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We discuss the emergence and growth of the cooperativity accompanying vitrification based on the density fluctuation dynamics for fragile glass-forming liquids. (i) The relaxation of density fluctuations proceeds by the particle (density)…

Soft Condensed Matter · Physics 2019-11-11 Akira Furukawa

We develop a transferable machine learning model which predicts structural relaxation from amorphous supercooled liquid structures. The trained networks are able to predict dynamic heterogeneity across a broad range of temperatures and time…

Soft Condensed Matter · Physics 2024-02-27 Gerhard Jung , Giulio Biroli , Ludovic Berthier

The glass transition refers to the non-equilibrium process by which an equilibrium liquid is transformed to a non-equilibrium disordered solid, or vice versa. Associated response functions, such as heat capacities, are markedly different on…

Soft Condensed Matter · Physics 2013-03-26 Aaron S. Keys , Juan P. Garrahan , David Chandler

One of the most controversial hypotheses for explaining the heterogeneous dynamics of glasses postulates the temporary coexistence of two phases characterized by a high and by a low diffusivity. In this scenario, two phases with different…

Soft Condensed Matter · Physics 2015-07-16 R. Pastore , A. Coniglio , M. Pica Ciamarra

Driven granular systems readily form glassy phases at high particle volume fractions and low driving amplitudes. We use computer simulations of a driven granular glass to evidence a re-entrance melting transition into a fluid state, which,…

Soft Condensed Matter · Physics 2013-02-19 Jan Plagge , Claus Heussinger

Using an activation mechanism reproducing facilitation, a dynamic phase transition triggered by a few active molecules was recently found in a supercooled model liquid. Prompted by this finding we investigate the presence of a similar…

Soft Condensed Matter · Physics 2025-11-14 Quoc Tuan Truong , Victor Teboul

Extending mode-coupling theory, we elaborate a microscopic theory for the glass transition of liquids confined between two parallel flat hard walls. The theory contains the standard MCT equations in bulk and in two dimensions as limiting…

Soft Condensed Matter · Physics 2010-09-15 Simon Lang , Vitalie Botan , Martin Oettel , David Hajnal , Thomas Franosch , Rolf Schilling

We propose a novel computational strategy to study the glass transition of molecular fluids. Our approach combines the construction of simple yet realistic models with the development of Monte Carlo algorithms to accelerate equilibration…

Statistical Mechanics · Physics 2026-03-31 Romain Simon , Jean-Louis Barrat , Ludovic Berthier

The dynamics of glass formation in monatomic and binary liquids are studied numerically using a microscopic field theory for the evolution of the time-averaged atomic number density. A stochastic framework combining phase field crystal free…

Materials Science · Physics 2015-05-27 Joel Berry , Martin Grant

We explore the glassy dynamics of soft colloids using microgels and charged particles interacting by steric and screened Coulomb interactions, respectively. In the supercooled regime, the structural relaxation time $\tau_\alpha$ of both…

We divide glass and viscous liquid sciences into two major research areas, the first dealing with how to avoid crystals and so access the viscous liquid state, and the second dealing with how liquids behave when no crystals form. We review…

Disordered Systems and Neural Networks · Physics 2009-11-13 C. Austen Angell

Within the mode-coupling theory for ideal glass-transitions, the mean-squared displacement and the correlation function for density fluctuations are evaluated for a colloidal liquid of particles interacting with a square-well potential for…

Soft Condensed Matter · Physics 2007-05-23 M. Sperl

Super cooled liquids display increasingly heterogeneous dynamics as temperature is lowered towards the glass transition ($T_{g}$). A hallmark of this dynamical heterogeneity is the spontaneous emergence of cooperative rearranging regions…

Soft Condensed Matter · Physics 2021-12-16 Dipanwita Ghoshal , Ashwin Joy

We analyse the symmetries and the self-consistent perturbative approaches of dynamical field theories for glassforming liquids. In particular, we focus on the time-reversal symmetry (TRS), which is crucial to obtain fluctuation-dissipation…

Statistical Mechanics · Physics 2007-05-23 A. Andreanov , G. Biroli , A. Lefevre

The physics of highly excited Rydberg atoms is governed by blockade or exclusion interactions that hinder the excitation of atoms in the proximity of a previously excited one. This leads to cooperative effects and a relaxation dynamics…

Statistical Mechanics · Physics 2018-09-12 Carlos Pérez-Espigares , Igor Lesanovsky , Juan P. Garrahan , Ricardo Gutiérrez

We assess the validity of "microscopic" approaches of glass-forming liquids based on the sole k nowledge of the static pair density correlations. To do so we apply them to a benchmark provided by two liquid models that share very similar…

Statistical Mechanics · Physics 2011-10-10 Ludovic Berthier , Gilles Tarjus

We use large-scale molecular dynamics simulations to study the kinetics of the liquid-gas phase separation if the temperature is lowered across the glass transition of the dense phase. We observe a gradual change from phase separated…

Statistical Mechanics · Physics 2011-06-01 Vincent Testard , Ludovic Berthier , Walter Kob

We use a simple mode-coupling approach to investigate glassy dynamics of partially pinned fluid systems. Our approach is different from the mode-coupling theory developed by Krakoviack [Phys. Rev. Lett. 94, 065703 (2005), Phys. Rev. E 84,…

Disordered Systems and Neural Networks · Physics 2015-06-04 Grzegorz Szamel , Elijah Flenner

Many molecular glass forming liquids show a shift of the glass transition Tg to lower temperatures when the liquid is confined into mesoporous host matrices. Two contrary explanations for this effect are given in literature: First,…

Mesoscale and Nanoscale Physics · Physics 2010-01-22 J. Koppensteiner , W. Schranz , M. A. Carpenter

Molecular anisotropy plays an important role in the glass transition of a liquid. Recently, a novel bulk glass state has been discovered by optical microscopy experiments on suspensions of ellipsoidal colloids. 'Liquid glass' is a…

Soft Condensed Matter · Physics 2024-05-16 Mohammed Alhissi , Andreas Zumbusch , Matthias Fuchs