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By molecular-dynamics simulations, we have studied the devitrification (or crystallization) of aged hard-sphere glasses. First, we find that the dynamics of the particles are intermittent: Quiescent periods, when the particles simply…

Soft Condensed Matter · Physics 2014-04-03 Eduardo Sanz , Chantal Valeriani , Emanuela Zaccarelli , Wilson C K Poon , Michael E Cates , Peter N Pusey

The discovery of ultrastable glasses has raised novel challenges about glassy systems. Recent experiments studied the macroscopic devitrification of ultrastable glasses into liquids upon heating but lacked microscopic resolution. We use…

Statistical Mechanics · Physics 2023-04-13 Cecilia Herrero , Camille Scalliet , M. D. Ediger , Ludovic Berthier

The glassy dynamics of dense active matter have recently become a topic of interest due to their importance in biological processes such as wound healing and tissue development. However, while the liquid-state properties of dense active…

Soft Condensed Matter · Physics 2024-11-13 Masaki Yoshida , Hideyuki Mizuno , Atsushi Ikeda

We use computer simulations to study the glass transition of dense fluids made of polydisperse, repulsive spheres. For hard particles, we vary the volume fraction, phi, and use compressible particles to explore finite temperatures, T>0. In…

Statistical Mechanics · Physics 2009-08-25 Ludovic Berthier , Thomas A. Witten

Creating amorphous solid states by randomly bonding an ensemble of dense liquid monomers is a common procedure which is applied to create a variety of materials such as epoxy resins, colloidal gels, and vitrimers. The properties of the…

Soft Condensed Matter · Physics 2024-01-26 Misaki Ozawa , Jean-Louis Barrat , Walter Kob , Francesco Zamponi

Dynamic heterogeneity in glass-formers has been related to their static structure using the concept of dynamic propensity. We re-examine this relationship by analyzing dynamical fluctuations in two atomistic glass-formers and two…

Statistical Mechanics · Physics 2009-08-25 Ludovic Berthier , Robert L. Jack

We study by Molecular Dynamics simulation a dense one-component system of particles confined on a spherical substrate. We more specifically investigate the evolution of the structural and dynamical properties of the system when changing the…

Soft Condensed Matter · Physics 2018-05-23 Julien-Piera Vest , Gilles Tarjus , Pascal Viot

The topological nature of the disorder of glasses and supercooled liquids strongly affects their high-frequency dynamics. In order to understand its main features, we analytically studied a simple topologically disordered model, where the…

Disordered Systems and Neural Networks · Physics 2009-11-07 T. S. Grigera , V. Martin-Mayor , G. Parisi , P. Verrocchio

We study the solid-to-liquid transition in a two-dimensional fully periodic soft-glassy model with an imposed spatially heterogeneous stress. The model we consider consists of droplets of a dispersed phase jammed together in a continuous…

Soft Condensed Matter · Physics 2018-06-06 Matteo Lulli , Roberto Benzi , Mauro Sbragaglia

We compare dynamical heterogeneities in equilibrated supercooled liquids and in the nonequilibrium glassy state within the framework of the random first order transition theory. Fluctuating mobility generation and transport in the glass are…

Statistical Mechanics · Physics 2014-01-21 Apiwat Wisitsorasak , Peter G. Wolynes

We use computer simulations to investigate the static properties of a simple glass-forming fluid in which the positions of a finite fraction of the particles has been frozen in. By probing the equilibrium distribution of the overlap between…

Disordered Systems and Neural Networks · Physics 2015-06-12 Walter Kob , Ludovic Berthier

We study heterogeneities in a binary Lennard-Jones system below the glass transition using molecular dynamics simulations. We identify mobile and immobile particles and measure their distribution of vibrational amplitudes. For temperatures…

Disordered Systems and Neural Networks · Physics 2013-05-29 Katharina Vollmayr-Lee , Annette Zippelius

We derive a phase diagram for amorphous solids and liquid supercooled water and explain why the amorphous solids of water exist in several different forms. Application of large-deviation theory allows us to prepare such phases in computer…

Statistical Mechanics · Physics 2015-06-16 David T Limmer , David Chandler

We investigate the characteristic length scales associated with the glass transition phenomenon. By studying an atomic glass-forming liquid in negatively curved space, for which the local order is well identified and the amount of…

Statistical Mechanics · Physics 2010-02-10 François Sausset , Gilles Tarjus

We study the strong role played by structural (quenched) heterogeneities on static and dynamic properties of the Frustrated Ising Lattice Gas in two dimensions, already in the liquid phase. Differently from the dynamical heterogeneities…

Disordered Systems and Neural Networks · Physics 2009-11-10 Mendeli H. Vainstein , Daniel A. Stariolo , Jeferson J. Arenzon

Solids subjected to repeated cycles of stress or deformation can fail after several cycles, a phenomenon termed fatigue failure. Although intensely investigated for a wide range of materials owing to its obvious practical importance, a…

Soft Condensed Matter · Physics 2024-09-27 Swarnendu Maity , Himangsu Bhaumik , Shivakumar Athani , Srikanth Sastry

We introduce a new quantity to probe the glass transition. This quantity is a linear generalized compressibility which depends solely on the positions of the particles. We have performed a molecular dynamics simulation on a glass forming…

Disordered Systems and Neural Networks · Physics 2009-11-07 Herve M. Carruzzo , Clare C. Yu

The glassy state is known to undergo slow structural relaxation, where the system progressively explores lower free-energy minima which are either amorphous (ageing) or crystalline (devitrification). Recently, there is growing interest in…

Soft Condensed Matter · Physics 2017-08-03 Taiki Yanagishima , John Russo , Hajime Tanaka

We study the phase ordering dynamics of a two dimensional model colloidal solid using molecular dynamics simulations. The colloid particles interact with each other with a Hamaker potential modified by the presence of equatorial "patches"…

Disordered Systems and Neural Networks · Physics 2014-12-30 Chandana Mondal , Smarajit Karmakar , Surajit Sengupta

Ultrastable glasses have risen to prominence due to their potentially useful material properties and the tantalizing possibility of a general method of preparation via vapor deposition. Despite the importance of this novel class of…

Statistical Mechanics · Physics 2014-12-09 Glen M Hocky , Ludovic Berthier , David R. Reichman