English

Combinatorial Entropy for Distinguishable Entities in Indistinguishable States

Mathematical Physics 2009-11-13 v2 math.MP

Abstract

The combinatorial basis of entropy by Boltzmann can be written H=N1lnWH= {N}^{-1} \ln \mathbb{W}, where HH is the dimensionless entropy of a system, per unit entity, NN is the number of entities and W\mathbb{W} is the number of ways in which a given realization of the system can occur, known as its statistical weight. Maximizing the entropy (``MaxEnt'') of a system, subject to its constraints, is then equivalent to choosing its most probable (``MaxProb'') realization. For a system of distinguishable entities and states, W\mathbb{W} is given by the multinomial weight, and HH asymptotically approaches the Shannon entropy. In general, however, W\mathbb{W} need not be multinomial, leading to different entropy measures. This work examines the allocation of distinguishable entities to non-degenerate or equally degenerate, indistinguishable states. The non-degenerate form converges to the Shannon entropy in some circumstances, whilst the degenerate case gives a new entropy measure, a function of a multinomial coefficient, coding parameters, and Stirling numbers of the second kind.

Keywords

Cite

@article{arxiv.0709.3124,
  title  = {Combinatorial Entropy for Distinguishable Entities in Indistinguishable States},
  author = {Robert K. Niven},
  journal= {arXiv preprint arXiv:0709.3124},
  year   = {2009}
}

Comments

Manuscript for CTNEXT07, Catania, draft

R2 v1 2026-06-21T09:19:18.572Z