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We investigate the interplay of quantum interference effects and electronic-vibrational coupling in electron transport through single-molecule junctions, employing a nonequilibrium Green's function approach. Our findings show that inelastic…

Mesoscale and Nanoscale Physics · Physics 2013-02-18 R. Härtle , M. Butzin , M. Thoss

Understanding current-induced bond rupture in single-molecule junctions is both of fundamental interest and a prerequisite for the design of molecular junctions, which are stable at higher bias voltages. In this work, we use a fully quantum…

Mesoscale and Nanoscale Physics · Physics 2021-06-30 Yaling Ke , André Erpenbeck , Uri Peskin , Michael Thoss

Understanding and controlling the flow of heat is a major challenge in nanoelectronics. When a junction is driven out of equilibrium by light or the flow of electric charge, the vibrational and electronic degrees of freedom are, in general,…

Mesoscale and Nanoscale Physics · Physics 2011-06-29 Daniel R. Ward , David A. Corley , James M. Tour , Douglas Natelson

Some of us have recently reported in Science 321 232 (2008) vibrational cooling of translationally cold Cs_2 molecules into the lowest vibrational level v=0 of the singlet X 1Sigma_g ground electronic state. Starting from a sample of cold…

In this article we study the frictionless cooling of atoms trapped in a harmonic potential, while minimizing the transient energy of the system. We show that in the case of unbounded control, this goal is achieved by a singular control,…

Optimization and Control · Mathematics 2014-01-17 Dionisis Stefanatos , Jr-Shin Li

We report a method using scanning tunnelling microscope single molecular break junction to simultaneously measure and correlate the single-molecule thermopower and electrical conductance. In contrast to previously reported approaches, it…

Mesoscale and Nanoscale Physics · Physics 2021-09-24 Joseph M. Hamill , Christopher Weaver , Tim Albrecht

We describe single electron tunneling through molecular structures under the influence of nano-mechanical excitations. We develop a full quantum mechanical model, which includes charging effects and dissipation, and apply it to the…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Daniel Boese , Herbert Schoeller

The vibrational dynamics of adsorbate molecules in single-molecule junctions depend critically on the geometric structure and electronic interactions between molecule and substrate. Vibrations, excited mechanochemically or by external…

Mesoscale and Nanoscale Physics · Physics 2025-09-17 Lukas Hörmann , Reinhard J. Maurer

The thermoelectric transport through a molecular bridge is discussed, with an emphasis on the effects of inelastic processes of the transport electrons caused by the coupling to the vibrational modes of the molecule. In particular it is…

Mesoscale and Nanoscale Physics · Physics 2015-03-17 O. Entin-Wohlman , Y. Imry , A. Aharony

We present an original method to estimate the conductivity of a single molecule anchored to nanometric-sized metallic electrodes, using a Mechanically Controlled Break Junction (MCBJ) operated at room temperature in liquid. We record the…

Mesoscale and Nanoscale Physics · Physics 2018-03-16 M. Gil , T. Malinowski , M. Iazykov , H. Klein

We review studies of vibrational energy transfer in a molecular junction geometry, consisting of a molecule bridging two heat reservoirs, solids or large chemical compounds. This setup is of interest for applications in molecular…

Mesoscale and Nanoscale Physics · Physics 2016-06-22 Dvira Segal , Bijay Kumar Agarwalla

Molecular electronics is a fascinating area of research with the ability to tune device properties by a chemical tailoring of organic molecules. However, molecular electronics devices often suffer from dispersion and lack of reproducibility…

Mesoscale and Nanoscale Physics · Physics 2013-02-11 Nicolas Clement , David Guerin , Stephane Pleutin , Sylvie Godey , Dominique Vuillaume

We discuss the electronic transport through molecules in the Kondo regime. We concentrate here on the influence of molecular vibrations. Two types of vibrations are investigated: (i) the breathing internal molecular modes, where the…

Mesoscale and Nanoscale Physics · Physics 2009-12-21 J. Mravlje , A. Ramsak

Molecular spintronics is made possible by the coupling between electronic configuration and magnetic po- larization of the molecules. For control and application of the individual molecular states it is necessary to both read and write…

Mesoscale and Nanoscale Physics · Physics 2016-04-27 T. Saygun , J. Bylin , H. Hammar , J. Fransson

Exploring the use of individual molecules as active components in electronic devices has been at the forefront of nanoelectronics research in recent years. Compared to semiconductor microelectronics, modeling transport in single-molecule…

Mesoscale and Nanoscale Physics · Physics 2015-06-24 Yongqiang Xue , Mark A. Ratner

Cooling a range of molecules to ultracold temperatures (<1 mK) is a difficult but important challenge in molecular physics and chemistry. Collective cavity cooling of molecules is a promising method that does not rely on molecular energy…

Atomic Physics · Physics 2012-05-11 Guangjiong Dong , Chang Wang , Weiping Zhang

Cooling atoms to ultralow temperatures has produced a wealth of opportunities in fundamental physics, precision metrology, and quantum science. The more recent application of sophisticated cooling techniques to molecules, which has been…

Atomic Physics · Physics 2017-09-21 John L Bohn , Ana Maria Rey , Jun Ye

Ultracold molecular gases are promising as an avenue to rich many-body physics, quantum chemistry, quantum information, and precision measurements. This richness, which flows from the complex internal structure of molecules, makes the…

Atomic Physics · Physics 2015-06-18 A. M. Jayich , A. C. Vutha , M. T. Hummon , J. V. Porto , W. C. Campbell

We present a theoretical analysis of heat transport through a single-molecule junction with two possible transport channels for electrons where interactions between electrons on the molecule and phonons in the nuclear environment is strong…

Mesoscale and Nanoscale Physics · Physics 2023-07-13 Natalya A. Zimbovskaya

Physical arguments and comparisons with published experimental data suggest that in simple liquids: i) single-molecule-scale viscous forces are produced by temperature-dependent London dispersion forces, ii) viscosity decay with increasing…

Fluid Dynamics · Physics 2020-10-09 Russell G. Keanini , Jerry Dahlberg , Peter T. Tkacik