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We have presented first an axiomatic derivation of Boltzmann entropy on the basis of two axioms consistent with two basic properties of thermodynamic entropy. We have then studied the relationship between Boltzmann entropy and information…

General Physics · Physics 2007-12-22 C. G. Chakrabarti , Indranil Chakrabarty

We examine the {combinatorial} or {probabilistic} definition ("Boltzmann's principle") of the entropy or cross-entropy function $H \propto \ln \mathbb{W}$ or $D \propto - \ln \mathbb{P}$, where $\mathbb{W}$ is the statistical weight and…

Statistical Mechanics · Physics 2015-05-13 Robert K. Niven

General relationship between mean Boltzmann entropy and Gibbs entropy is established. It is found that their difference is equal to fluctuation entropy, which is a Gibbs-like entropy of macroscopic quantities. The ratio of the fluctuation…

Statistical Mechanics · Physics 2018-04-19 Pasko Zupanovic , Domagoj Kuic

The paper deals with the generalization of both Boltzmann entropy and distribution in the light of most-probable interpretation of statistical equilibrium. The statistical analysis of the generalized entropy and distribution leads to some…

Quantum Physics · Physics 2009-11-13 C. G. Chakrabarti , Indranil Chakrabarty

Complex systems that are characterized by strong correlations and fat-tailed distribution functions have been argued to be incompatible within the framework of Boltzmann-Gibbs entropy. As an alternative, so-called generalized entropies were…

Statistical Mechanics · Physics 2022-08-15 Rudolf Hanel , Stefan Thurner

It is by now well known that the Boltzmann-Gibbs (BG) entropy $S_{BG}=-k\sum_{i=1}^W p_i \ln p_i$ can be usefully generalized into the entropy $S_q=k (1-\sum_{i=1}^Wp_i^{q}) / (q-1)$ ($q\in \mathcal{R}; S_1=S_{BG}$). Microscopic dynamics…

Statistical Mechanics · Physics 2009-11-10 Giorgos-Artemios Tsekouras , Constantino Tsallis

We shall prove that the celebrated R\'enyi entropy is the first example of a new family of infinitely many multi-parametric entropies. We shall call them the $Z$-entropies. Each of them, under suitable hypotheses, generalizes the celebrated…

Mathematical Physics · Physics 2017-02-07 Piergiulio Tempesta

The notion of entropy penetrates much of science. A key feature of the all-important notion of Boltzmann-Gibbs-Shannon entropy is its extensivity (additivity over independent subsystems). However, there is a need for other quantities. In…

Mathematical Physics · Physics 2008-07-29 Flemming Topsoe

This contribution is dedicated to dilucidating the role of the Gibbs entropy in the discussion of the emergence of irreversibility in the macroscopic world from the microscopic level. By using an extension of the Onsager theory to the phase…

Statistical Mechanics · Physics 2009-11-10 A. Perez-Madrid

Classical statistical mechanics of macroscopic systems in equilibrium is based on Boltzmann's principle. Tsallis has proposed a generalization of Boltzmann-Gibbs statistics. Its relation to dynamics and nonextensivity of statistical systems…

Classical Physics · Physics 2009-11-10 H. J. Haubold , A. M. Mathai , R. K. Saxena

A new axiomatic characterization with a minimum of conditions for entropy as a function on the set of states in quantum mechanics is presented. Traditionally unspoken assumptions are unveiled and replaced by proven consequences of the…

Mathematical Physics · Physics 2014-07-02 Bernhard Baumgartner

Ludwig Boltzmann had a hunch that irreversibility exhibited by a macroscopic system arises from the reversible dynamics of its microscopic constituents. He derived a nonlinear integro-differential equation - now called the Boltzmann…

Statistical Mechanics · Physics 2007-05-23 K. P. N. Murthy

A plethora of natural, artificial and social systems exist which do not belong to the Boltzmann-Gibbs (BG) statistical-mechanical world, based on the standard additive entropy $S_{BG}$ and its associated exponential BG factor. Frequent…

Statistical Mechanics · Physics 2016-06-29 Constantino Tsallis

During the past dozen years there have been numerous articles on a relation between entropy and probability which is non-additive and has a parameter $q$ that depends on the nature of the thermodynamic system under consideration. For $q=1$…

Statistical Mechanics · Physics 2009-11-07 Michael Nauenberg

We brief{}ly review the connection between statistical mechanics and thermodynamics. We show that, in order to satisfy thermodynamics and its Legendre transformation mathematical frame, the celebrated Boltzmann-Gibbs~(BG) statistical…

Statistical Mechanics · Physics 2014-11-03 Constantino Tsallis , Leonardo J. L. Cirto

A statistical thermodynamic approach of moving particles forming an elastic body is presented which leads to reveal molecular-mechanical properties of classical and nonextensive dynamical systems. We derive the Boltzmann-Gibbs (BG) entropy…

Statistical Mechanics · Physics 2009-11-10 Enrique Canessa

Boltzmann's Principle S = k ln W was repeatedly criticized by Einstein since it lacked a proper dynamical foundation in view of the thermal motion of the particles, out of which a physical system consists. This suggests, in particular, that…

Statistical Mechanics · Physics 2013-02-11 E. G. D. Cohen

We study a mechanical system that was considered by Boltzmann in 1868 in the context of the derivation of the canonical and microcanonical ensembles. This system was introduced as an example of ergodic dynamics, which was central to…

Dynamical Systems · Mathematics 2020-08-06 Giovanni Gallavotti , Ian Jauslin

We propose a generalisation of Gibbs' statistical mechanics into the domain of non-negligible phase space correlations. Derived are the probability distribution and entropy as a generalised ensemble average, replacing…

Statistical Mechanics · Physics 2014-09-10 R. A. Treumann , W. Baumjohann

The aim of the present paper is to present a careful and accessible discussion of the formal aspects of Boltzmann-Gibbs and Tsallis entropies. We begin with a brief overview of Boltzmann-Gibbs entropy, highlighting its main properties and…

Statistical Mechanics · Physics 2025-10-23 Kelvin dos Santos Alves , Rogerio Teixeira Cavalcanti