Related papers: Vibrationally Excited C$_4$H
We present results from our ALMA Cycle 0 observations, at the frequencies around the HCN, HCO+, and HNC J=4-3 transition lines, of the luminous infrared galaxy IRAS 20551-4250 at z=0.043, which is known to host an energetically important…
We report new Atacama Large Millimeter/Submillimeter Array (ALMA) observations of a circumstellar disk around Source I in Orion KL, an archetype of massive protostar candidate. We detected two ortho-H$_{2}$O lines at 321 GHz…
The spectral investigation of the triply ionized gold (Au IV) has been carried out in the wavelength region of 500--2106 {\AA}. The gold spectra were photographed at the National Institute of Standards and Technology (NIST, USA) on a 10.7-m…
We found four series of harmonically related lines in IRC\,+10216 with the Yebes\,40m and IRAM\,30m telescopes. The first series corresponds to a molecule with a rotational constant, $B$, of 1448.5994$\pm$0.0013 MHz and a distortion…
We report electronic, vibrational, and rotational spectroscopic parameters for the ground state, X$^2\Sigma^{+}$, of singly charged aluminium monohalides, employing single-reference coupled-cluster theory with single and double excitations…
We identify the molecular ion NH^+ as a potential candidate for probing variations in the fine structure constant alpha and electron-to-proton mass ratio mu. NH^+ has an anomalously low-lying excited Sigma state, being only a few hundred…
We report the detection of a strong submillimeter wavelength HCN laser line at a frequency near 805 GHz toward the carbon star IRC+10216. This line, the J=9-8 rotational transition within the (04(0)0) vibrationally excited state, is one of…
Low-frequency Raman peaks, below 250 cm-1, are observed in hydrogen between 2-174 GPa and 13-300 K. The origin of these features is attributed to reorientational transitions (DeltaJ = 0; Q0-branch), which shift from the Rayleigh line as…
The term values of all rotational levels of the $^4$He${_2}^+\,X^+\,^2\Sigma_u^+\,(\nu^+=0)$ ground vibronic state with rotational quantum number $N^+\le 19$ have been determined with an accuracy of 8 x 10$^{-4}$ cm$^{-1}$ ($\sim{25}$ MHz)…
We present the unambiguous discovery of six new class II methanol maser transitions, three of which are torsionally excited (vt=1). The newly discovered 6.18-GHz 17_-2 -> 18_-3 E (vt=1), 7.68-GHz 12_4 -> 13_3 A- (vt=0), 7.83-GHz 12_4 ->…
We synthesized the astrochemically relevant molecule 3-hydroxypropanal (HOCH$_2$CH$_2$CHO) and subsequently measured and analyzed its rotational spectrum in several frequency regions ranging from 130 to 485 GHz. We analyzed the ground…
AGB stars are major contributors to the chemical enrichment of the ISM through nucleosynthesis and extensive mass loss. Most of our current knowledge of AGB atmospheric and circumstellar chemistry, in particular in a C-rich environment, is…
We report on the observation of coherent molecular vibrations launched by the breaking of a molecular bond. The methyl radical, which is produced by $267\,\mathrm{nm}$ photodissociation of methyl iodide, is excited to high levels in its…
Chemiluminescent radiation of the vibrationally and rotationally excited OH radical, which dominates the nighttime near-infrared emission of the Earth's atmosphere in wide wavelength regions, is an important tracer of the chemical and…
The first excited torsional state of the chiral molecule propylene oxide, $\mathrm{CH_{3}C_{2}H_{3}O}$, is investigated from millimeter up to sub-millimeter wavelengths (75-950 GHz). The first excited vibrational mode of propylene oxide,…
High-precision variational calculations of the operators for the relativistic corrections in the leading $m\alpha^4$ order are presented. The ro-vibrational states in the range of the total orbital angular momentum $L\!=\!0\!-\!4$ and…
We present a mid-infrared high spectral resolution spectrum of CRL618 in the frequency ranges 778-784 and 1227-1249 cm^-1 (8.01-8.15 and 12.75-12.85 um) taken with the Texas Echelon-cross-Echelle Spectrograph (TEXES) and the Infrared…
The $\mathrm{\tilde{C}}$ $^1$B$_2$ state of SO$_2$ has a double-minimum potential in the antisymmetric stretch coordinate, such that the minimum energy geometry has nonequivalent SO bond lengths. However, low-lying levels with odd quanta of…
The evidence for benzonitrile (C$_6$H$_5$CN}) in the starless cloud core TMC-1 makes high-resolution studies of other aromatic nitriles and their ring-chain derivatives especially timely. One such species is phenylpropiolonitrile…
The observation of a wide peaking structure in the $B_{c}^{+} \gamma$ mass spectrum is reported using proton-proton collision data collected by the LHCb detector at center-of-mass energies of $7$, $8$, and $13~\text{TeV}$, corresponding to…