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Ligand coated nanoparticles are complex objects consisting of a metallic or semiconductor core with organic ligands grafted on their surface. These organic ligands provide stability to a nanoparticle suspension. In solutions, the effective…

Soft Condensed Matter · Physics 2022-03-01 Dinesh Chintha , Shivanand Kumar Veesam , Emanuele Boattini , Laura Filion , Sudeep N Punnathanam

Nonreciprocal effective interaction forces can occur between mesoscopic particles in colloidal suspensions that are driven out of equilibrium. These forces violate Newton's third law actio=reactio on coarse-grained length and time scales.…

Soft Condensed Matter · Physics 2016-01-20 Jörg Bartnick , Marco Heinen , Alexei V Ivlev , Hartmut Löwen

A theoretical scheme for the calculation of the full phase diagram (including cloud and shadow curves, binodals and distribution functions of the coexisting phases) for colloid-polymer mixtures with polymer chain length polydispersity and…

Soft Condensed Matter · Physics 2009-11-13 Y. V. Kalyuzhnyi , P. T. Cummings

The analytical solution of the recently proposed ideal chain polymer mean-spherical approximation (Yu.Kalyuzhnyi, Mol.Phys., 94, 735(1998)) is presented for the multicomponent mixture of charged hard-sphere linear chain flexible molecules.…

Condensed Matter · Physics 2009-11-07 Yu. V. Kalyuzhnyi , P. T. Cummings

The mechanical properties of aggregated colloids depend on the mutual interplay of inter-particle potentials, contact forces, aggregate structure and material properties of the bare particles. Owing to this variety of influences…

Soft Condensed Matter · Physics 2012-05-15 Marcel Roth , Carsten Schilde , Philipp Lellig , Arno Kwade , Günter K. Auernhammer

A simulation model is presented, comprising elastic spheres with a short range attraction. Besides conservative forces, radial- and shear friction, and radial noise are added. The model can be used to simulate colloids, granular solids and…

Soft Condensed Matter · Physics 2008-11-19 Robert D. Groot , Simeon D. Stoyanov

Within mean-field theory we determine the universal scaling function for the effective force acting on a single colloid located near the interface between two coexisting liquid phases of a binary liquid mixture close to its critical…

Soft Condensed Matter · Physics 2015-06-22 Adam D. Law , Ludger Harnau , Matthias Troendle , Siegfried Dietrich

We consider the problem of inserting a stiff chain into a colloidal suspension of particles that interact with it through excluded volume forces. The free energy of insertion is associated with the work of creating a cavity devoid of…

Soft Condensed Matter · Physics 2009-11-10 M. Castelnovo , R. K. Bowles , H. Reiss , W. M. Gelbart

The paper presents a short overview of the theoretical, numerical and experimental works on the critical behavior of a dilute polymer solution of long-flexible polymer chains confined in semi-infinite space restricted by a surface or in a…

Soft Condensed Matter · Physics 2018-01-08 Zoryana Usatenko , Krzysztof S. Danel

While the excess chemical potential is the key quantity in determining phase diagrams, its direct computation for high-density liquids of long polymer chains has posed a significant challenge. Computationally, the excess chemical potential…

Soft Condensed Matter · Physics 2023-11-30 Mohammadhasan Dinpajooh , Jonathan Millis , James Donley , Marina G. Guenza

In this paper we study the shape characteristics of a polymer chain in a good solvent using a mesoscopic level of modelling. The dissipative particle dynamics simulations are performed in the $3D$ space at a range of chain lengths $N$. The…

Soft Condensed Matter · Physics 2016-11-24 Ostap Kalyuzhnyi , Jaroslav Ilnytskyi , Yurij Holovatch , Christian von Ferber

The depletion interactions between two colloidal plates or between two colloidal spheres, induced by interacting polymers in a good solvent, are calculated theoretically and by computer simulations. A simple analytical theory is shown to be…

Soft Condensed Matter · Physics 2009-11-07 A. A. Louis , P. G. Bolhuis , E. J. Meijer , J. P. Hansen

We study the potential of mean force (PMF) between atomistic silica and gold nanoparticles in the vacuum by using molecular dynamics simulations. Such an investigation is devised in order to fully characterize the effective interactions…

Soft Condensed Matter · Physics 2018-03-08 Gianmarco Munaò , Andrea Correa , Antonio Pizzirusso , Giuseppe Milano

The settling of colloidal particles with short-ranged attractions is investigated via highly resolved immersed boundary simulations. At modest volume fractions, we show that inter-colloid attractions lead to clustering that reduces the…

Soft Condensed Matter · Physics 2018-03-29 Andrew M. Fiore , Gang Wang , James W. Swan

We present a novel simulation technique derived from Brownian cluster dynamics used so far to study the isotropic colloidal aggregation. It now implements the classical Kern-Frenkel potential to describe patchy interactions between…

Soft Condensed Matter · Physics 2015-06-19 Achutha Prabhu , Sujin B. Babu , Jorge S. Dolado , J. -C. Gimel

The design of complex materials and the formation of specific patterns often arise from the properties of the individual building blocks. In this respect, colloidal systems offer a unique opportunity because nowadays they can be synthesized…

Soft Condensed Matter · Physics 2022-03-01 Fabrizio Camerin , Emanuela Zaccarelli

We derive an analytical pair potential of mean force for Brownian molecules in the liquid-state. Our approach accounts for many-particle correlations of crowding particles of the liquid, and for diffusive transport across the spatially…

Soft Condensed Matter · Physics 2012-06-21 Alessio Zaccone , Eugene M. Terentjev

We study theoretically and experimentally the solvent-mediated critical Casimir force acting on colloidal particles immersed in a binary liquid mixture of water and 2,6-lutidine and close to substrates which are chemically patterned with…

Effective interactions between charged particles dispersed in an electrolyte are most commonly modeled using the Derjaguin-Landau-Verwey-Overbeek (DLVO) potential, where the ions in the suspension are coarse-grained out at mean-field level.…

Soft Condensed Matter · Physics 2025-10-23 Thijs ter Rele , Gerardo Campos-Villalobos , René van Roij , Marjolein Dijkstra

The surface tension of interacting polymers in a good solvent is calculated theoretically and by computer simulations for a planar wall geometry and for the insertion of a single colloidal hard-sphere. This is achieved for the planar wall…

Soft Condensed Matter · Physics 2016-08-31 A. A. Louis , P. G. Bolhuis , E. J. Meijer , J. P. Hansen