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Tetragonal beta-FeSe obtained by hydrothermal reaction is not superconducting and transforms to a triclinic structure at 60 K unlike superconducting FeSe from solid state synthesis, which becomes orthorhombic at 90 K. In contrast,…

Superconductivity · Physics 2015-10-28 Ursula Pachmayr , Natalie Fehn , Dirk Johrendt

We report measurements of structural phase transition of four parent compounds $R$FeAsO ($R$ = La, Sm, Gd, and Tb) by means of low-temperature X-ray diffraction (XRD). Magnetic transition temperatures associated with Fe ions ($T_{N1}$) are…

Here we report the synthesis and discovery of superconductivity in a novel ternary iridium-arsenide compound BaIr2As2. The polycrystalline BaIr2As2 sample was synthesized by a high temperature and high pressure method. Crystal structural…

Superconductivity · Physics 2017-08-22 Xiao-Chuan Wang , Bin-Bin Ruan , Jia Yu , Bo-Jin Pan , Qing-Ge Mu , Tong Liu , Gen-Fu Chen , Zhi-An Ren

Two-dimensional iron-chalcogenide intercalates display a remarkable correlation of the interlayer spacing with the enhancement of the superconducting critical temperature ($T_c$). In this work, synchrotron x-ray absorption ($XAS$, at Fe and…

The ternary iron arsenide BaFe2As2 with the tetragonal ThCr2Si2-type structure exhibits a spin density wave (SDW) anomaly at 140 K, very similar to LaFeAsO, the parent compound of the iron arsenide superconductors. BaFe2As2 is a poor…

Single crystals of SrFe2-xPtxAs2 (0 < x < 0.36) were grown using the self flux solution method and characterized using x-ray crystallography, electrical transport, magnetic susceptibility, and specific heat measurements. The…

Superconductivity · Physics 2010-10-21 Kevin Kirshenbaum , Shanta R. Saha , Tyler Drye , Johnpierre Paglione

Exploration of new superconductors has always been one of the research directions in condensed matter physics. We report here a new layered heterostructure of [(Fe,Al)(OH)2][FeSe]1.2, which is synthesized by the hydrothermal ion-exchange…

The nature of the pseudogap in high transition temperature (high-Tc) superconducting cuprates has been a major issue in condensed matter physics. It is still unclear whether the high-Tc superconductivity can be universally associated with…

Using one-step solid state reaction method, we have successfully synthesized the superconductor SrFe1-xRuxAs. X-ray diffraction indicates that the material has formed the ThCr2Si2-type structure with a space group I4/mmm. The systematic…

Superconductivity · Physics 2015-05-13 Yanpeng Qi , Lei Wang , Zhaoshun Gao , Dongliang Wang , Xianping Zhang , Yanwei Ma

X-ray diffraction indicates that the structure of the recently discovered room temperature carbonaceous sulfur hydride (C-S-H) superconductor is derived from previously established van der Waals compounds found in the H$_2$S-H$_2$ and…

CaFe$_2$As$_2$ has been synthesized and found to form in the tetragonal, ThCr$_2$Si$_2$ structure with lattice parameters $a = 3.912(68) \AA$ and $c = 11.667(45) \AA$. Upon cooling through 170 K, CaFe$_2$As$_2$ undergoes a first order,…

Strongly Correlated Electrons · Physics 2009-11-13 N. Ni , S. Nandi , A. Kreyssig , A. I. Goldman , E. D. Mun , S. L. Bud'ko , P. C. Canfield

Superconductivity in Iron-Arsenic based pnictides emerges in close proximity to an antiferromagnetic (AFM)ordered parent state and the AFM phase overlaps with superconducting (SC) phase in some pnictides for certain range of doping.…

Strongly Correlated Electrons · Physics 2015-01-20 Anirban Dutta , Neeraj Kumar , A. Thamizhavel , Anjan K. Gupta

Neutron and x-ray diffraction measurements are presented for powders and single crystals of CaCo{1.86}As2. The crystal structure is a collapsed-tetragonal ThCr2Si2-type structure as previously reported, but with 7(1)% vacancies on the Co…

Materials with graphene-like layers attract tremendous attention due to their electronic structures and superconducting properties. In this study, we synthesized LaP2 polycrystalline and observed a superconducting transition around 30 GPa.…

Superconductivity · Physics 2025-11-18 Mingxin Zhang , Cuiying Pei , Bangshuai Zhu , Qi Wang , Juefei Wu , Yanpeng Qi

We synthesized the samples Sr$_{1-x}$Sm$_x$FFeAs with ZrCuSiAs-type structure. These samples were characterized by resistivity and susceptibility. It is found that substitution of rare earth metal for alkaline earth metal in this system…

Superconductivity · Physics 2009-03-20 G. Wu , Y. L. Xie , H. Chen , M. Zhong , R. H. Liu , B. C. Shi , Q. J. Li , X. F. Wang , T. Wu , Y. J. Yan , J. J. Ying , X. H. Chen

The recent discovery of high temperature superconductivity in a layered iron arsenide has led to an intensive search to optimize the superconducting properties of iron-based superconductors by changing the chemical composition of the spacer…

We report the successful substitution of cobalt, nickel, and copper for iron in the 1038 phase parent compound Ca$_{10}$(FeAs)$_{10}$(Pt$_3$As$_8$) yielding Ca$_{10}$(Fe$_{1-x}$Co$_x$As)$_{10}$(Pt$_3$As$_8$),…

Superconductivity · Physics 2014-10-29 Tobias Stürzer , Fabian Kessler , Dirk Johrendt

The recently discovered quaternary arsenide oxide superconductor La[O1-xFx]FeAs with the superconducting critical transition temperature (Tc) of 26 K [1], has been quickly expanded to another high-Tc superconducting system beyond copper…

New iron selenide superconductors by intercalating smaller-sized alkali metals (Li, Na) and alkaline earths using high-temperature routes have been pursued ever since the discovery of superconductivity at about 30 K in KFe2Se2, but all have…

Superconductivity · Physics 2012-05-30 T. P. Ying , X. L. Chen , G. Wang , S. F. Jin , T. T. Zhou , X. F. Lai , H. Zhang , W. Y. Wang

We study superconductivity in the superionic phase of the clathrate hydride Li$_2$MgH$_{16}$, where hydrogen ions diffuse among the lattice formed by lithium and magnesium ions. By employing the stochastic path-integral approach, we…

Superconductivity · Physics 2024-06-13 Haoran Chen , Junren Shi