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Nearly all glass-forming liquids feature, along with the structural alpha-relaxation process, a faster secondary process (beta-relaxation), whose nature belongs to the great mysteries of glass physics. However, for some of these liquids, no…

Disordered Systems and Neural Networks · Physics 2010-04-15 A. A. Pronin , M. V. Kondrin , A. G. Lyapin , V. V. Brazhkin , A. A. Volkov , P. Lunkenheimer , A. Loidl

In the upcoming process to overcome the limitations of the standard von Neumann architecture, synaptic electronics is gaining a primary role for the development of in-memory computing. In this field, Ge-based compounds have been proposed as…

Materials Science · Physics 2021-02-18 Francesco Tavanti Behnood Dianat , Alessandra Catellani , Arrigo Calzolari

Dielectric relaxation measurements on supercooled triphenyl phosphite show that at low temperatures time-temperature superposition (TTS) is accurately obeyed for the primary (alpha) relaxation process. Measurements on 6 other molecular…

Soft Condensed Matter · Physics 2009-10-31 Niels Boye Olsen , Tage Christensen , Jeppe C. Dyre

The dynamical glass transition is typically taken to be the temperature at which a glassy liquid is no longer able to equilibrate on experimental timescales. Consequently, the physical properties of these systems just above or below the…

Soft Condensed Matter · Physics 2017-03-08 Samuel S. Schoenholz , Ekin D. Cubuk , Efthimios Kaxiras , Andrea J. Liu

The glass transition temperature (Tg) is the temperature, after which the supercooled liquid undergoes a dynamical arrest. Usually, the glass network modifiers (e.g., Na2O) affect the behavior of Tg. However, in aluminosilicate glasses, the…

Materials Science · Physics 2020-07-09 Achraf Atila , Said Ouaskit , Abdellatif Hasnaoui

Due to high viscosity, glassy systems evolve slowly to the ordered state. Results of molecular dynamics simulation reveal that the structural ordering in glasses becomes observable over "experimental" (finite) time-scale for the range of…

Materials Science · Physics 2015-06-24 Anatolii V. Mokshin , Bulat N. Galimzyanov

We investigate the structural relaxation of a soft-sphere liquid quenched isochorically ($\phi=0.7$) and instantaneously to different temperatures $T_f$ above and below the glass transition. For this, we combine extensive Brownian dynamics…

In order to describe the slow response of a glass former we discuss some distribution of correlation times, e.g., the generalized gamma distribution (GG) and an extension thereof (GGE), the latter allowing to reproduce a simple peak…

Soft Condensed Matter · Physics 2009-11-07 T. Blochowicz , C. Tschirwitz , S. Benkhof , E. A. Rossler

In this work, we present a new model for the interpretation of the local dynamic behavior and the mechanical reinforcement mechanism in polymer nanocomposites. The temperature dependence of the dynamics in the glassy region is described by…

Soft Condensed Matter · Physics 2019-05-16 Georgios Kritikos , Kostas Karatasos

Temporal relaxation of density fluctuations in supercooled liquids near the glass transition occurs in multiple steps. The short-time $\beta$-relaxation is generally attributed to spatially local processes involving the rattling motion of a…

Statistical Mechanics · Physics 2016-03-02 Smarajit Karmakar , Chandan Dasgupta , Srikanth Sastry

Performing molecular dynamics simulations for all-atom models, we characterize the conformational and structural relaxations of poly(ethylene oxide) and poly(propylene oxide) melts. The temperature dependence of these relaxation processes…

Soft Condensed Matter · Physics 2009-11-13 Michael Vogel

Thermal expansion of MAX phases along different directions tended to be different because of the anisotropy of hexagonal crystals. Herein, a new Hf2SeC phase was synthesized and confirmed to be relatively isotropic, whose coefficients of…

We theoretically investigate glass transition behaviors of the glassy graphene in a wide range of temperature, where this amorphous graphene is described as a hard-sphere fluid. The dynamic arrest of a particle is assumingly caused by…

Soft Condensed Matter · Physics 2020-03-11 Tran Dinh Cuong , Anh D. Phan , Katsunori Wakabayashi , Pham Thanh Huy

We consider a gauge theory of the glass transition in the frustrated XY model being simplest model containing topologically nontrivial excitations. We describe the transition kinetics and find that the three-dimensional system exhibits the…

Statistical Mechanics · Physics 2019-06-26 Mikhail Vasin

We test a hypothesis for the origin of dynamical heterogeneity in slowly relaxing systems, namely that it emerges from soft (Goldstone) modes associated with a broken continuous symmetry under time reparametrizations. We do this by…

Disordered Systems and Neural Networks · Physics 2013-10-30 Karina E. Avila , Horacio E. Castillo , Azita Parsaeian

Elastic models of the glass transition relate the relaxation dynamics and the elastic properties of structural glasses. They are based on the assumption that the relaxation dynamics occurs through activated events in the energy landscape…

Soft Condensed Matter · Physics 2015-08-20 M. Pica Ciamarra , Peter Sollich

The glass transition of supercooled fluids is a particular challenge for computer simulation, because the (longest) relaxation times increase by about 15 decades upon approaching the transition temperature T_g. Brute-force molecular…

Statistical Mechanics · Physics 2007-05-23 Kurt Binder , Jörg Baschnagel , Walter Kob , Wolfgang Paul

Upon cooling, glass-forming liquids experience a two-step relaxation associated to the cage rattling and the escape from the cage, and the following decoupling between the \b{eta}- and the {\alpha}-relaxations. The found decoupling…

Disordered Systems and Neural Networks · Physics 2017-06-07 P. Luo , P. Wen , H. Y. Bai , B. Ruta , W. H. Wang

In an attempt to quantitatively characterize the recently observed slow dynamics in the isotropic and nematic phase of liquid crystals, we investigate the single-particle orientational dynamics of rodlike molecules across the…

Soft Condensed Matter · Physics 2009-11-13 Biman Jana , Dwaipayan Chakrabarti , Biman Bagchi

The relaxation dynamics and thermodynamic properties of supercooled and glassy gambogic acid are investigated using both theory and experiment. We measure the temperature dependence of the relaxation times in three polymorphs (alpha-,…