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This work reports the peculiar properties of a graphene film prepared by the chemical vapor deposition (CVD) of ethylene in high vacuum on a well oriented and carefully cleaned Pt(111) crystal surface maintained at high temperature. In-situ…

Mesoscale and Nanoscale Physics · Physics 2015-06-15 E. Cazzanelli , T. Caruso , M. Castriota , A. R. Marino , A. Politano , G. Chiarello , M. Giarola , G. Mariotto

We report graphene films composed mostly of one or two layers of graphene grown by controlled carbon precipitation on the surface of polycrystalline Ni thin films during atmospheric chemical vapor deposition(CVD). Controlling both the…

We synthesize large-area graphene via atmospheric-pressure (AP) chemical vapor deposition (CVD) on copper, and transfer to SiO2 wafers. In contrast to low-pressure (LP) CVD on copper, optical contrast and atomic force microscopy…

Materials Science · Physics 2011-07-15 Daniel R. Lenski , Michael S. Fuhrer

Germanium is emerging as the substrate of choice for the growth of graphene in CMOS-compatible processes. For future application in next generation devices the accurate control over the properties of high-quality graphene synthesized on Ge…

Materials Science · Physics 2018-05-04 A. M. Scaparro , V. Miseikis , C. Coletti , A. Notargiacomo , M. Pea , M. De Seta , L. Di Gaspare

We have demonstrated a new method for the large-area graphene growth, which can lead to a scalable low-cost high-throughput production technology. The method is based on growing single-layer or few-layer graphene films from a molten phase.…

Materials Science · Physics 2010-11-19 Shaahin Amini , Javier Garay , Guanxiong Liu , Alexander A. Balandin , Reza Abbaschian

Multilayer graphene (MLG) films were grown by chemical vapour deposition (CVD) on molybdenum carbide ($MoC_{x}$) substrates. We fabricated the catalytic $MoC_{x}$ films by plasma enhanced atomic layer deposition (PEALD). The mechanism of…

Applied Physics · Physics 2020-01-01 Eldad Grady , Chenhui Li , Oded Raz , W. M. M. Kessels , Ageeth A. Bol

The development of wafer-scale continuous single-crystal graphene layers is key in view of its prospective applications. To this end, here we pave the way for a graphene growth model in the framework of the Langmuir adsorption theory and…

Materials Science · Physics 2013-05-14 HoKwon Kim , Eduardo Saiz , Manish Chhowalla , Cecilia Mattevi

Graphene growth by chemical vapor deposition has received a lot of attention recently owing to the ease with which large area films can be grown, but growth of large domain or equivalently large grain size has not been reported yet. In this…

Materials Science · Physics 2010-10-20 Xuesong Li , Carl W. Magnuson , Archana Venugopal , Eric M. Vogel , Rodney S. Ruoff , Luigi Colombo

A bottom-up chemical vapor deposition (CVD) process for the growth of graphene nanomesh films is demonstrated. The process relies on silicon nanospheres to block nucleation sites for graphene CVD on copper substrates. These spheres are…

Materials Science · Physics 2016-09-16 Matthias König , Günther Ruhl , Joerg-Martin Batke , Max C. Lemme

In this report, we demonstrated a simple but efficient strategy to synthesize millimeter-sized graphene single crystal grains by regulating the supply of reactants in chemical vapor deposition process. Polystyrene was used as a carbon…

Materials Science · Physics 2012-08-28 Tianru Wu , Guqiao Ding , Honglie Shen , Haomin Wang , Lei Sun , Da Jiang , Xiaoming Xie , Mianheng Jiang

Understanding the atomistic mechanism in graphene growth is crucial for controlling the number of layers or domain sizes to meet practical needs. In this work, focusing on the growth of graphene by chemical vapor deposition on copper…

Materials Science · Physics 2024-06-12 Tongtong Wang , Jian Zheng , Xin Wei , Dajun Shu

Graphene nanoribbons (GNRs) are considered one of the most promising materials for next generation electronics, however a reliable and controllable synthesis method is still lacking. Here, we report the CVD growth of GNRs on a copper…

Mesoscale and Nanoscale Physics · Physics 2022-01-04 Haibin Sun , Fengning Liu , Leining Zhang , Ben McLean , Hao An , Ming Huang , Marc-Georg Willinger , Rodney Ruoff , Zhujun Wang , Feng Ding

In recent years, liquid metal catalysts have emerged as a compelling choice for the controllable, large-scale, and high-quality synthesis of two-dimensional materials. At present, there is little mechanistic understanding of the intricate…

Epitaxial growth via chemical vapor deposition is considered to be the most promising way towards synthesizing large area graphene with high quality. However, it remains a big theoretical challenge to reveal growth kinetics with atomically…

Chemical Physics · Physics 2015-09-30 Huijun Jiang , Zhonghuai Hou

By limiting the carbon segregation at the copper surface defects, a pulsed chemical vapor deposition method for single layer graphene growth is shown to inhibit the formation of few-layer regions, leading to a fully single-layered graphene…

Liquid metal catalysts (LMCats), primarily molten copper, have demonstrated their efficiency in the chemical vapour deposition (CVD) approach for synthesising high-quality, large-area graphene. However, their high melting temperatures limit…

We report high room-temperature mobility in single layer graphene grown by Chemical Vapor Deposition (CVD) after wet transfer on SiO$_2$ and hexagonal boron nitride (hBN) encapsulation. By removing contaminations trapped at the interfaces…

Chemical vapor deposition (CVD) is an important method to synthesis grapheme on a substract. Recently, Cu becomes the most popular CVD substrate for graphene growth. Here, we combine electronic structure calculation, molecular dynamics…

Materials Science · Physics 2011-09-14 Wenhua Zhang , Ping Wu , Zhenyu Li , Jinlong Yang

We evaluate how a second graphene layer forms and grows on Cu foils during chemical vapor deposition (CVD). Low-energy electron diffraction and microscopy is used to reveal that the second layer nucleates and grows next to the substrate,…

Materials Science · Physics 2015-06-04 Shu Nie , Wei Wu , Shirui Xing , Qingkai Yu , Jiming Bao , Shin-shem Pei , Kevin F. McCarty

Chemical Vapor Deposition (CVD) of graphene on copper is one of the most efficient technologies for producing high quality graphene for large areas. Nevertheless, still high pressures and big quantities of precursor gas are currently…

Materials Science · Physics 2014-09-18 V-M. Freire , A. Ramirez , E. Pascual , E. Bertran , J-L. Andujar