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Black phosphorus (BP) is a layered material with anisotropic properties. We study interfaces formed by a pentacene monolayer adsorbed on monolayer BP, a prototypical system for BP surface passivation. We place the pentacene monolayer along…

Materials Science · Physics 2022-12-09 Naseem Ud Din , Zhen-Fei Liu

Atomically thin black phosphorus (BP) field-effect transistors show strong-weak localization transition which is tunable through gate voltages. Hopping transports through charge impurity induced localized states are measured at low-carrier…

Mesoscale and Nanoscale Physics · Physics 2017-11-22 Gen Long , Shuigang Xu , Xiangbin Cai , Zefei Wu , Tianyi Han , Jiangxiazi Lin , Yuanwei Wang , Liheng An , Yuan Cai , Xinran Wang , Ning Wang

Low-dimensional systems based on black phosphorus (BP) have recently attracted much interest. Since the crystal structure of BP consists of 2D layers with a strong in-plane anisotropy, its electronic properties at a high magnetic field…

Mesoscale and Nanoscale Physics · Physics 2025-03-26 H. Okamura , S. Iguchi , T. Sasaki , Y. Ikemoto , T. Moriwaki , Y. Akahama

The energy bandgap is an intrinsic character of semiconductors, which largely determines their properties. The ability to continuously and reversibly tune the bandgap of a single device during real time operation is of great importance not…

Mesoscale and Nanoscale Physics · Physics 2017-04-26 Shi-Li Yan , Zhi-Jian Xie , Jian-Hao Chen , Takashi Taniguchi , Kenji Watanabe

Phosphorene, a monolayer of black phosphorus (BP), is an elemental two-dimensional material with interesting physical properties, such as high charge carrier mobility and exotic anisotropic in-plane properties. To fundamentally understand…

Mesoscale and Nanoscale Physics · Physics 2019-12-04 Yangjin Lee , Sol Lee , Jun-Yoeong Yoon , Jinwoo Cheon , Hu Young Jeong , Kwanpyo Kim

Black phosphorus (BP), a layered van der Waals material, reportedly has a band gap sensitive to external perturbations and manifests a Dirac-semimetal phase when its band gap is closed. Previous studies were focused on effects of each…

Mesoscale and Nanoscale Physics · Physics 2017-04-12 Hyeonjin Doh , Hyoung Joon Choi

Two-dimensional crystals are emerging materials for nanoelectronics. Development of the field requires candidate systems with both a high carrier mobility and, in contrast to graphene, a sufficiently large electronic bandgap. Here we…

Materials Science · Physics 2014-07-08 Jingsi Qiao , Xianghua Kong , Zhi-Xin Hu , Feng Yang , Wei Ji

Black phosphorus stands out from the family of two-dimensional materials as a semiconductor with a direct, layer-dependent bandgap in energy corresponding to the spectral range from the visible to the mid-infrared (mid-IR), as well as many…

Optics · Physics 2017-10-10 Ruoming Peng , Kaveh Khaliji , Nathan Youngblood , Roberto Grassi , Tony Low , Mo Li

Harnessing electronic excitations involving coherent coupling to bosonic modes is essential for the design and control of emergent phenomena in quantum materials [1]. In situations where charge carriers induce a lattice distortion due to…

We report ab-initio calculations of the phonon dispersion relations of the single-layer and bulk dichalcogenides MoS2 and WS2. We explore in detail the behavior of the Raman active modes, A1g and E2g as a function of the number of layers.…

Materials Science · Physics 2015-05-30 A. Molina-Sánchez , L. Wirtz

Ultrathin black phosphorus, or phosphorene, is the second known elementary two-dimensional material that can be exfoliated from a bulk van der Waals crystal. Unlike graphene it is a semiconductor with a sizeable band gap and its excellent…

Monolayer black and blue phosphorenes possess electronic and optical properties that result in unique features when the two materials are stacked. We devise a low-strain van-der-Waals double layer and investigate its properties with ab…

Materials Science · Physics 2021-01-29 Michele Re Fiorentin , Giancarlo Cicero , Maurizia Palummo

Molybdenum disulfide (MoS2) of single and few-layer thickness was exfoliated on SiO2/Si substrate and characterized by Raman spectroscopy. The number of S-Mo-S layers of the samples was independently determined by contact-mode atomic-force…

Materials Science · Physics 2010-11-16 Changgu Lee , Hugen Yan , Louis E. Brus , Tony F. Heinz , James Hone , Sunmin Ryu

Molybdenum disulfide, MoS2, has recently gained considerable attention as a layered material where neighboring layers are only weakly interacting and can easily slide against each other. Therefore, mechanical exfoliation allows the…

Materials Science · Physics 2016-06-10 Alejandro Molina-Sánchez , Kerstin Hummer , Ludger Wirtz

The ability to assemble layers of two-dimensional (2D) materials to form permutations of van der Waals heterostructures provides significant opportunities in materials design and synthesis. Interlayer interactions provide a path to new…

Mesoscale and Nanoscale Physics · Physics 2023-01-09 Zachariah Hennighausen , Jisoo Moon , Kathleen M. McCreary , Connie H. Li , Olaf M. J. van `t Erve , Berend T. Jonker

The encapsulation of two-dimensional layered materials such as black phosphorus is of paramount importance for their stability in air. However, the encapsulation poses several questions, namely, how it affects, via the weak van der Waals…

We investigate magnetism and band structure engineering in Moir\'e superlattice of blue phosphorus ($\beta$-P) and grey arsenene ($\beta$-As) bilayers, using \textit{ab initio} calculations. The electronic states near the valence and…

Materials Science · Physics 2019-05-20 Shantanu Agnihotri , Maneesh Kumar , Yogesh Singh Chauhan , Amit Agarwal , Somnath Bhowmick

We review the basic optical, electronic, optoelectronic, thermoelectric and mechanical properties of few-layer black phosphorus (BP), a layered semiconductor that can be exfoliated from bulk BP, the most stable allotrope of phosphorus. The…

Mesoscale and Nanoscale Physics · Physics 2017-10-17 Andrey Chaves , W. Ji , J. Maassen , T. Dumitrica , T. Low

Unencapsulated, exfoliated black phosphorus (BP) flakes are found to chemically degrade upon exposure to ambient conditions. Atomic force microscopy, electrostatic force microscopy, transmission electron microscopy, X-ray photoelectron…

In the large family of two-dimensional (2D) layered materials including graphene, its honeycomb analogs, and transition-metal dichalcogenides, the interlayer coupling plays a rather intriguing role. On the one hand, the weak van der Waals…

Superconductivity · Physics 2022-07-01 D. Huang , H. Nakamura , K. Küster , U. Wedig , N. B. M. Schröter , V. N. Strocov , U. Starke , H. Takagi
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