M-boron is entirely composed of B20 clusters in a hexagonal arrangement. Most strikingly, the highest…

Common two-dimensional (2D) materials have a layered 3D structure with covalently bonded, atomically thin layers held together by weak van der Waals forces. However, in a recent transmission electron microscopy experiment, atomically thin…

Mesoscale and Nanoscale Physics · Physics 2018-02-07 Janne Nevalaita , Pekka Koskinen

Engineering atomic-scale structures allows great manipulation of physical properties and chemical processes for advanced technology. We show that the B atoms deployed at the centers of honeycombs in boron sheets, borophene, behave as nearly…

Among exciting recent advances in the field of two-dimensional (2D) materials, the successful fabrications of the C60 fullerene networks has been a particularly inspiring accomplishment. Motivated by the recent achievements, herein we…

Materials Science · Physics 2023-08-11 Bohayra Mortazavi , Yves Remond , Hongyuan Fang , Timon Rabczuk , Xiaoying Zhuang

We present a comprehensive first-principles investigation of boron fullerenes and two-dimensional boron sheets, unified under a coordination-based framework. By classifying over a dozen boron nanostructures, including B$_{12}$, B$_{40}$,…

Materials Science · Physics 2025-07-10 Nevill Gonzalez Szwacki

The effect of external static charging on borophenes - 2D boron crystals - is investigated by using first principles calculations. The influence of the excess negative charge on the stability of the 2D structures is examined using a very…

Materials Science · Physics 2021-09-21 T. Tarkowski , J. A. Majewski , N. Gonzalez Szwacki

Two-dimensional boron monolayer (borophene) stands out from the two-dimensional atomic layered materials due to its structural flexibility, tunable electronic and mechanical properties from a large number of allotropic materials. The…

Materials Science · Physics 2022-05-31 Yuchong Kang , Xiaoyun Ma , Jing Fu , Kun Yang , Zongguo Wang , Haibo Li , Wei Ma , Jin Zhang

Large-area single-crystal surface structures were successfully prepared on Cu(111) substrate with boron deposition, which is critical for prospective applications. However, the proposed borophene structures do not match the scanning…

Materials Science · Physics 2022-11-22 Xiao-Ji Weng , Jie Bai , Jingyu Hou , Yi Zhu , Li Wang , Penghui Li , Anmin Nie , Bo Xu , Xiang-Feng Zhou , Yongjun Tian

We simulate boron on Pb(110) surface by using ab initio evolutionary methodology. Interestingly, the two-dimensional (2D) Dirac Pmmn boron can be formed because of good lattice matching. Unexpectedly, by increasing the thickness of 2D…

Two-dimensional systems have strengthened their position as one of the key materials for novel applications. Very recently, boron joined the distinguished group of elements that are confirmed to possess 2D allotropes, named borophenes. In…

Materials Science · Physics 2021-09-21 N. Gonzalez Szwacki

The search of new superhard materials has received a strong impulse by industrial demands for low-cost alternatives to diamond and $c$-BN, such as metal borides. In this Letter we introduce a new family of superhard materials, "fused…

Materials Science · Physics 2021-08-18 Santanu Saha , Wolfgang von der Linden , Lilia Boeri

We adopt a global optimization method to predict two-dimensional (2D) nanostructures through the particle-swarm optimization (PSO) algorithm. By performing PSO simulations, we predict new stable structures of 2D boron-carbon (B-C) compounds…

Materials Science · Physics 2011-12-30 Xinyu Luo , Jihui Yang , Hanyu Liu , Xiaojun Wu , Yanchao Wang , Yanming Ma , Su-Huai Wei , Xingao Gong , Hongjun Xiang

Fabrication of ordered structures at the nanoscale limit poses a cornerstone challenge for modern technologies. In this work we show how naturally occurring moir\'e patterns in Ir(111)-supported graphene template the formation of 2D ordered…

In this work, we employ density functional theory (DFT) to explore the structure of boron clusters doped with two chromium atoms (B$_7$Cr$_2$). The results show that the most stable structure is a bipyramidal configuration formed by a B$_7$…

Materials Science · Physics 2024-07-31 P. L. Rodríguez-Kessler

The icosahedra boron chain and three icosahedra sheets (with {\alpha}, {\delta}4, and {\delta}6 symmetries), constructed by the icosahedra B12, have been obtained as new members of boron family using a highly efficient molecular dynamics…

Materials Science · Physics 2014-09-29 C. B. Kah , M. Yu , P. Tandy , C. S. Jayanthi , S. Y. Wu

We report free-standing atomic crystals that are strictly 2D and can be viewed as individual atomic planes pulled out of bulk crystals or as unrolled single-wall nanotubes. By using micromechanical cleavage, we have prepared and studied a…

Materials Science · Physics 2007-05-23 K. S. Novoselov , D. Jiang , T. Booth , V. V. Khotkevich , S. M. Morozov , A. K. Geim

Graphene has received a great deal of attention and this has more recently extended to boron nitride sheets (BNS) with a similar structure. Both have hexagonal lattices and it is only the alternation of atoms in boron nitride, which changes…

Chemical Physics · Physics 2016-02-23 A. F. Jalbout , T. H. Seligman

The recent discovery of graphene has sparked significant interest, which has so far been focused on the peculiar electronic structure of this material, in which charge carriers mimic massless relativistic particle. However, the structure of…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Jannik C. Meyer , A. K. Geim , M. I. Katsnelson , K. S. Novoselov , T. J. Booth , S. Roth