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Lattice and spin excitations have been studied by Raman scattering in hexagonal YbMnO3 single crystals. The temperature dependences of the phonon modes show that the E2 mode at 256 cm-1 related to the displacement of Mn and O ions in a-b…

Strongly Correlated Electrons · Physics 2012-11-12 J. Liu , C. Toulouse , P. Rovillain , M. Cazayous , Y. Gallais , M. -A. Measson , S. W. Cheong , N. Lee , A. Sacuto

The magnetic field dependent phase diagram of the ferroelectric material ${\rm Ho}_{1-x}Y_{x}MnO_{3}$ has been investigated for x = 0, 0.6, and 0.8 for fields directed along both the ab in-plane and c-axis basal plane directions. Dielectric…

Strongly Correlated Electrons · Physics 2009-11-11 R. Vasic , H. Zhou , E. Jobiliong , C. R. Wiebe , J. S. Brooks

We have investigated crystal field and phonon dynamics of the multiferroic orthoferrite DyFeO$_3$ via polarized infrared spectroscopy. Reflectance of single crystals was measured in the far- to mid-infrared spectral range at range of…

Strongly Correlated Electrons · Physics 2013-02-14 A. D. LaForge , J. Whalen , T. Siegrist , A. P. Ramirez , Z. Schlesinger

Strong magnetic-ferroelectric coupling in hexagonal HoMnO3 has been observed previously at spin reorientation temperature between P6'3cm' and the P6'3cm' magnetic phases. In contrast, YMnO3 has only a single magnetic phase (P6'3cm') and no…

Strongly Correlated Electrons · Physics 2013-03-26 Jagath Gunasekera , Owen P. Vajk , Yuan Wang , Kevin Tarwater , Tom W. Heitmann

We have investigated the temperature-dependent Raman-active phonons and the magnetic properties of Gd(Co1/2Mn1/2)O3 perovskite ceramics in the temperature range from 40 K to 300 K. The samples crystallized in an orthorhombic distorted…

Materials Science · Physics 2015-06-17 R. X. Silva , H. Reichlova , X. Marti , D. A. B. Barbosa , M. W. Lufaso , A. P. Ayala , C. W. A. Paschoal

Spin wave dispersion in the metallic antiferromagnet Mn$_3$Pt was investigated just above the order-order transition temperature by using the inelastic neutron scattering technique. The spin wave dispersion at $T = 400$ K along [100], [110]…

Materials Science · Physics 2017-07-06 Soshi Ibuka , Tetsuya Yokoo , Shinichi Itoh , Kazuya Kamazawa , Mitsutaka Nakamura , Motoharu Imai

We present a systematic first-principles study of the phonon spectrum of hexagonal YMnO3 in ferroelectric (multiferroic) phase. We investigated in detail the low-energy phonon modes, their dispersion, symmetry, as well as the infrared…

Materials Science · Physics 2012-07-30 Konstantin Z. Rushchanskii , Marjana Ležaić

A prominent band centered at around 1000-1300 cm-1 and associated with resonant enhancement of two-phonon Raman scattering is reported in multiferroic BiFeO3 thin films and single crystals. A strong anomaly in this band occurs at the…

We present a fully analytical model of hybridization between magnon, and phonons observed experimentally in magneto-Raman scattering in van der Waals (vdW) antiferromagnets (AFM). Here, the representative material, FePS3, has been shown to…

Mesoscale and Nanoscale Physics · Physics 2025-01-03 Somsubhra Ghosh , Mainak Palit , Sujan Maity , Subhadeep Datta

Synthetic powder, ore samples and mineral single crystals of goethite ($\alpha-$FeOOH) were investigated with polarized Raman spectroscopy at temperatures from 300 K to 473 K. The symmetry of the vibrational modes, observed in different…

Materials Science · Physics 2020-06-24 M. V. Abrashev , V. G. Ivanov , B. S. Stefanov , N. D. Todorov , J. Rosell , V. Skumryev

Alloyed MnxZn1_xPS3 samples have been grown covering the whole compositional range and studied by means of Raman spectroscopy at temperatures covering from 4K up to 850K. Our results, supported by SQUID magnetic measurements, allowed, from…

Spin-phonon coupling effects, as reflected in phonon frequency shifts between ferromagnetic (FM) and G-type antiferromagnetic (AFM) configurations in cubic CaMnO$_3$, SrMnO$_3$, BaMnO$_3$, LaCrO$_3$, LaFeO$_3$ and La$_2$(CrFe)O$_6$, are…

Strongly Correlated Electrons · Physics 2012-11-20 Jiawang Hong , Alessandro Stroppa , Jorge Íñiguez , Silvia Picozzi , David Vanderbilt

Raman experiments on the spin-Peierls compound CuGeO$_3$ and the substituted (Cu$_{1- x}$,Zn$_x$)GeO$_3$ and Cu(Ge$_{1-x}$,Ga$_x$)O$_3$ compounds were performed in order to investigate the response of specific magnetic excitations of the…

We report on the microwave, terahertz (THz), infrared and Raman spectroscopic studies of $BiMn_{7}O_{12}$ ceramics, shedding more light into the nature of two structural phase transitions and their possible relation with ferroelectricity in…

Materials Science · Physics 2024-01-08 A. Maia , M. Kempa , V. Bovtun , R. Vilarinho , C. Kadlec , J. Agostinho Moreira , A. A. Belik , P. Proschek , S. Kamba

We report investigation of phonons and oxygen diffusion in Bi2O3 and (Bi0.7Y0.3)2O3. The phonon spectra have been measured in Bi2O3 at high temperatures up to 1083 K using inelastic neutron scattering. Ab-initio calculations have been used…

In this letter we investigated the temperature-dependent Raman spectra of CaMn7O12 helimagnet from room temperature down to 10 K. The temperature dependence of the Raman mode parameters show remarkable anomalies for both antiferromagnetic…

Measurements of the structure of hexagonal RMnO3 (R=rare earths (Ho) and Y) for temperatures significantly above the ferroelectric transition temperature (TFE) were conducted to determine the nature of the transition. The local and long…

Materials Science · Physics 2015-05-30 T. A. Tyson , T. Wu , H. Y. Chen , J. Bai , K. H. Ahn , K. I. Pandya , S. B. Kim , S. -W. Cheong

Compressively strained epitaxial (001) EuTiO3 thin films of tetragonal symmetry have been deposited on (001) (LaAlO3)_0.29-(SrAl_{1/2}Ta_{1/2}O3)_0.71 (LSAT) substrates by reactive molecular-beam epitaxy. Enhancement of the Neel temperature…

Polycrystalline ceramic samples and a single crystal of EuTiO3 have been investigated by Raman spectroscopy in the temperature range 80-300 K. Although synchrotron XRD data clearly indicated the cubic to tetragonal phase transition around…

Materials Science · Physics 2021-04-21 P. Pappas , E. Liarokapis , M. Calamiotou , A. Bussmann-Holder

Phonon measurements in the A15-type superconductors were complicated in the past because of the unavailability of large single crystals for inelastic neutron scattering, e.g., in the case of Nb$_3$Sn, or unfavorable neutron scattering…

Superconductivity · Physics 2019-04-19 A. Sauer , D. A. Zocco , A. H. Said , R. Heid , A. Böhmer , F. Weber