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We investigate the dynamics of kinetically constrained models of glass formers by analysing the statistics of trajectories of the dynamics, or histories, using large deviation function methods. We show that, in general, these models exhibit…

Statistical Mechanics · Physics 2009-01-21 J. P. Garrahan , R. L. Jack , V. Lecomte , E. Pitard , K. van Duijvendijk , F. van Wijland

The Random First Order Transition (RFOT) theory started with the pioneering work of Kirkpatrick, Thirumalai and Wolynes. It leverages the methods and advances of the theory of disordered systems. It fares remarkably well at reproducing the…

Disordered Systems and Neural Networks · Physics 2022-08-12 Giulio Biroli , Jean-Philippe Bouchaud

We examine the dynamics of hard spheres and discs at high packing fractions in two and three dimensions, modeling the simplest systems exhibiting a glass transition. As it is well known, cooperativity and dynamic heterogeneity arise as…

Soft Condensed Matter · Physics 2007-05-23 Burkhard Doliwa , Andreas Heuer

We use event driven simulations to analyze glassy dynamics as a function of density and energy dissipation in a two-dimensional bidisperse granular fluid under stationary conditions. Clear signatures of a glass transition are identified,…

Statistical Mechanics · Physics 2011-10-05 Iraj Gholami , Andrea Fiege , Annette Zippelius

We present a comprehensive theoretical study of finite size effects in the relaxation dynamics of glass-forming liquids. Our analysis is motivated by recent theoretical progress regarding the understanding of relevant correlation length…

Statistical Mechanics · Physics 2012-09-12 Ludovic Berthier , Giulio Biroli , Daniele Coslovich , Walter Kob , Cristina Toninelli

We study the statistical mechanics of supercooled liquids when the system evolves at a temperature $T$ with a field $\epsilon$ linearly coupled to its overlap with a reference configuration of the same liquid sampled at a temperature $T_0$.…

Statistical Mechanics · Physics 2022-04-05 Benjamin Guiselin , Ludovic Berthier , Gilles Tarjus

The mode coupling theory (MCT) of glasses, while offering an incomplete description of glass transition physics, represents the only established route to first-principles prediction of rheological behavior in nonergodic materials such as…

Soft Condensed Matter · Physics 2009-09-29 J. M. Brader , Th. Voigtmann , M. Fuchs , R. G. Larson , M. E. Cates

We numerically study a nondisordered lattice spin system with a first order liquid-crystal transition, as a model for supercooled liquids and glasses. Below the melting temperature the system can be kept in the metastable liquid phase, and…

Statistical Mechanics · Physics 2009-11-07 Andrea Cavagna , Irene Giardina , Tomas S. Grigera

We study the local dynamical fluctuations in glass-forming models of particles embedded in $d$-dimensional space, in the mean-field limit of $d\to\infty$. Our analytical calculation reveals that single-particle observables, such as squared…

Disordered Systems and Neural Networks · Physics 2022-04-27 Giulio Biroli , Patrick Charbonneau , Giampaolo Folena , Yi Hu , Francesco Zamponi

Metallic glasses possess outstanding mechanical and physical properties, making them promising candidates for advanced structural and functional applications; however, the lack of understanding and control over their glass transition and…

Soft Condensed Matter · Physics 2025-06-04 Wei Chu , Zheng Wang , Christopher Ness , Konrad Samwer , Alessio Zaccone , Lina Hu

The growth of correlation lengths in equilibrium glass-forming liquids near the glass transition is considered a critical finding in the quest to understand the physics of glass formation. These understandings helped us understand various…

Soft Condensed Matter · Physics 2023-08-16 Anoop Mutneja , Smarajit Karmakar

We simulate the compression of a two-component Lennard-Jones liquid at a variety of constant temperatures using a molecular dynamics algorithm in an isobaric-isothermal ensemble. The viscosity of the liquid increases with pressure,…

chem-ph · Physics 2009-10-22 Shelly L. Shumway , Andrew S. Clarke , Hannes Jónsson

Recent experiments performed on a variety of soft glassy materials have demonstrated that any imposed shear flow serves to simultaneously fluidize these systems in all spatial directions [Ovarlez \textit{et al.} (2010)]. When probed with a…

Soft Condensed Matter · Physics 2012-02-27 T. F. F. Farage , J. M. Brader

Dense soft glasses show strong collective caging behavior at sufficiently low temperatures. Using molecular dynamics simulations of a model glass former, we show that the incorporation of activity or self-propulsion, f0, can induce cage…

Soft Condensed Matter · Physics 2016-08-01 Rituparno Mandal , Pranab Jyoti Bhuyan , Madan Rao , Chandan Dasgupta

Thermodynamics and kinetics are thought to be linked in glass transitions. The quantitative predictions of -relaxation activation barriers provided by the theory of glasses based on random first order transitions are compared with…

Soft Condensed Matter · Physics 2007-05-23 Jacob D. Stevenson , Peter G. Wolynes

At the mean-field level, on fully connected lattices, several disordered spin models have been shown to belong to the universality class of "structural glasses", with a "random first-order transition" (RFOT) characterized by a discontinuous…

Disordered Systems and Neural Networks · Physics 2012-10-11 C. Cammarota , G. Biroli , M. Tarzia , G. Tarjus

If quenched fast enough, a liquid is able to avoid crystallization and will remain in a metastable supercooled state down to the glass transition, with an important increase in viscosity upon further cooling. There are important differences…

Disordered Systems and Neural Networks · Physics 2016-06-01 C. Yildirim , J. -Y. Raty , M. Micoulaut

We consider the Mode Coupling Theory (MCT) of Glass transition for a Binary fluid. The Equations of Nonlinear Fluctuating Hydrodynamics are obtained with a proper choice of the slow variables corresponding to the conservation laws. The…

Statistical Mechanics · Physics 2009-11-07 Upendra Harbola , Shankar P. Das

Little is known about the coupling of rotation and translation in dense systems. Here, we report results of confocal fluorescence microscopy where simultaneous recording of translational and rotational particle trajectories from a…

Soft Condensed Matter · Physics 2024-11-08 John Geiger , Niklas Grimm , Matthis Fuchs , Andreas Zumbusch

We show that the dynamics of kinetically constrained models of glass formers takes place at a first-order coexistence line between active and inactive dynamical phases. We prove this by computing the large-deviation functions of suitable…

Statistical Mechanics · Physics 2009-11-13 J. P. Garrahan , R. L. Jack , V. Lecomte , E. Pitard , K. van Duijvendijk , F. van Wijland