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When electrolyte solutions are confined in micro- and nanochannels their conductivity is significantly different from those in a bulk phase. Here we revisit the theory of this phenomenon by focusing attention on the reduction in the ion…

Soft Condensed Matter · Physics 2023-11-08 Olga I. Vinogradova , Elena F. Silkina

We employ molecular dynamics simulations to investigate ion and water transport driven by an electric field through quasi-two-dimensional nanoslits with a tapered geometry. Despite the absence of surface charge on the channel walls and the…

Soft Condensed Matter · Physics 2025-09-29 Tim Veenstra , Gerardo Campos-Villalobos , Giuliana Giunta , René van Roij , Marjolein Dijkstra

Ion transport in biological and synthetic nanochannels is characterized by such phenomena as ion current fluctuations, rectification, and pumping. Recently, it has been shown that the nanofabricated synthetic pores could be considered as…

Chemical Physics · Physics 2009-11-11 I. D. Kosinska

This work presents a modified Kedem-Katchalsky equations for osmosis through nano-pore. osmotic reflection coefficient of a solute was found to be chiefly affected by the entrance of the pore while filtration reflection coefficient can be…

Biological Physics · Physics 2017-01-05 Liangsuo Shu , Xiaokang Liu , Yingjie Li , Baoxue Yang , Suyi Huang , Yixin Lin , Shiping Jin

Fluidic devices exhibiting ion current rectification (ICR), or ionic diodes, are of broad interest for applications including desalination, energy harvesting, and sensing, amongst others. For such applications a large conductance is…

Soft Condensed Matter · Physics 2022-10-11 Mark Aarts , Willem Boon , Blaise Cuénod , M. Dijkstra , René van Roij , Esther Alarcon-Llado

We revisit the classical problem of flow of electrolyte solutions through charged capillary nanopores or nanotubes as described by the capillary pore model (also called "space charge" theory). This theory assumes very long and thin pores…

Chemical Physics · Physics 2019-08-16 P. B. Peters , R. van Roij , M. Z. Bazant , P. M. Biesheuvel

We develop a hydrodynamic theory for an electron system exhibiting the anomalous Hall effect, and show that an additional anomalous Hall effect is induced by a vorticity generated near boundaries. We calculate the momentum flux and force…

Mesoscale and Nanoscale Physics · Physics 2021-07-28 Hiroshi Funaki , Riki Toshio , Gen Tatara

Thermo-osmotic flows - flows generated in micro and nanofluidic systems by thermal gradients - could provide an alternative approach to harvest waste heat. However, such use would require massive thermo-osmotic flows, which are up to now…

Fluid Dynamics · Physics 2022-01-21 Cecilia Herrero , Michael De San Féliciano , Samy Merabia , Laurent Joly

We present mesoscopic DPD-simulations of polyelectrolyte electrophoresis in confined nanogeometries, for varying salt concentration and surface slip conditions. Special attention is given to the influence of electroosmotic flow (EOF) on the…

Soft Condensed Matter · Physics 2011-03-03 Jens Smiatek , Friederike Schmid

The standard view is that at low energies Mott insulators exhibit only magnetic properties while charge degrees of freedom are frozen out as the electrons become localized by a strong Coulomb repulsion. We demonstrate that this is in…

Strongly Correlated Electrons · Physics 2009-11-13 L. N. Bulaevskii , C. D. Batista , M. Mostovoy , D. Khomskii

Partitioning and transport of water and small solutes into and through nanopores is important to a variety of chemical and biological processes and applications. Here we study the partitioning of positive ions of increasing size into the…

Chemical Physics · Physics 2007-05-23 Lu Yang , Shekhar Garde

The present study deals with the effect of ionic advection on electroosmotic flow over charge modulated surfaces in a generalized paradigm when the classically restrictive "weak field" limit may be relaxed. Going beyond the commonly…

Fluid Dynamics · Physics 2015-09-29 Uddipta Ghosh , Suman Chakraborty

Electron transport in clean 2D systems with weak electron-phonon (e-ph) coupling can transition from an Ohmic to a ballistic or a hydrodynamic regime. The ballistic regime occurs when electron-electron (e-e) scattering is weak whereas the…

Mesoscale and Nanoscale Physics · Physics 2019-04-10 Mani Chandra , Gitansh Kataria , Deshdeep Sahdev , Ravishankar Sundaraman

A numerical study within the framework of the Poisson-Nernst-Planck equations is conducted to investigate electrostatic screening of charged bio-molecules within synthetic pores having diameters of at least 10 Debye lengths. We show that…

Biological Physics · Physics 2009-11-13 Yang Liu , Jon Sauer , Robert Dutton

Electrical image potentials can be important in small spaces, such as nanoscale pores in porous electrodes, which are used in capacitive desalination and in supercapacitors. It will be shown here that inside pores in porous metallic…

Mesoscale and Nanoscale Physics · Physics 2022-04-27 Jeffrey B Sokoloff

The comprehensive depiction of the many-body effects governing nanoconfined electrolytes is an essential step for the conception of nanofluidic devices with optimized performance. By incorporating self-consistently multivalent charges into…

Soft Condensed Matter · Physics 2020-12-14 Sahin Buyukdagli

We present an electrostatic theory of the optical rectification, namely, the static photovoltage or photocurrent generation under a light illumination, in metallic particles. The hydrodynamical model for the charge carriers in the metals is…

Optics · Physics 2022-03-23 Tetsuyuki Ochiai

We theoretically propose a method of rectifying spin current with a linearly-polarized electromagnetic wave in inversion-asymmetric magnetic insulators. To demonstrate the proposal, we consider quantum spin chains as a simple example; these…

Strongly Correlated Electrons · Physics 2019-05-22 Hiroaki Ishizuka , Masahiro Sato

We establish experimentally the flow patterns of induced-charge electro-osmosis (ICEO) around immobilized metallic spheres in aqueous electrolyte. The AC field modifies local electrolyte concentration and causes quadrupolar flows with…

Soft Condensed Matter · Physics 2015-06-23 Chenhui Peng , Israel Lazo , Sergij V. Shiyanovskii , Oleg D. Lavrentovich

The flow of ions through permeable channels causes voltage drop in physiological nanodomains such as synapses, dendrites and dendritic spines, and other protrusions. How the voltage changes around channels in these nanodomains has remained…

Soft Condensed Matter · Physics 2025-01-10 Frédéric Paquin-Lefebvre , David Holcman