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We have extended our experimentally constrained molecular relaxation technique (P. Biswas {\it et al}, Phys. Rev. B {\bf 71} 54204 (2005)) to hydrogenated amorphous silicon: a 540-atom model with 7.4 % hydrogen and a 611-atom model with 22…

Materials Science · Physics 2009-11-13 Parthapratim Biswas , Raymond Atta-Fynn , David A. Drabold

Water and the hydroxyl radical are major constituents of the envelope of O-rich late-type stars. Transitions involving energy levels that are highly excited have been observed in both H$_2$O and OH. These and more recently discovered…

In bulk systems, molecules are routinely identified by their vibrational spectrum using Raman or infrared spectroscopy. In recent years, vibrational excitation lines have been observed in low-temperature conductance measurements on single…

Mesoscale and Nanoscale Physics · Physics 2010-02-25 Johannes S. Seldenthuis , Herre S. J. van der Zant , Mark A. Ratner , Joseph M. Thijssen

We want to study the rotational spectra of CH$_3^{13}$C(O)CH$_3$ and $^{13}$CH$_3$C(O)CH$_3$ and search for them in Sagittarius B2(N2). We investigated the laboratory rotational spectrum of isotopically enriched CH$_3^{13}$C(O)CH$_3$…

The fundamental vibrational interval of H$_{2}^+$ has been determined to be $\Delta G _{1/2} = 2191.126\,614(17)$ cm$^{-1}$ by continuous-wave laser spectroscopy of Stark manifolds of Rydberg states of H$_2$ with the H$_{2}^+$ ion core in…

Atomic Physics · Physics 2024-01-18 Ioana Doran , Nicolas Hölsch , Maximilian Beyer , Frédéric Merkt

We present high spectral resolution mid-IR observations of SiS towards the C-rich AGB star IRC+10216 carried out with the Texas Echelon-cross-Echelle Spectrograph mounted on the NASA Infrared Telescope Facility. We have identified 204…

Solar and Stellar Astrophysics · Physics 2015-08-26 J. P. Fonfria , J. Cernicharo , M. J. Richter , M. Fernandez-Lopez , L. Velilla Prieto , J. H. Lacy

We report high angular resolution (4.9" x 3.0") images of reactive ions SH+, HOC+, and SO+ toward the Orion Bar photodissociation region (PDR). We used ALMA-ACA to map several rotational lines at 0.8 mm, complemented with multi-line…

Astrophysics of Galaxies · Physics 2017-05-31 Javier R. Goicoechea , S. Cuadrado , J. Pety , E. Bron , J. H. Black , J. Cernicharo , E. Chapillon , A. Fuente , M. Gerin

The vibrational branching ratios from the lowest excited electronic state for $\textrm{SrOCH}_3$, $\textrm{SrNH}_2$, and $\textrm{SrSH}$ are measured at the $< 0.1\%$ level. Spectra are obtained by driving the $\tilde{X} - \tilde{A}$…

Atomic Physics · Physics 2025-10-07 Alexander Frenett , Zack Lasner , Lan Cheng , John M. Doyle

New rotational line strengths for the C2 Swan system have been calculated for vibrational bands with v'=0-10 and v"=0-9, and J values up to J=34-96, based on previous observations in 30 vibrational bands. Line positions from several sources…

Solar and Stellar Astrophysics · Physics 2015-06-12 James S. A. Brooke , Peter F. Bernath , Timothy W. Schmidt , George B. Bacskay

New laboratory data of CH$_2$CHCN (vinyl cyanide) in its ground and vibrationally excited states at the microwave to THz domain allow searching for these excited state transitions in the Orion-KL line survey. Frequency-modulated…

Observations have recently indicated that the Universe at the present stage is in an accelerating expansion, a process that has great implications. We evaluate the spectrum of relic gravitational waves in the current accelerating Universe…

Astrophysics · Physics 2007-05-23 Yang Zhang , Yefei Yuan , Wen Zhao , Ying-Tian Chen

We present ALMA sub-arcsecond-resolution observations of both continuum and molecular lines at 345 GHz towards the massive star-forming region IRAS 16351-4722 (hereafter I16351). A total of 12 dust cores were detected based on high spatial…

A cryogenic 22-pole ion trap apparatus is used in combination with a table-top pulsed IR source to probe weakly bound CH$^+$-He and CH$^+$-He$_4$ complexes by predissociation spectroscopy at 4 K. The infrared photodissociation spectra of…

While it is now well established that large carbon chain species and radiative electron attachment (REA) are key ingredients triggering interstellar anion chemistry, the role played by smaller molecular anions, for which REA appears to be…

Astrophysics of Galaxies · Physics 2021-11-16 C. M. R. Rocha , H. Linnartz

We report the first detection of the S(1) pure rotational line of ortho-H2 at 17.04 um in an asymptotic giant branch star, using observations of IRC+10216 with the Echelon-cross-echelle Spectrograph (EXES) mounted on the Stratospheric…

Solar and Stellar Astrophysics · Physics 2022-03-30 J. P. Fonfría , C. N. DeWitt , E. J. Montiel , J. Cernicharo , M. J. Richter

The neutron-rich carbon isotopes 19,17C have been investigated via proton inelastic scattering on a liquid hydrogen target at 70 MeV/nucleon. The invariant mass method in inverse kinematics was employed to reconstruct the energy spectrum,…

Linear carbon chains are common in various types of astronomical molecular sources. Possible formation mechanisms involve both bottom-up and top-down routes. We have carried out a combined observational and modeling study of the formation…

Observations towards IRC +10216 of CS, SiO, SiS, NaCl, KCl, AlCl, AlF, and NaCN have been carried out with the IRAM 30-m telescope in the 80-357.5 GHz frequency range. A large number of rotational transitions covering a wide range of energy…

Astrophysics of Galaxies · Physics 2015-06-04 M. Agundez , J. P. Fonfria , J. Cernicharo , C. Kahane , F. Daniel , M. Guelin

Rovibrational quantum states in the $X^1\Sigma_g^+$ electronic ground state of H$_2$ are prepared in the $v=13$ vibrational level up to its highest bound rotational level $J=7$, and in the highest bound vibrational level $v=14$ (for $J=1$)…

Chemical Physics · Physics 2021-06-09 K. -F. Lai , M. Beyer , E. J. Salumbides , W. Ubachs