Combinatorial Entropy for Distinguishable Entities in Indistinguishable States
Abstract
The combinatorial basis of entropy by Boltzmann can be written , where is the dimensionless entropy of a system, per unit entity, is the number of entities and is the number of ways in which a given realization of the system can occur, known as its statistical weight. Maximizing the entropy (``MaxEnt'') of a system, subject to its constraints, is then equivalent to choosing its most probable (``MaxProb'') realization. For a system of distinguishable entities and states, is given by the multinomial weight, and asymptotically approaches the Shannon entropy. In general, however, need not be multinomial, leading to different entropy measures. This work examines the allocation of distinguishable entities to non-degenerate or equally degenerate, indistinguishable states. The non-degenerate form converges to the Shannon entropy in some circumstances, whilst the degenerate case gives a new entropy measure, a function of a multinomial coefficient, coding parameters, and Stirling numbers of the second kind.
Cite
@article{arxiv.0709.3124,
title = {Combinatorial Entropy for Distinguishable Entities in Indistinguishable States},
author = {Robert K. Niven},
journal= {arXiv preprint arXiv:0709.3124},
year = {2009}
}
Comments
Manuscript for CTNEXT07, Catania, draft