Related papers: Microscopic examinations of Co valences and spin s…
The nature of the magnetic ground state of highly frustrated systems remained puzzling to this day. Here, we have performed multifrequency electron spin resonance (ESR) measurements on a putative quantum spin liquid compound…
This work reports on the temperature dependence of the electron spin resonance (ESR) of Gd$^{3+}$-doped SmB$_{6}$ single crystals at X- and Q-band microwave frequencies in different crystallographic directions. We found an anomalous…
[published in Phys. Rev. B 85, 035119 (2012)] The evolution of spin dynamics from the quantum critical system YbRh2Si2 to the stable trivalent Yb system YbCo2Si2 was investigated by Electron Spin Resonance (ESR) spectroscopy. While the…
La doped SrFeO$_{3}$, La$_{1/3}$Sr$_{2/3}$FeO$_{3}$, exhibits a metal-to-insulator transition accompanied by both antiferromagnetic and charge ordering states along with the Fe-O bond disproportionation below a critical temperature near…
Materials that exhibit both strong spin orbit coupling and electron correlation effects are predicted to host numerous new electronic states. One prominent example is the Jeff =1/2 Mott state in Sr2IrO4, where introducing carriers is…
The LaIn3-xSnx alloy system is composed of superconducting Pauli paramagnets. For LaIn3 the superconducting critical temperature T_c is approximately 0.7 K and it shows an oscillatory dependence as a function of Sn substitution, presenting…
In RBaCo_{2}O_{5+x} compounds (R is rare earth) variability of the oxygen content allows precise doping of CoO_2 planes with both types of charge carriers. We study transport properties of doped GdBaCo_{2}O_{5+x} single crystals and find a…
Kondo insulators combine strong electronic correlations with spin orbit coupling and thereby provide a potential realization of correlated topological insulators. We present model calculations which allow us to study the onset of bulk…
The nature of electronic states due to strong correlation and geometric frustration on the triangular lattice is investigated in connection to the unconventional insulating state of Na$_x$CoO$_2$ at $x=0.5$. We study an extended Hubbard…
We develop a model approach to describe charge fluctuations and different charge phases in strongly correlated 3d oxides. As a generic model system one considers that of centers each with three possible valence states described in frames of…
We present Co $L_3$-edge resonant inelastic x-ray scattering (RIXS) of bulk LaCoO$_3$ across the thermally-induced spin-state crossover around 100~K. Owing to a high energy resolution of 25~meV, we observe unambiguously the dispersion of…
The diamagnetic-paramagnetic and insulator-metal transitions in LnCoO3 perovskites (Ln = La, Y, rare earths) are reinterpreted and modeled as a two-level excitation process. In distinction to previous models, the present approach can be…
We report a soft x-ray resonant magnetic scattering study of the spin configuration in multiferroic thin films of Co$_{0.975}$Ge$_{0.025}$Cr$_2$O$_4$ (Ge-CCO) and CoCr$_2$O$_4$ (CCO), under low- and high-magnetic fields, from 0.2 T up to…
The metal-insulator and spin state transitions of CoO under high pressure are studied by using density functional theory combined with dynamical mean-field theory. Our calculations predict that the metal-insulator transition in CoO is a…
The delicate balance between spin-orbit coupling, Coulomb repulsion and crystalline electric field interactions observed in Ir-based oxides is usually manifested as exotic magnetic behavior. Here we investigate the evolution of the exchange…
Inspired by the recent discovery of high-temperature superconductivity in bilayer nickelates, we investigate the role of magnetism emerging from a hypothetical insulating $d^8$ parent state. We demonstrate that due to the interplay of…
We have examined cobalt based valence tautomer molecules such as Co(SQ)$_2$(phen) using density functional theory (DFT) and variational configuration interaction (VCI) approaches based upon a model Hamiltonian. Our DFT results extend…
Experiments on the $Gd^{3+}$ Electron Spin Resonance (ESR) in the filled skutterudite $Ce_{1-x}Gd_{x}Fe_{4}P_{12}$ ($x \approx 0.001$), at temperatures where the host resistivity manifests a smooth insulator-metal crossover, provides…
We show for the system La1-xCexCoO3 (0.1 <= x <= 0.4) that it is possible to synthesize electron-doped cobaltites by the growth of epitaxial thin films. For La1-xCexCoO3, ferromagnetic order is observed within the entire doping range (with…
We report the discovery of a ferroelectric ground state below 4.5 K in highly underdoped La_2CuO_(4+x) accompanied by slow charge dynamics which develop below T~40 K. An anisotropic magnetoelectric response has also been observed,…