Related papers: Electroosmotic flow rectification in conical nanop…
Using molecular dynamics simulations, we show that, when subject to a periodic external electric field, a nanopore in ionic solution acts as a capacitor with memory (memcapacitor) at various frequencies and strengths of the electric field.…
We study conformational and electrophoretic properties of polyelectrolytes (PEs) in tetravalent salt solutions under the action of electric fields by means of molecular dynamics simulations. Chain conformations are found to have a sensitive…
In a circular channel passing over-limiting current (faster than diffusion), transient vortices of bulk electroconvection are observed in salt-depleted region within the horizontal plane. The spatiotemporal evolution of the salt…
In electrochemical systems, an understanding of the underlying transport processes is required to aid in their better design. This includes knowledge of possible near-electrode convective mixing that can enhance measured currents. Here, for…
In novel ultra-pure materials electrons can form a viscous fluid, which is fundamentally different by its dynamics from the electron gas in ordinary conductors with significant density of defects. The shape of the non-stationary flow of…
The interface between a liquid and a solid is the location of plethora of intrincate mechanisms at the nanoscale, at the root of their specific emerging properties in natural processes or technological applications. However, while the…
The electrochemical processes in energy storage materials are generally linked with changes of molar volume of the host compound. Here, the frequency dependent strain response of 1D electrochemically active systems to periodic electric bias…
A nanocomposite film containing highly polarizable inclusions in a fluid background is explored when an external electric field is applied perpendicular to the planar film. For small electric fields, the induced dipole moments of the…
The venerable theory of electrokinetic phenomena rests on the hypothesis of a dilute solution of point-like ions near a weakly charged surface, whose potential relative to the bulk is of order the thermal voltage ($kT/e \approx 25$ mV at…
The steady-state current-voltage response of ion-selective systems varies as the number of ion-selective components is varied. For the highly investigated unipolar system, including only one ion-selective component, it has been shown that…
Energy harvesting from evaporation has become a hot topic in the last couple of years. Researchers have speculated on several possible mechanisms. Electrokinetic energy conversion is the least hypothetical one. The basics of pressure-driven…
It has been suggested that superhydrophobic surfaces, due to the presence of a no-shear zone, can greatly enhance transport of surface charges, leading to a considerable increase in the streaming potential. This could find potential use in…
In this article we review recent work aimed at showing explicitly the influence of electromagnetic self corrections on the dynamics of a circular vortex line endowed with a current at first order in the coupling between the current and the…
Fluctuations affect nanoporous transport in complex and intricate ways, making optimization of signal-to-noise in artificial designs challenging. Here we focus on the simplest nanopore system, where non-interacting particles diffuse through…
Short nanopores find extensive applications capitalizing on their high throughput and detection resolution. Ionic behaviors through long nanopores are mainly determined by charged inner-pore walls. When pore lengths decrease to sub-200 nm,…
Electrolyte-filled channels with modulated wall charge distribution subjected to an applied DC electric field, form time-independent vortices whose sense of circulation is determined by the field direction [Physical Review Letters $…
Ultrafine particle behavior in electro-hydrodynamic (EHD) flow induced by corona discharge is studied experimentally and numerically. The EHD flow serves as a primary particle aspiration/sampling mechanism, the collector does not require…
The ionic selectivity of nanopores is crucial for the energy conversion based on nanoporous membranes. It can be significantly affected by various parameters of nanopores and the applied fields driving ions through porous membranes. Here,…
Polymer translocation experiments typically involve anionic polyelectrolytes such as DNA molecules driven through negatively charged nanopores. Quantitative modelling of polymer capture to the nanopore followed by translocation therefore…
In this paper, we study electrostatic properties between two similar or oppositely charged surfaces immersed in an electrolyte solution by using mean-field approach accounting for solvent polarization and non-uniform size effect. Applying a…