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Statistical mechanics can only be ultimately justified in terms of microscopic dynamics (classical, quantum, relativistic, or any other). It is known that Boltzmann-Gibbs statistics is based on the hypothesis of exponential sensitivity to…

Statistical Mechanics · Physics 2009-11-10 Constantino Tsallis

In this lecture we briefly review the definition, consequences and applications of an entropy, $S_q$, which generalizes the usual Boltzmann-Gibbs entropy $S_{BG}$ ($S_1=S_{BG}$), basis of the usual statistical mechanics, well known to be…

Statistical Mechanics · Physics 2007-05-23 Constantino Tsallis , Fulvio Baldovin , Roberto Cerbino , Paolo Pierobon

A new concept named nonsymmetric entropy which generalizes the concepts of Boltzman's entropy and shannon's entropy, was introduced. Maximal nonsymmetric entropy principle was proven. Some important distribution laws were derived naturally…

Information Theory · Computer Science 2007-07-13 Chengshi Liu

Asymptotically entropy of chaotic systems increases linearly and the sensitivity to initial conditions is exponential with time: these two behaviors are related. Such relationship is the analogous of and under specific conditions has been…

Statistical Mechanics · Physics 2011-01-04 Roberto Tonelli , Giuseppe Mezzorani , Franco Meloni , Marcello Lissia , Massimo Coraddu

J. Willard Gibbs published a book in 1902 on statistical mechanics that quickly received significant attention from his contemporaries because of the reputation that he had secured with his prior work on thermodynamics. People reading…

History and Philosophy of Physics · Physics 2024-12-17 Bruce D. Popp

This contribution inquires into Clausius' proposal that "the entropy of the world tends to a maximum.'" The question is raised whether the entropy of "the world" actually does have a maximum; and if the answer is "Yes!," what such states of…

History and Philosophy of Physics · Physics 2019-06-11 Michael K. -H. Kiessling

The factorization problem of $q$-exponential distribution within nonextensive statistical mechanics is discussed on the basis of Abe's general pseudoadditivity for equilibrium systems. it is argued that the factorization of compound…

Statistical Mechanics · Physics 2009-11-07 Qiuping A. Wang

The combinatorial basis of entropy by Boltzmann can be written $H= {N}^{-1} \ln \mathbb{W}$, where $H$ is the dimensionless entropy of a system, per unit entity, $N$ is the number of entities and $\mathbb{W}$ is the number of ways in which…

Mathematical Physics · Physics 2009-11-13 Robert K. Niven

Starting from the BBGKY hierarchy, describing the kinetics of nonlinear particle system, we obtain the relevant entropy and stationary distribution function. Subsequently, by employing the Lorentz transformations we propose the relativistic…

Statistical Mechanics · Physics 2012-06-12 G. Kaniadakis

Based on the q-exponential distribution which has been observed in more and more physical systems, the varentropy method is used to derive the uncertainty measure of such an abnormal distribution function. The uncertainty measure obtained…

Mathematical Physics · Physics 2010-09-07 Congjie Ou , Aziz El Kaabouchi , Qiuping A. Wang , Jincan Chen

In ordinary statistical mechanics the Boltzmann-Shannon entropy is related to the Maxwell-Bolzmann distribution $p_i$ by means of a twofold link. The first link is differential and is offered by the Jaynes Maximum Entropy Principle. The…

Statistical Mechanics · Physics 2009-10-02 G. Kaniadakis

Boltzmann-Gibbs statistical mechanics applies satisfactorily to a plethora of systems. It fails however for complex systems generically involving strong space-time entanglement. Its generalization based on nonadditive $q$-entropies…

Statistical Mechanics · Physics 2021-01-15 R. M. de Oliveira , Samuraí Brito , L. R. da Silva , Constantino Tsallis

For a dynamical system far from equilibrium, one has to deal with empirical probabilities defined through time-averages, and the main problem is then how to formulate an appropriate statistical thermodynamics. The common answer is that the…

Statistical Mechanics · Physics 2009-11-10 A. Carati

Tsallis has suggested a nonextensive generalization of the Boltzmann-Gibbs entropy, the maximization of which gives a generalized canonical distribution under special constraints. In this brief report we show that the generalized canonical…

Statistical Mechanics · Physics 2021-04-28 Brian R. La Cour , William C. Schieve

Translation of Ludwig Boltzmann's paper "\"Uber die Eigenschaften monozyklischer und anderer damit verwandter Systeme" Crelles Journal 98. S. 68-94. 1884 u. 1885 from German into English. In this foundational paper Boltzmann introduced two…

History and Philosophy of Physics · Physics 2019-06-24 Ludwig Boltzmann

The cornerstones of Boltzmann-Gibbs and nonextensive statistical mechanics respectively are the entropies $S_{BG} \equiv -k \sum_{i=1}^W p_i \ln p_i $ and $S_{q}\equiv k (1-\sum_{i=1}^Wp_i^{q})/(q-1) (q\in{\mathbb R} ; S_1=S_{BG})$. Through…

Statistical Mechanics · Physics 2017-08-23 Constantino Tsallis

Thermodynamics makes definite predictions about the thermal behavior of macroscopic systems in and out of equilibrium. Statistical mechanics aims to derive this behavior from the dynamics and statistics of the atoms and molecules making up…

Statistical Mechanics · Physics 2018-03-28 Sheldon Goldstein , David A. Huse , Joel L. Lebowitz , Pablo Sartori

We prove that information-theoretic maximum entropy (MaxEnt) approach to canonical ensemble is mathematically equivalent to the classic approach of Boltzmann, Gibbs and Darwin-Fowler. The two approaches, however, "interpret" a same…

Statistical Mechanics · Physics 2011-06-01 Hao Ge , Hong Qian

A question that is currently highly debated is whether the microcanonical entropy should be expressed as the logarithm of the phase volume (volume entropy, also known as the Gibbs entropy) or as the logarithm of the density of states…

Statistical Mechanics · Physics 2015-05-28 Michele Campisi

Boltzmann's principle is used to select the "most probable" realization (macrostate) of an isolated or closed thermodynamic system, containing a small number of particles ($N \llsp \infty$), for both classical and quantum statistics. The…

Statistical Mechanics · Physics 2015-05-13 Robert K. Niven