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CsCa$_2$Fe$_4$As$_4$F$_2$ is a newly discovered iron-based superconductor with $T_\mathrm{c}\sim$ 30 K containing double Fe$_2$As$_2$ layers that are separated by insulating Ca$_2$F$_2$ spacer layers. Here we report the transport and…

Superconductivity · Physics 2019-04-10 Zhi-Cheng Wang , Yi Liu , Si-Qi Wu , Ye-Ting Shao , Zhi Ren , Guang-Han Cao

Magnetization, susceptibility, specific heat, resistivity, neutron and x-ray diffraction have been used to characterize the properties of single crystalline CaFe2-xNixAs2 as a function of Ni doping for x varying from 0 to 0.1. The combined…

We have discovered a new iron pnictide oxide superconductor (Fe2As2)(Sr4(Mg,Ti)2O6). This material is isostructual with (Fe2As2)(Sr4M2O6) (M = Sc, Cr), which was found in our previous study. The structure of this compound is tetragonal with…

Superconductivity · Physics 2010-03-26 Shinya Sato , Hiraku Ogino , Naoto Kawaguchi , Yukari Katsura , Kohji Kishio , Jun-ichi Shimoyama

We used low-temperature synchrotron x-ray diffraction to investigate the structural phase transitions of Fe1+yTe in the vicinity of a tricitical point in the phase diagram. Detailed analysis of the powder diffraction patterns and…

Superconductivity · Physics 2013-10-03 Cevriye Koz , Sahana Rößler , Alexander A. Tsirlin , Steffen Wirth , Ulrich Schwarz

In a superconductor electrons form pairs and electric transport becomes dissipation-less at low temperatures. Recently discovered iron based superconductors have the highest superconducting transition temperature next to copper oxides. In…

Materials Science · Physics 2014-12-02 Xianhui Chen , Pengcheng Dai , Donglai Feng , Tao Xiang , Fu-Chun Zhang

We study the crystal structure of the tetragonal iron selenide FeSe and its nematic phase transition to the low-temperature orthorhombic structure using synchrotron x-ray and neutron scattering analyzed in both real and reciprocal space. We…

Iron-based superconductors can be categorized as two types of parent compounds by considering the nature of their temperature-induced phase transitions; namely, first order transitions for 122- and 11-type compounds and second-order…

Pressure-dependent diffraction response of the superconducting phase separated Cs0.72Fe1.57Se2 has been studied using synchrotron radiation up to the pressure of 19 GPa. The main and secondary phases of Cs0.72Fe1.57Se2 have been observed in…

The Ca10(PtnAs8)(Fe2As2)5 (n=3,4) compounds are a new type of iron pnictide superconductors whose structures consist of stacking Ca-PtnAs8-Ca-Fe2As2 layers in a unit cell. When n=3 (the 10-3-8 phase), the undoped compound is an…

Superconductivity · Physics 2023-02-06 Peiwen Gao , Liling Sun , Ni Ni , Jing Guo , Qi Wu , Chao Zhang , Dachun Gu , Ke Yang , Sheng Jiang , Robert Joseph Cava , Zhongxian Zhao

We report the detailed analysis of temperature dependent neutron diffraction pattern of the Cr$_2$CoAl inverse Heusler alloy and unveil the magnetic structure up to the phase transition as well as its fully compensated ferrimagnetic nature.…

Strongly Correlated Electrons · Physics 2023-03-22 Guru Dutt Gupt , Yousef Kareri , James Hester , Clemens Ulrich , R. S. Dhaka

We have recently predicted and subsequently verified experimentally by specific heat measurements that EuTiO3 undergoes a structural phase transition at elevated temperature TS = 282 K. The origin of the phase transition has been attributed…

Materials Science · Physics 2012-05-25 J. Köhler , R. Dinnebier , A. Bussmann-Holder

TThe parent compounds of iron-arsenide superconductors, $A$Fe$_{2}$As$_{2}$ ($A$=Ca, Sr, Ba), undergo a tetragonal to orthorhombic structural transition at a temperature $T_{\mathrm{TO}}$ in the range 135 to 205K depending on the alkaline…

Strongly Correlated Electrons · Physics 2015-05-18 M. A. Tanatar , E. C. Blomberg , A. Kreyssig , M. G. Kim , N. Ni , A. Thaler , S. L. Bud'ko , P. C. Canfield , A. I. Goldman , I. I. Mazin , R. Prozorov

We present temperature-dependent single-crystal diffraction results on seven antifluorite-type $A_2MeX_6$ compounds with $Me$=Os or Ir: K$_2$OsCl$_6$, $A_2$OsBr$_6$ with $A$=K, Rb, Cs and NH$_4$, and K$_2$Ir$X_6$ with $X$=Cl and Br. The…

Materials Science · Physics 2024-03-19 A. Bertin , L. Kiefer , P. Becker , L. Bohatý , M. Braden

A displacive, 2nd order structural phase transition at Ts=395 K from space group I`4 2 m below Ts to I 4/m c m above Ts has been discovered in the two-dimensional spin dimer compound SrCu2(BO3)2. The temperature evolution of the structure…

Strongly Correlated Electrons · Physics 2009-10-31 K. Sparta , G. J. Redhammer , P. Roussel , G. Heger , G. Roth , P. Lemmens , A. Ionescu , M. Grove , G. Guentherodt , F. Huening , H. Lueken , H. Kageyama , K. Onizuka , Y. Ueda

The nature of the phase separation in KxFe2-ySe2 single crystals is not well understood. Here, temperature dependent SEM images provide compelling evidence that phase separation corresponds to a nucleation and growth process rather than a…

Superconductivity · Physics 2016-02-12 Yong Liu , Qingfeng Xing , Warren E. Straszheim , Jeff Marshman , Pal Pedersen , Thomas A. Lograsso

We present a calorimetric study on single crystals of Ca(Fe1-xCox)2As2 (x = 0, 0.032, 0.051, 0.056, 0.063, and 0.146). The combined first order spin-density wave/structural transition occurs in the parent CaFe2As2 compound at 168 K and…

Superconductivity · Physics 2015-05-30 M. Abdel-Hafiez , L. Harnagea , S. Singh , U. Stockert , S. Wurmehl , R. Klingeler , A. U. B. Wolter , B. Buechner

CaFe$_2$As$_2$ has been found to be exceptionally sensitive to the application of hydrostatic pressure and superconductivity has been found to exist in a narrow pressure region that appears to be at the interface between two different phase…

Superconductivity · Physics 2009-11-13 Milton S. Torikachvili , Sergey L. Bud'ko , Ni Ni , Paul C. Canfield

LaRu$_3$Si$_2$ is of current research interest as a kagome metal with a superconducting transition temperature, $T_c\sim$7 K and higher temperature charge density wave (CDW) orders. Here we report electrical transport and X-ray diffraction…

The discovery of high temperature superconductivity in La[O1-xFx]FeAs at the beginning of this year [1] has generated much excitement and has led to the rapid discovery of similar compounds with as high as 55 K transition temperatures [2].…

Superconductivity · Physics 2008-06-30 M. C. Boyer , Kamalesh Chatterjee , W. D. Wise , G. F. Chen , J. L. Luo , N. L. Wang , E. W. Hudson

The superconducting and structural properties of a series of Mg1-xAlxB2 samples have been investigated. X-ray diffraction results confirmed the existence of a structural transition associated with the significant change in inter-boron layer…

Superconductivity · Physics 2009-11-07 J. Y. Xiang , D. N. Zheng , J. Q. Li , L. Li , P. L. Lang , H. Chen , C. Dong , G. C. Che , Z. A. Ren , H. H. Qi , H. Y. Tian , Y. M. Ni , Z. X. Zhao