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We investigate mixing effects on the glass state of binary colloidal hard-sphere-like mixtures with large size asymmetry, at a constant volume fraction phi = 0.61. The structure, dynamics and viscoelastic response as a function of mixing…

Soft Condensed Matter · Physics 2015-06-12 Tatjana Sentjabrskaja , Donald Guu , M Paul Lettinga , Stefan U Egelhaaf , Marco Laurati

We investigate the response of a system of hard spheres to two classes of perturbations over a range of densities spanning the fluid, crystalline, and glassy regimes within a molecular dynamics framework. Firstly, we consider the relaxation…

Statistical Mechanics · Physics 2025-09-04 Matthew Kafker , Xerxes D. Arsiwalla

In supercooled liquids, vitrification generally suppresses crystallization. Yet some glasses can still crystallize despite the arrest of diffusive motion. This ill-understood process may limit the stability of glasses, but its microscopic…

The evolution of porous structure and mechanical properties of binary glasses under tensile loading were examined using molecular dynamics simulations. We consider vitreous systems obtained in the process of phase separation after a rapid…

Soft Condensed Matter · Physics 2018-07-19 Nikolai V. Priezjev , Maxim A. Makeev

We report a detailed experimental study of the structure and dynamics of glassy states in hard spheres with short-range attraction. The system is a suspension of nearly-hard-sphere colloidal particles and non-adsorbing linear polymer which…

Soft Condensed Matter · Physics 2009-11-10 K. N. Pham , S. U. Egelhaaf , P. N. Pusey , W. C. K. Poon

A fascinating feature of metallic glasses is their ability to explore different configurations under mechanical deformations. This effect is usually observed through macroscopic observables, while little is known on the consequence of the…

Disordered Systems and Neural Networks · Physics 2023-01-09 A. Cornet , G. Garbarino , F. Zontone , Y. Chushkin , J. Jacobs , E. Pineda , T. Deschamps , S. Li , A. Ronca , J. Shen , G. Morard , N. Neuber , M. Frey , R. Busch , I. Gallino , M. Mezouar , G. Vaughan , B. Ruta

Lithium disilicate glasses and glass-ceramics are good potential candidates for biomedical applications and solid-state batteries, and serve as models of nucleation and crystal growth. Moreover, these glasses exhibit a phase separation that…

We study the dynamics of a one-dimensional fluid of orientable hard rectangles with a non-coarse-grained microscopic mechanism of facilitation. The length occupied by a rectangle depends on its orientation, which is coupled to an external…

Disordered Systems and Neural Networks · Physics 2011-12-09 Jeferson J. Arenzon , Deepak Dhar , Ronald Dickman

We show how dynamical heterogeneities in glass forming systems emerge as a consequence of the existence of dynamical constraints, and we offer an interpretation of the glass transition as an entropy crisis in trajectory space (space-time)…

Statistical Mechanics · Physics 2009-11-07 Juan P. Garrahan , David Chandler

Using numerical simulations, we study the failure of an amorphous solid under quasi-static expansion starting from a homogeneous high-density state. During the volume expansion, we demonstrate the existence of instabilities manifesting via…

Soft Condensed Matter · Physics 2023-03-10 Umang A. Dattani , Smarajit Karmakar , Pinaki Chaudhuri

Recently, progress has been made in the understanding of anomalous vibrational excitations in amorphous solids. In the lowest-frequency region, the vibrational spectrum follows a non-Debye quartic law, which persists up to zero frequency…

Disordered Systems and Neural Networks · Physics 2021-01-26 Masanari Shimada , Hideyuki Mizuno , Atsushi Ikeda

It has been recently shown [E. Lerner, G. D\"uring, and E. Bouchbinder, Phys. Rev. Lett. 117, 035501 (2016)] that the non-phononic vibrational modes of structural glasses at low-frequencies $\omega$ are quasi-localized and follow a…

Soft Condensed Matter · Physics 2018-04-03 Edan Lerner , Eran Bouchbinder

A wide range of materials can exist in microscopically disordered solid forms, referred to as amorphous solids or glasses. Such materials -- oxide glasses and metallic glasses, to polymer glasses, and soft solids such as colloidal glasses,…

Soft Condensed Matter · Physics 2021-08-20 Anshul D. S. Parmar , Srikanth Sastry

The universal anomalous vibrational and thermal properties of amorphous solids are believed to be related to the local variations of the elasticity. Recently it has been shown that the vibrational properties are sensitive to the glass's…

Soft Condensed Matter · Physics 2019-09-30 Alireza Shakerpoor , Elijah Flenner , Grzegorz Szamel

We study by molecular dynamics the interplay between arrest and crystallization in hard spheres. For state points in the plane of volume fraction ($0.54 \leq phi \leq 0.63$) and polydispersity ($0 \leq s \leq 0.085$), we delineate states…

Soft Condensed Matter · Physics 2009-10-21 E. Zaccarelli , C. Valeriani , E. Sanz , W. C. K. Poon , M. E. Cates , P. N. Pusey

In amorphous solids at finite temperatures the particles follow chaotic trajectories which, at temperatures sufficiently lower than the glass transition, are trapped in "cages". Averaging their positions for times shorter than the diffusion…

Statistical Mechanics · Physics 2019-12-11 Prasenjit Das , Valery Ilyin , Itamar Procaccia

We describe a method to determine whether a material has isomorphs in its thermodynamic phase diagram. Isomorphs are state points for which various properties are invariant in reduced units. Such materials are commonly identified from…

Soft Condensed Matter · Physics 2017-09-13 D. Fragiadakis , C. M. Roland

The effect of ring stiffness and pressure on the glassy dynamics of a thermal assembly of two-dimensional ring polymers is investigated using extensive coarse-grained molecular dynamics simulations. In all cases, dynamical slowing down is…

Soft Condensed Matter · Physics 2023-06-06 Sayantan Ghosh , Satyavani Vemparala , Pinaki Chaudhuri

The solidity of glassy materials is believed to be due to the cage formed around each particle by its neighbors, but in reality the details of cage-formation remain elusive [1-4]. This cage starts to be formed at the onset…

Soft Condensed Matter · Physics 2020-12-02 Bo Li , Kai Lou , Walter Kob , Steve Granick

We use a random pinning procedure to investigate stable glassy states associated with large deviations of the activity in a model glass-former. We pin particles both from active (equilibrium) configurations and from stable (inactive) glassy…

Statistical Mechanics · Physics 2014-07-02 Christopher J. Fullerton , Robert L. Jack