English

Temperature-dependent structure of an intermetallic ErPd$_2$Si$_2$ single crystal: A combined synchrotron and in-house X-ray diffraction study

Materials Science 2022-08-02 v1

Abstract

We have grown intermetallic ErPd2_2Si2_2 single crystals employing laser-diodes with the floating-zone method. The temperature-dependent crystallography was determined using synchrotron and in-house X-ray powder diffraction measurements from 20 to 500 K. The diffraction patterns fit well with the tetragonal II4/mmmmmm space group (No. 139) with two chemical formulas within one unit cell. Our synchrotron X-ray powder diffraction study shows that the refined lattice constants are aa = 4.10320(2) {\AA}, cc = 9.88393(5) {\AA} at 298 K and aa = 4.11737(2) {\AA}, cc = 9.88143(5) {\AA} at 500 K, resulting in the unit-cell volume VV = 166.408(1) {\AA}3^3 (298 K) and 167.517(2) {\AA}3^3 (500 K). In the whole studied temperature range, we did not find any structural phase transition. Upon cooling, the lattice constants a and c are shortened and elongated, respectively.

Keywords

Cite

@article{arxiv.2203.16212,
  title  = {Temperature-dependent structure of an intermetallic ErPd$_2$Si$_2$ single crystal: A combined synchrotron and in-house X-ray diffraction study},
  author = {Kaitong Sun and Yinghao Zhu and Si Wu and Junchao Xia and Pengfei Zhou and Qian Zhao and Chongde Cao and Hai-Feng Li},
  journal= {arXiv preprint arXiv:2203.16212},
  year   = {2022}
}

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5 Figures, 4 Tables