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While 3$d$-containing materials display strong electron correlations, narrow band widths, and robust magnetism, 5$d$ systems are recognized for strong spin-orbit coupling, increased hybridization, and more diffuse orbitals. Combining these…

We report measurements and analysis of magnetization, resistivity and thermopower of polycrystalline samples of the perovskite-type Co/Rh oxide La$_{0.8}$Sr$_{0.2}$Co$_{1-x}$Rh$_x$O$_{3-\delta}$. This system constitutes a solid solution for…

Strongly Correlated Electrons · Physics 2015-05-19 S. Shibasaki , I. Terasaki , E. Nishibori , H. Sawa , J. Lybeck , H. Yamauchi , M. Karppinen

Recently, the iridate double perovskite Sr$_2$YIrO$_6$ has attracted considerable attention due to the report of unexpected magnetism in this Ir$^{5+}$ (5d$^4$) material, in which according to the J$_{eff}$ model, a non-magnetic ground…

Iridate heterostructures are gaining interest as their magnetic properties are much more sensitive to structural distortion compared to pure spin systems due to spin-orbital entanglement induced by strong spin-orbit coupling. While bulk…

Strongly Correlated Electrons · Physics 2021-07-16 Shubhajyoti Mohapatra , Sreemayee Aditya , Rohit Mukherjee , Avinash Singh

Transition-metal ions with $5d^2$ electronic configuration in a cubic crystal field are prone to have a vanishing dipolar magnetic moment but finite higher-order multipolar moments, and they are expected to exhibit exotic physical…

Strongly Correlated Electrons · Physics 2025-07-16 J. Okamoto , G. Shibata , Yu. S. Posonov , H. Hayashi , K. Yamaura , H. Y. Huang , A. Singh , C. T. Chen , A. Tanaka , S. V. Streltsov , D. J. Huang , A. Fujimori

Through a neutron scattering, charge transport, and magnetization study, the correlated ground state in the bilayer iridium oxide Sr$_3$Ir$_2$O$_7$ is explored. Our combined results resolve scattering consistent with a high temperature…

Motivated by the recent activities on the Ni-based diamond lattice antiferromagnet NiRh$_2$O$_4$, we theoretically explore on a general ground the unique spin and orbital physics for the Ni$^{2+}$ ions with a $3d^8$ electron configuration…

Strongly Correlated Electrons · Physics 2019-07-10 Fei-Ye Li , Gang Chen

Sr2IrO4 was predicted to be an unconventional superconductor upon carrier doping since it highly resembles the high-temperature cuprates. Here, to understand carrier doping effect on spin-orbit coupled Mott insulator Sr2IrO4, the electronic…

Strongly Correlated Electrons · Physics 2017-01-05 Jie Cheng , Xuanyong Sun , Shengli Liu , Bin Li , Haiyun Wang , Peng Dong , Yu Wang , Wei Xu

A three-orbital-model approach for studying spin wave excitations in the strongly spin-orbit coupled layered perovskite iridates is presented which provides a unified description of magnetic excitations as well as the electronic band…

Strongly Correlated Electrons · Physics 2017-04-05 Shubhajyoti Mohapatra , Jeroen van den Brink , Avinash Singh

In 5d transition metal oxides, novel properties arise from the interplay of electron correlations and spin--orbit interactions. Na4IrO4, where 5d transition-metal Ir atom occupies the center of the square-planar coordination environment, is…

Materials Science · Physics 2017-12-01 Di Wang , Feng Tang , Yongping Du , Xiangang Wan

Analogs of the high-T$_c$ cuprates have been long sought after in transition metal oxides. Due to the strong spin-orbit coupling (SOC), the $5d$ perovskite iridates Sr$_2$IrO$_4$ exhibit a low-energy electronic structure remarkably similar…

Strongly Correlated Electrons · Physics 2017-10-26 Sen Zhou , Kun Jiang , Hua Chen , Ziqiang Wang

The electronic states of many Mott insulators, including iridates, are often conceptualized in terms of localized atomic states such as the famous "$J_\text{eff}=1/2$ state". Although, orbital hybridization can strongly modify such states…

Strongly Correlated Electrons · Physics 2019-03-27 Y. Wang , Ruitang Wang , Jungho Kim , M. H. Upton , D. Casa , T. Gog , G. Cao , G. Kotliar , M. P. M. Dean , X. Liu

Effects of spin-orbit interactions in condensed matter are an important and rapidly evolving topic. Strong competition between spin-orbit, on-site Coulomb and crystalline electric field interactions in iridates drives exotic quantum states…

Strongly Correlated Electrons · Physics 2018-02-27 Gang Cao , Pedro Schlottmann

Motivated by experiments on the double perovskites La2ZnIrO6 and La2MgIrO6, we study the magnetism of spin-orbit coupled j=1/2 iridium moments on the three-dimensional, geometrically frustrated, face-centered cubic lattice. The…

Strongly Correlated Electrons · Physics 2015-09-30 A. M. Cook , S. Matern , C. Hickey , A. A. Aczel , A. Paramekanti

In the search for topological phases in correlated electron systems, iridium-based pyrochlores A2Ir2O7 -- materials with 5d transition-metal ions -- provide fertile grounds. Several novel topological states have been predicted but the…

Strongly Correlated Electrons · Physics 2015-10-21 Liviu Hozoi , H. Gretarsson , J. P. Clancy , B. -G. Jeon , B. Lee , K. H. Kim , V. Yushankhai , Peter Fulde , Young-June Kim , Jeroen van den Brink

The nature of insulating phase in 5$d$ based Sr$_2$IrO$_4$ is quite debated as the theoretical as well as experimental investigations have put forward evidences in favor of both magnetically driven Slater-type and interaction driven…

Strongly Correlated Electrons · Physics 2017-02-08 Imtiaz Noor Bhatti , A. K. Pramanik

Novel materials, which often exhibit surprising or even revolutionary physical properties, are necessary for critical advances in technologies. Simultaneous control of structural and physical properties via a small electrical current is of…

Strongly Correlated Electrons · Physics 2020-06-18 Gang Cao

By combining 5d transition-metal oxides showing pronounced spin-orbit interactions and oxide-based heterostructures, we propose rutile-based IrO2/TiO2 superlattices as promising candidates for unconventional electronic properties. By means…

Strongly Correlated Electrons · Physics 2017-02-16 Xing Ming , Kunihiko Yamauchi , Tamio Oguchi , Silvia Picozzi

$\gamma$-triclinic and $\alpha$-monoclinic polymorphs of CoV$_{2}$O$_{6}$ are two of the few known transition metal ion based materials that display stepped $1/3$ magnetization plateaus at low temperatures. Neutron diffraction [M. Markkula…

Strongly Correlated Electrons · Physics 2015-12-23 F. Wallington , A. M. Arevalo-Lopez , J. W. Taylor , J. R. Stewart , V. Garcia-Sakai , J. P. Attfield , C. Stock

We study the structural evolution of Sr$_3$Ir$_2$O$_7$ as a function of pressure using x-ray diffraction. At a pressure of 54 GPa at room temperature, we observe a first-order structural phase transition, associated with a change from…