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To solve a long-standing problem of condensed matter physics with determining a proper description of the thermodynamic evolution of the time scale of molecular dynamics near the glass transition, we extend the well-known Adam-Gibbs model…

We compare dynamical heterogeneities in equilibrated supercooled liquids and in the nonequilibrium glassy state within the framework of the random first order transition theory. Fluctuating mobility generation and transport in the glass are…

Statistical Mechanics · Physics 2014-01-21 Apiwat Wisitsorasak , Peter G. Wolynes

We have connected the dynamic fragility, namely the rapidity of the relaxation time increase upon temperature reduction, to the excess entropy and heat capacity of a large number of glass-forming polymers. The connection was obtained in a…

Soft Condensed Matter · Physics 2009-11-11 D. Cangialosi , A. Alegria , J. Colmenero

The phenomenon of the glass transition is an unresolved problem of condensed matter physics. Its prominent feature, the super-Arrhenius temperature dependence of the transport coefficients remains a challenge to be described over the full…

Soft Condensed Matter · Physics 2015-06-04 B. Schmidtke , N. Petzold , R. Kahlau , M. Hofmann , E. A. Rossler

Quantum effects in material systems are often pronounced at low energies and become insignificant at high temperatures. We find that, perhaps counterintuitively, certain quantum effects may follow the opposite route and become sharp when…

Statistical Mechanics · Physics 2015-09-08 Z. Nussinov , F. Nogueira , M. Blodgett , K. F. Kelton

In this paper, we study the thermal relaxation in the one-dimensional self-gravitating system, or the so-called sheet model. According to the standard argument, the thermal relaxation time of the system is around $Nt_c$, where $N$ is the…

Astrophysics · Physics 2007-05-23 Junichiro Makino

We review the Random First Order Transition Theory of the glass transition, emphasizing the experimental tests of the theory. Many distinct phenomena are quantitatively predicted or explained by the theory, both above and below the glass…

Disordered Systems and Neural Networks · Physics 2015-06-25 Vassiliy Lubchenko , P. G. Wolynes

Understanding and predicting the glassy dynamics of small organic molecules is critical for applications ranging from pharmaceuticals to energy and food preservation. In this work, we present a theoretical framework that combines molecular…

Soft Condensed Matter · Physics 2025-09-16 Anh D. Phan , Ngo T. Que , Nguyen T. T. Duyen

The two-dimensional XY gauge glass, which describes disordered superconducting grains in strong magnetic fields, is investigated, with regard to the possibility of a glass transition. We compute the glass susceptibility and the correlation…

Condensed Matter · Physics 2009-10-31 M. Y. Choi , Sung Yong Park

Amorphous glass-forming polymers exhibit multiple relaxation processes, including the structural {\alpha}-relaxation associated with the glass transition and faster secondary relaxations that typically follow Arrhenius behavior. Recently, a…

Soft Condensed Matter · Physics 2026-03-10 Valeriy V. Ginzburg , Oleg V. Gendelman , Simone Napolitano , Riccardo Casalini , Alessio Zaccone

We use Time Resolved Correlation (TRC), a recently introduced light scattering method, to study the dynamics of a variety of jammed, or glassy, soft materials. The output of a TRC experiment is cI(t,tau), the time series of the degree of…

Soft Condensed Matter · Physics 2009-11-10 Agnes Duri , Pierre Ballesta , Luca Cipelletti , Hugo Bissig , Veronique Trappe

We propose a scenario for the glass transition based on the cooperative nature of nucleation processes and entropic effects. The main point is the relation between the off-equilibrium energy dissipation and nucleation processes in…

Soft Condensed Matter · Physics 2009-11-07 A. Crisanti , F. Ritort

We present the temperature dependence of alpha-relaxation times of 13 glass formers determined from broadband dielectric spectroscopy, also including data from aging measurements. The data sets partly cover relaxation-time ranges of up to…

Soft Condensed Matter · Physics 2010-06-03 P. Lunkenheimer , S. Kastner , M. K öhler , A. Loidl

The dramatic slowdown of dynamics in supercooled liquids approaching the glass transition remains one of the central unresolved problems in condensed matter physics. We review approaches that attribute this slowdown to growing thermodynamic…

Soft Condensed Matter · Physics 2026-03-06 Massimo Pica Ciamarra , Jeppe C. Dyre , Edan Lerner , Matthieu Wyart

The behaviour of a model glass forming liquid is analyzed for a range of densities, with a focus on the temperature interval where the liquid begins to display non-Arrhenius temperature dependence of relaxation times. Analyzing the dynamics…

Statistical Mechanics · Physics 2007-05-23 Srikanth Sastry

The following properties are in the present literature associated with the behavior of super-cooled glass-forming liquids: faster than exponential growth of the relaxation time, dynamical heterogeneities, growing point-to-set correlation…

Statistical Mechanics · Physics 2011-01-25 Florent Krzakala , Lenka Zdeborová

At temperatures well below their glass transition, the deformation properties of bulk metallic glasses are characterised by a sharp transition from elasticity to plasticity, a reproducible yield stress, and an approximately linear decrease…

Soft Condensed Matter · Physics 2013-11-18 P. M. Derlet , R. Maaß

We develop a transferable machine learning model which predicts structural relaxation from amorphous supercooled liquid structures. The trained networks are able to predict dynamic heterogeneity across a broad range of temperatures and time…

Soft Condensed Matter · Physics 2024-02-27 Gerhard Jung , Giulio Biroli , Ludovic Berthier

We consider nonequilibrium (NEQ) states such as supercooled liquids and glasses that are described with use of internal variables. We classify the latter by state-dependent hierarchy of relaxation times to assess their relevance for…

Statistical Mechanics · Physics 2018-04-04 P. D. Gujrati

We consider the non-equilibrium dynamics of the East model, a linear chain of 0-1 spins evolving under a simple Glauber dynamics in the presence of a kinetic constraint which forbids flips of those spins whose left neighbor is 1. We focus…

Mathematical Physics · Physics 2013-09-04 Paul Chleboun , Alessandra Faggionato , Fabio Martinelli
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