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The growing interest in the dynamical properties of colloidal suspensions, both in equilibrium and under an external drive such as shear or pressure flow, requires the development of accurate methods to correctly include hydrodynamic…

Soft Condensed Matter · Physics 2019-11-11 José Ruiz-Franco , Diego Jaramillo-Cano , Manuel Camargo , Christos N. Likos , Emanuela Zaccarelli

Recently reported colloidal aggregation data obtained for different monovalent salts (NaCl, NaNO$_3$, and NaSCN) and at high electrolyte concentrations are matched with the stochastic solutions of the master equation to obtain bond average…

Soft Condensed Matter · Physics 2014-12-30 Gerardo Odriozola

A new method is presented for mesoscopic simulations of particle dispersions in liquid crystal solvents. It allows efficient first-principle simulations of the dispersions involving many particles with many-body interactions mediated by the…

Soft Condensed Matter · Physics 2015-06-24 Ryoichi Yamamoto , Yasuya Nakayama , Kang Kim

As an extension of the former study on 2-dimensional systems, we simulate phase behavior of polymer-grafted colloidal particles in 3 dimensions by molecular Monte Carlo technique in the canonical ensemble. We use a spherically symmetric…

Soft Condensed Matter · Physics 2014-04-02 Yuki Norizoe , Toshihiro Kawakatsu

We present a theoretical approach which maps polymer blends onto mixtures of soft-colloidal particles. The analytical mesoscale pair distribution functions reproduce well data from united atom molecular dynamics simulations of polyolefin…

Statistical Mechanics · Physics 2009-11-10 G. Yatsenko , E. J. Sambriski , M. G. Guenza

We present a theory of effective electrostatic interactions in polydisperse suspensions of charged macroions, generalizing to mixtures a theory previously developed for monodisperse suspensions. Combining linear response theory with a…

Soft Condensed Matter · Physics 2013-08-20 Jun Kyung Chung , Alan R. Denton

We review briefly the concept of colloidal dispersions, their general properties and some of their most important applications, as well as the basic molecular interactions that give rise to their properties in equilibrium. Similarly, we…

Soft Condensed Matter · Physics 2015-09-28 R. Lopez-Esparza , M. A. Balderas Altamirano , E. Pérez , A. Gama Goicochea

Colloidal dispersions are prized as model systems to understand basic properties of materials, and are central to a wide range of industries from cosmetics to foods to agrichemicals. Among the key developments in using colloids to address…

Soft Condensed Matter · Physics 2022-06-22 Jun Dong , Francesco Turci , Robert L. Jack , Malcolm A. Faers , C. Patrick Royall

The transport properties of colloidal particles in active liquids have been studied extensively. It has led to a deeper understanding of the interactions between passive and active particles. However, the phase behavior of colloidal…

Soft Condensed Matter · Physics 2023-01-30 Pragya Kushwaha , Vivek Semwal , Sayan Maity , Shraddha Mishra , Vijayakumar Chikkadi

Interparticle interactions and bulk properties of colloidal suspensions can be substantially modified by addition of nanoparticles. Extreme asymmetries in size and charge between colloidal particles and nanoparticles present severe…

Soft Condensed Matter · Physics 2018-01-03 Alan R. Denton

Percolation and critical phenomena show common features such as scaling and universality. Colloidal particles, immersed in a solvent close to criticality, experience long-range effective forces, named critical Casimir forces. %These…

Soft Condensed Matter · Physics 2014-07-16 Nicoletta Gnan , Emanuela Zaccarelli , Francesco Sciortino

We present Monte Carlo simulations of colloidal particles pulled into grafted polymer layers by external fields. The insertion free energy of a single colloid into the polymer layer is qualitatively different for surfaces with an ordered…

Soft Condensed Matter · Physics 2012-10-17 Tine Curk , Francisco J. Martinez-Veracoechea , Daan Frenkel , Jure Dobnikar

The association between polyelectrolytes (PEs) of the same size but opposite charge is systematically studied in terms of the potential of mean force (PMF) along their center-of-mass reaction coordinate via coarse-grained, implicit-solvent,…

Soft Condensed Matter · Physics 2017-06-05 Xiao Xu , Matej Kanduč , Jianzhong Wu , Joachim Dzubiella

We map dilute or semi-dilute solutions of non-intersecting polymer chains onto a fluid of ``soft'' particles interacting via a concentration dependent effective pair potential, by inverting the pair distribution function of the centers of…

Soft Condensed Matter · Physics 2009-10-31 A. A. Louis , P. G. Bolhuis , J. P. Hansen , E. J. Meijer

An effective pair potential for systems of uniformly charged lamellar colloids in the presence of an electrolytic solution of microscopic co- and counterions is derived. The charge distribution on the discs is expressed as a collection of…

Soft Condensed Matter · Physics 2009-10-31 D. G. Rowan , J. -P. Hansen , E. Trizac

We investigate effective interactions between a colloidal particle, immersed in a binary mixture of smaller spheres, and a semipermeable membrane. The colloid is modeled as a big hard sphere and the membrane is represented as an infinitely…

Soft Condensed Matter · Physics 2007-05-23 Pawel Bryk

In experimental systems, colloidal particles are virtually always at least somewhat polydisperse, which can have profound effects on their ability to crystallize. Unfortunately, accurately predicting the effects of polydispersity on phase…

Soft Condensed Matter · Physics 2025-10-09 Antoine Castagnède , Laura Filion , Frank Smallenburg

This article presents a new force model for performing quantitative simulations of dense granular materials. Interactions between multiple contacts (MC) on the same grain are explicitly taken into account. Our readily applicable method…

Soft Condensed Matter · Physics 2018-10-22 Nicolas Brodu , Joshua A. Dijksman , Robert P. Behringer

The possibility to induce demixing in a colloidal mixture by adding small polymers, or other equivalent depletant agents, is theoretically investigated. By use of Mean Field Theory, suitably generalized to deal with short range effective…

Soft Condensed Matter · Physics 2015-10-28 Alberto Parola , Luciano Reatto

Solutions of interacting linear polymers are mapped onto a system of ``soft'' spherical particles interacting via an effective pair potential. This coarse-graining reduces the individual monomer-level description to a problem involving only…

Soft Condensed Matter · Physics 2007-05-23 V. Krakoviack , J. P. Hansen , A. A. Louis