Related papers: Rotational cooling of trapped polyatomic molecules
We introduce, analyze, and compare two novel methods of Single Photon Cooling that generically cool and compress molecular gases. The first method compresses the molecular gas density by three orders of magnitude and increases collision…
We propose a method of stimulated laser cooling of diatomic molecules by counter-propagating $\pi$-trains of ultrashort laser pulses. The cooling cycles occur on the rovibrational transitions inside the same ground electronic manifold, thus…
Current dual-frequency magneto-optical traps for ultracold molecules are plagued by sub-Doppler heating effects, making them vastly inferior to standard atomic MOTs. Here we demonstrate theoretically that the sub-Doppler effects in such a…
In red-detuned magneto-optical traps (MOTs) of molecules, sub-Doppler heating competes with Doppler cooling, resulting in high temperature and low density. A solution is offered by the blue-detuned MOT where sub-Doppler cooling dominates…
We report laser cooling and trapping of yttrium monoxide (YO) molecules in an optical lattice. We show that gray molasses cooling remains exceptionally efficient for YO molecules inside the lattice with a molecule temperature as low as…
We model sympathetic cooling of ground-state CaF molecules by ultracold Li and Rb atoms. The molecules are moving in a microwave trap, while the atoms are trapped magnetically. We calculate the differential elastic cross sections for CaF-Li…
Librational motion, whereby a rigid body undergoes angular oscillation around a preferred direction, can be observed in optically trapped, silica microspheres. We demonstrate the cooling of one librational degree of freedom for $\sim…
Polar molecules in selected quantum states can be guided, decelerated, and trapped using electric fields created by microstructured electrodes on a chip. Here we explore how transitions between two of these quantum states can be induced…
We propose a general technique to produce cold spin-polarized molecules, in which rotationally excited states are first populated by coherent microwave excitation, and then allowed to spin-flip and relax via collisional quenching, which…
Relatively little is known about the dynamics of electron transfer reactions at low collision energy. We present a study of Penning ionization of ground state methyl fluoride molecules by electronically excited neon atoms in the 13…
The thermal conductivity of solid SF6, CHCI3, C6H6, and CCl4 was investigated by the linear-flow method under saturated vapor pressures in the temperature range from 80 K to the corresponding melting temperatures and then recalculated for a…
The effect of substituting a hydrogen atom by a chlorine atom or a methyl group by a trichloromethyl (CCl3) group at the stereogenic center of light-driven second generation molecular motors is calculated in order to assess the effect on…
We propose a simple microscopic model of molecular dynamics simulation to study orientational glass in three dimensions. We present simulation results for mixtures of mildly anisotropic particles and spherical impurities. We realize fcc…
Using frequency-chirped radiation pressure slowing, we precisely control the velocity of a pulsed CaF molecular beam down to a few m/s, compressing its velocity spread by a factor of 10 while retaining high intensity: at a velocity of…
Recent work with laser-cooled molecules in attractive optical traps has shown that the differential AC Stark shifts arising from the trap light itself can become problematic, limiting collisional shielding efficiencies, rotational coherence…
We study theoretically the behavior of laser-cooled calcium monofluoride (CaF) molecules in an optical molasses and magneto-optical trap (MOT), and compare our results to recent experiments. We use multi-level optical Bloch equations to…
For laser cooling considerations, we have theoretically investigated the electronic, rovibrational and hypefine structures of BaF molecule. The highly diagonal Franck-Condon factors and the branching ratios for all possible transitions…
It has been roughly three decades since laser cooling techniques produced ultracold atoms, leading to rapid advances in a vast array of fields. Unfortunately laser cooling has not yet been extended to molecules because of their complex…
Ultracold polar molecules offer strong electric dipole moments and rich internal structure, which makes them ideal building blocks to explore exotic quantum matter, implement novel quantum information schemes, or test fundamental symmetries…
Direct laser cooling of molecules has reached a phase space density exceeding 10$^{-6}$ in optical traps, but with rather small molecular numbers. To progress towards quantum degeneracy, a mechanism is needed that combines sub-Doppler…