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In this letter we show that superconducting Fe1.01Se undergoes a structural transition at 90 K from a tetragonal to an orthorhombic phase but that non-superconducting Fe1.03Se does not. Further, high resolution electron microscopy study at…

Superconductivity · Physics 2009-08-11 T. M. McQueen , A. J. Williams , P. W. Stephens , J. Tao , Y. Zhu , V. Ksenofontov , F. Casper , C. Felser , R. J. Cava

With single crystal X-ray diffraction studies, we compare the structures of three sample showing optimal superconductivity, K0.774(4)Fe1.613(2)Se2, K0.738(6)Fe1.631(3)Se2 and Cs0.748(2)Fe1.626(1)Se2. All have an almost identical ordered…

Superconductivity · Physics 2015-05-27 P. Zavalij , Wei Bao , X. F. Wang , J. J. Ying , X. H. Chen , D. M. Wang , J. B. He , X. Q. Wang , G. F Chen , P-Y Hsieh , Q. Huang , M. A. Green

Pressure dependence of the electronic and crystal structures of K$_{x}$Fe$_{2-y}$Se$_{2}$, which has pressure-induced two superconducting domes of SC I and SC II, was investigated by x-ray emission spectroscopy and diffraction. X-ray…

The fluorine-doped rare-earth iron oxyarsenides, REFeAsO1-xFx (RE =rare earth) have recently emerged as a new family of high-temperature superconductors with transition temperatures (Tc) as high as 55 K (refs 1-4). Early work has provided…

Another phase transition that is probably of first order is found in the beta-pyrochlore oxide superconductor KOs2O6 with a superconducting transition temperature Tc of 9.6 K. It takes place at Tp=7.5 K in the superconducting state in a…

Superconductivity · Physics 2015-06-25 Z Hiroi , S Yonezawa , J Yamaura

We have grown intermetallic ErPd$_2$Si$_2$ single crystals employing laser-diodes with the floating-zone method. The temperature-dependent crystallography was determined using synchrotron and in-house X-ray powder diffraction measurements…

Materials Science · Physics 2022-08-02 Kaitong Sun , Yinghao Zhu , Si Wu , Junchao Xia , Pengfei Zhou , Qian Zhao , Chongde Cao , Hai-Feng Li

The interplay between superconductivity, magnetism and crystal structure in iron-based superconductors is a topic of great interest amongst the condensed matter physics community as it is thought to be the key to understanding the…

We have investigated low-temperature crystal structure of BiCh2-based compounds LaO1-xFxBiSSe (x = 0, 0.01, 0.02, 0.03, and 0.5), in which anomalous two-fold-symmetric in-plane anisotropy of superconducting states has been observed for x =…

In this paper, nominal compositions of NdFeAsO0.8F0.2, NdFeAs0.95Sb0.05O0.8F0.2 and NdFeAs0.95P0.05O0.8F0.2 were prepared by one step solid state reaction method. The structural, electrical and morphological properties of samples were…

Materials Science · Physics 2019-01-04 Z. Alborzi , V. Daadmehr

The magnetic structure of superconducting Eu(Fe0.82Co0.18)2As2 is unambiguously determined by single-crystal neutron diffraction. A long-range ferromagnetic order of the Eu2+ moments along the c-direction is revealed below the magnetic…

Superconductivity · Physics 2014-05-06 W. T. Jin , S. Nandi , Y. Xiao , Y. Su , O. Zaharko , Z. Guguchia , Z. Bukowski , S. Price , W. H. Jiao , G. H. Cao , Th. Brueckel

The structural and magneto-transport properties of type-II Dirac semimetal candidate Ir2In8S have been investigated under high pressure. The ambient tetragonal structure (P4_2/mnm) is found to be stable up to 7 GPa, above which the system…

Superconductivity · Physics 2022-05-23 Pallavi Malavi , Prakash Kumar , Navita Jakhar , Surjeet Singh , S. Karmakar

Superconductivity was recently observed in the iron-arsenic-based compounds with a superconducting transition temperature (Tc) as high as 56K [1-7], naturally raising comparisons with the high Tc copper oxides. The copper oxides have…

Superconductivity · Physics 2009-11-13 H. Q. Yuan , J. Singleton , F. F. Balakirev , S. A. Baily , G. F. Chen , J. L. Luo , N. L. Wang

Tb2Ti2O7, a pyrochlore system, has garnered significant interest due to its intriguing structural and physical properties and their dependence on external physical parameters. In this study, utilizing high-brilliance synchrotron X-ray…

In this paper we report the synthesis of iron-based superconductors CaFe2-xRhxAs2 using one-step solid state reaction method, which crystallizes in the ThCr2Si2-type structure with a space group I4/mmm. The systematic evolution of the…

Superconductivity · Physics 2015-05-19 Yanpeng Qi , Lei Wang , Zhaoshun Gao , Dongliang Wang , Xianping Zhang , Chunlei Wang , Chao Yao , Yanwei Ma

At ambient pressure CaFe2As2 has been found to undergo a first order phase transition from a high temperature, tetragonal phase to a low temperature orthorhombic / antiferromagnetic phase upon cooling through T ~ 170 K. With the application…

Neutron diffraction measurements on a high quality single crystal of CeAu2Ge2 reveal two new magnetic structures that coexist with commensurate long range antiferromagnetic order below the Neel temperature T_N ~ 14 K. The new magnetic…

Strongly Correlated Electrons · Physics 2012-09-03 D. K. Singh , A. Thamizhavel , J. W. Lynn , S. K. Dhar , T. Hermann

Evidence for another phase transition at 120 K in the metallic pyrochlore oxide Cd2Re2O7, following the structural transition at 200 K and followed by the superconducting transition at 1.0 K, is given through resistivity, magnetoresistance,…

Strongly Correlated Electrons · Physics 2009-11-07 Zenji Hiroi , Jun-Ichi Yamaura , Yuji Muraoka , Masafumi Hanawa

Superconductivity has been found in the iron-arsenides with different structures by alternative stacking of the conducting Fe2As2 layers and spacer layers including alkali- or alkali-earth metal ions and PbO- or perovskite-type oxides…

Superconductivity · Physics 2015-06-17 X. F. Lu , N. Z. Wang , G. H. Zhang , X. G. Luo , Z. M. Ma , B. Lei , F. Q. Huang , X. H. Chen

A caged compound CeOs2Al10, crystallizing in the orthorhombic YbFe2Al10-type structure, undergoes a mysterious phase transition at T_0=29 K. We report the results of electron diffraction, magnetization, and magnetoresistance for single…

Strongly Correlated Electrons · Physics 2015-05-19 Y. Muro , J. Kajino , K. Umeo , K. Nishimoto , R. Tamura , T. Takabatake

Synchrotron X-ray diffraction (XRD) experiments were performed on the network compounds Ba1-xSrxAl2O4 at temperatures between 15 and 800 K. The ferroelectric phase of the parent BaAl2O4 is largely suppressed by the Sr-substitution and…

Materials Science · Physics 2016-09-07 S. Kawaguchi , Y. Ishii , E. Tanaka , H. Tsukasaki , Y. Kubota , S. Mori
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