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The nontrivial electronic topology of a topological insulator is thus far known to display signatures in a robust metallic state at the surface. Here, we establish vibrational anomalies in Raman spectra of the bulk that signify changes in…

In recent years, a low pressure transition around P $\sim$ 3 GPa exhibited by the A$_2$B$_3$-type 3D topological insulators is attributed to an electronic topological transition (ETT) for which there is no direct evidence either from theory…

Materials Science · Physics 2016-03-23 Achintya Bera , Koushik Pal , D V S Muthu , U V Waghmare , A K Sood

We report Raman signatures of electronic topological transition (ETT) at 3.6 GPa and rhombohedral ({\alpha}-Bi2Te3) to monoclinic ({\beta}-Bi2Te3) structural transition at ~ 8 GPa. At the onset of ETT, a new Raman mode appears near 107 cm-1…

Materials Science · Physics 2015-06-03 Gopal K. Pradhan , Achintya Bera , Pradeep Kumar , D. V. S. Muthu , A. K. Sood

We report high pressure Raman experiments of Black phosphorus up to 24 GPa. The line widths of first order Raman modes A$^1_g$, B$_{2g}$ and A$^2_g$ of the orthorhombic phase show a minimum at 1.1 GPa. Our first-principles density…

Strongly Correlated Electrons · Physics 2017-09-20 Satyendra Nath Gupta , Anjali Singh , Koushik Pal , Biswanath Chakraborti , D. V. S. Muthu , U V Waghmare , A. K. Sood

Raman spectra of the MgB2 ceramic samples were measured as a function of pressure up to 32 GPa at room temperature. The spectrum at normal conditions contains a very broad peak at ~590 cm-1 related to the E2g phonon mode. The frequency of…

Materials Science · Physics 2009-11-07 K. P. Meletov , J. Arvanitidis , M. P. Kulakov , N. N. Kolesnikov , G. A. Kourouklis

We report a theoretical \textit{ab-initio} study of $\beta$-As$_2$Te$_3$ ($R\bar{3}m$ symmetry) at hydrostatic pressures up to 12 GPa. We have systematically characterized the vibrational and electronic changes of the system induced by the…

We performed X-ray diffraction and electrical resistivity measurement up to pressures of 5 GPa and the first-principles calculations utilizing experimental structural parameters to investigate the pressure-induced topological phase…

Topological superconductivity with Majorana bound states, which are critical to implement nonabelian quantum computation, may be realized in three-dimensional semimetals with nontrivial topological feature, when superconducting transition…

We report measurements of the superconducting critical temperature Tc of polycrystalline MgB2 samples containing isotopically pure (10)B and (11)B under quasi-hydrostatic pressure conditions in He pressure media up to 44 GPa. Measurements…

Superconductivity · Physics 2007-05-23 V. V. Struzhkin , A. F. Goncharov , R. J. Hemley , H. K. Mao , G. Lapertot , S. L. Bud'ko , P. C. Canfield

The characteristics of topological insulators are manifested in both their surface and bulk properties, but the latter remain to be explored. Here we report bulk signatures of pressure-induced band inversion and topological phase…

We investigate the nonequilibrium photocarrier dynamics of WTe2 under pressure using the optical pump-probe spectroscopy. The pressure dependences of the electronic relaxation manifest anomalous changes around 0.8, 3.5, and 6 GPa,…

Strongly Correlated Electrons · Physics 2023-03-10 Kai Zhang , Fuhai Su , Dayong Liu , Wenjun Wang , Yongsheng Zhang , Zhi Zeng , Zhe Qu , Alexander F. Goncharov

High pressure Raman spectroscopy of bulk 2H-MoTe$_2$ upto $\sim$ 29 GPa is shown to reveal two phase transitions (at $\sim$ 6 and 16.5 GPa), which are analyzed using first-principles density functional theoretical calculations. The…

Materials Science · Physics 2017-03-08 Achintya Bera , Anjali Singh , D V S Muthu , U V Waghmare , A K Sood

Two pressure-induced phase transitions have been theoretically studied in the layered iron phosphorus triselenide (FePSe3). Topological analysis of chemical bonding in FePSe3 has been performed based on the results of first-principles…

Materials Science · Physics 2020-11-05 Robert A. Evarestov , Alexei Kuzmin

Since there is both strong electron-phonon coupling during a ferroelectric/FE transition and superconducting/SC transition, it has been an important topic to explore superconductivity from the FE instability. Sn$_2$P$_2$Se$_6$ arouses broad…

Superconductivity · Physics 2024-02-27 He Zhang , Wei Zhong , Xiaohui Yu , Binbin Yue , Fang Hong

Recently discovered class of 2D materials based on transition metal phosphorous trichalcogenides exhibit antiferromagnetic ground state, with potential applications in spintronics. Amongst them, FePS$ _{3} $ is a Mott insulator with a band…

One approach to discovering topological superconductor is establishing superconductivity based on well-identified topological insulators. However, the coexistence of superconductivity and topological state is always arcane. In this paper,…

Superconductivity · Physics 2022-09-30 Lei Kang , Zi-Yu Cao , Bo Wang

ZrSiS has recently gained attention due to its unusual electronic properties: nearly perfect electron-hole compensation, large, anisotropic magneto-resistance, multiple Dirac nodes near the Fermi level, and an extremely large range of…

Strongly Correlated Electrons · Physics 2019-02-21 D. VanGennep , T. A. Paul , C. W. Yerger , S. T. Weir , Y. K. Vohra , J. J. Hamlin

Here we present the superconducting property and structural stability of kagome CsV3Sb5 under in-situ high pressures. For the initial SC-I phase, its Tc is quickly enhanced from 3.5 K to 7.6 K and then totally suppressed at P~10 GPa.…

Superconductivity · Physics 2021-04-23 Xu Chen , Xinhui Zhan , Xiaojun Wang , Jun Deng , Xiao-bing Liu , Xin Chen , Jian-gang Guo , Xiaolong Chen

We report high-pressure photoluminescence, Raman scattering, and x-ray diffraction measurements on a lead-free halide perovskite $Cs_3Sb_2Br_9$. At about 3 GPa, an electronic transition manifests itself through a broad minimum in linewidth,…

Recent progress in understanding the electronic band topology and emergent topological properties encourage us to reconsider the band structure of well-known materials including elemental substances. Controlling such a band topology by…

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