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Soft materials, such as colloidal suspensions, polymer solutions, and biological systems, are typically multicomponent mixtures of macromolecules and simpler components (e.g., microions, monomers, solvent) that can assemble into complex…

Soft Condensed Matter · Physics 2015-05-13 Alan R. Denton

We report a numerical investigation of two colloids immersed in a critical solvent, with the aim of quantifying the effective colloid-colloid interaction potential. By turning on an attraction between the colloid and the solvent particles…

Soft Condensed Matter · Physics 2012-09-12 Nicoletta Gnan , Emanuela Zaccarelli , Francesco Sciortino

The dynamics of colloidal particles in potential energy landscapes have mainly been investigated theoretically. In contrast, here we discuss the experimental realization of potential energy landscapes with the help of light fields and the…

We develop a computational method for modeling electrostatic interactions of arbitrarily-shaped, polarizable objects on colloidal length scales, including colloids/nanoparticles, polymers, and surfactants, dispersed in explicit ion…

Soft Condensed Matter · Physics 2024-06-18 Emily Krucker-Velasquez , James W. Swan , Zachary Sherman

We show how to coarse grain polymers in a good solvent as single particles, interacting with density-independent or density-dependent interactions. These interactions can be between the centres of mass, the mid-points or end-points of the…

Soft Condensed Matter · Physics 2009-11-07 A. A. Louis , P. G. Bolhuis , R. Finken , V. Krakoviack , E. J. Meijer , J. P. Hansen

We consider a theoretical model for a binary mixture of colloidal particles and spherical emulsion droplets. The hard sphere colloids interact via additional short-ranged attraction and long-ranged repulsion. The droplet-colloid interaction…

Soft Condensed Matter · Physics 2012-01-11 Ingmar Schwarz , Andrea Fortini , Claudia Simone Wagner , Alexander Wittemann , Matthias Schmidt

We study the critical Casimir interaction between two spherical colloids immersed in a binary liquid mixture close to its critical demixing point. The surface of each colloid prefers one species of the mixture with the exception of a…

Statistical Mechanics · Physics 2020-04-22 Nima Farahmand Bafi , Piotr Nowakowski , Siegfried Dietrich

A recent Letter [Phys. Rev. Lett. 103, 156101 (2009)] reports the experimental observation of aggregation of colloidal particles dispersed in a liquid mixture of heavy water and 3-methylpyridine. The experimental data are interpreted in…

Soft Condensed Matter · Physics 2010-10-05 Andrea Gambassi , S. Dietrich

The determination of potentials of mean force for solute insertion in a membrane by means of all-atom molecular dynamics simulations is often hampered by sampling issues. A multiscale approach to conformational sampling was recently…

Chemical Physics · Physics 2017-10-09 Roberto Menichetti , Kurt Kremer , Tristan Bereau

Interparticle interactions in charge-stabilized colloidal suspensions, of arbitrary salt concentration, are described at the level of effective interactions in an equivalent one-component system. Integrating out from the partition function…

Soft Condensed Matter · Physics 2009-10-31 A. R. Denton

We study phase separation and transient gelation in a mixture consisting of polydisperse colloids and non-adsorbing polymers, where the ratio of the average size of the polymer to that of the colloid is approximately 0.063. Unlike what has…

Soft Condensed Matter · Physics 2011-06-23 S. M. Liddle , T. Narayanan , W. C. K. Poon

This contribution briefly reviews some recent work demonstrating the partial breakdown of the colloidal fluid <--> atomic fluid analogy. The success of liquid state theory for atomic fluids stems in part from the van der Waals picture,…

Soft Condensed Matter · Physics 2009-11-07 A. A. Louis

The effective interaction between charged colloidal particles confined between two planar like-charged walls is investigated using computer simulations of the primitive model describing asymmetric electrolytes. In detail, we calculate the…

Soft Condensed Matter · Physics 2016-08-15 E. Allahyarov , I. D'Amico , H. Löwen

Colloidal droplets are used in a variety of practical applications. Some of these applications require particles of different sizes. These include medical diagnostic methods, the creation of photonic crystals, the formation of…

Soft Condensed Matter · Physics 2024-04-04 P. A. Zolotarev , K. S. Kolegov

Mesoscopic density functional theory for inhomogeneous mixtures of sperical particles is developed in terms of mesoscopic volume fractions by a systematic coarse-graining procedure starting form microscopic theory. Approximate expressions…

Soft Condensed Matter · Physics 2015-05-20 A. Ciach

Unlike atoms, colloidal particles are not identical, but can only be synthesised within a finite size tolerance. Colloids are therefore polydisperse, i.e. mixtures of infinitely many components with sizes drawn from a continuous…

Soft Condensed Matter · Physics 2009-11-07 R. M. L. Evans , C. B. Holmes

Colloidal particles hold promise for mobilizing and removing trapped immiscible fluids from porous media, with implications for key energy and water applications. Most studies focus on accomplishing this goal using particles that can…

Soft Condensed Matter · Physics 2022-06-07 Joanna Schneider , Rodney D. Priestley , Sujit S. Datta

Experimental studies of the variation of the mean square displacement (MSD) of a particle in a confined colloid suspension that exhibits density variations on the scale length of the particle diameter are not in agreement with the…

Soft Condensed Matter · Physics 2018-06-13 Molly Wolfson , Christopher Liepold , Binhua Lin , Stuart A. Rice

We propose a new coarse-grained model for the description of liquid-vapor phase separation of colloid-polymer mixtures. The hard-sphere repulsion between colloids and between colloids and polymers, which is used in the well-known…

Soft Condensed Matter · Physics 2009-11-13 Jochen Zausch , Peter Virnau , Kurt Binder , Juergen Horbach , Richard L. Vink

A coarse-graining strategy, previously developed for polymer solutions, is extended here to mixtures of linear polymers and hard-sphere colloids. In this approach groups of monomers are mapped onto a single pseudoatom (a blob) and the…

Soft Condensed Matter · Physics 2015-01-07 Giuseppe D'Adamo , Andrea Pelissetto , Carlo Pierleoni
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